Skip to main content

Advertisement

Log in

Asymmetric wetting Janus fabrics with double-woven structure for oil/water separation

  • Polymers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The asymmetric wetting Janus fabric with double-woven structure was designed by using two systems of warp yarns and two types of the weft yarns with distinct wettability. The result shows that the fabric with double-woven structure possesses the asymmetric wettability with superhydrophobicity on one side while superhydrophilicity on the other side. This asymmetric wettability realizes a unidirectional permeation and oil/water separation effect. The efficiency of oil/water separation could be simply controlled by varying fabric densities; thus, suitable density should be regarded as an important factor in this system. In “water removal” mode, the separation efficiency and separation flux reached 99% and 2.5 L m−2 s−1, respectively. In “de-oiling” mode, the separation efficiency and separation flux reached 96% and 8 L m−2 s−1, respectively. According to this work, the as-prepared asymmetric wettability Janus fabric with double-woven structure is promisingly applied to oil/water separation and other related applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10
Figure 11

Similar content being viewed by others

References

  1. Cao G, Zhang W, Jia Z, Liu F, Yang H, Yu Q, Wang Y, Di X, Wang C, Ho S-H (2017) Dually prewetted underwater superoleophobic and under oil superhydrophobic fabric for successive separation of light oil/water/heavy oil three-phase mixtures. ACS Appl Mater Interfaces 9(41):36368–36376. https://doi.org/10.1021/acsami.7b08997

    Article  Google Scholar 

  2. An YP, Yang J, Yang HC, Wu MB, Xu ZK (2018) Janus membranes with charged carbon nanotube coatings for deemulsification and separation of oil-in-water emulsions. ACS Appl Mater Interfaces 10(11):9832–9840. https://doi.org/10.1021/acsami.7b19700

    Article  Google Scholar 

  3. Cao H, Gu W, Fu J, Liu Y, Chen S (2017) Preparation of superhydrophobic/oleophilic copper mesh for oil–water separation. Appl Surf Sci 412:599–605. https://doi.org/10.1016/j.apsusc.2017.04.012

    Article  Google Scholar 

  4. Wang Z, Liu G, Huang S (2016) In situ generated Janus fabrics for the rapid and efficient separation of oil from oil-in-water emulsions. Angew Chem Int Ed 55(47):14610–14613. https://doi.org/10.1002/anie.201607581

    Article  Google Scholar 

  5. Zeng XJ, Xu SP, Pi PH, Cheng J, Wang L, Wang SF, Wen XF (2018) Superhydrophobic-superoleophilic stainless steel meshes by spray-coating of a POSS hybrid acrylic polymer for oil–water separation. J Mater Sci 53(14):10554–10568. https://doi.org/10.1007/s10853-018-2314-4

    Article  Google Scholar 

  6. Wu JD, Zhang C, Jiang DJ, Zhao SF, Jiang YL, Cai GQ, Wang JP (2016) Self-cleaning pH/thermo-responsive cotton fabric with smart-control and reusable functions for oil/water separation. RSC Adv 6(29):24076–24082. https://doi.org/10.1039/c6ra02252a

    Article  Google Scholar 

  7. Feng S, Xing Y, Deng S, Shang W, Li D, Zhang M, Hou Y, Zheng Y (2018) An integrative mesh with dual wettable on-off switch ofwater/oil. Adv Mater Interfaces 5(6):1701193–1701198. https://doi.org/10.1002/admi.201701193

    Article  Google Scholar 

  8. Wang Z, Jiang X, Cheng X, Lau CH, Shao L (2015) Mussel-inspired hybrid coatings that transform membrane hydrophobicity into high hydrophilicity and underwater superoleophobicity for oil-in-water emulsion separation. ACS Appl Mater Interfaces 7(18):9534–9545. https://doi.org/10.1021/acsami.5b00894

    Article  Google Scholar 

  9. Li S, Huang J, Chen Z, Chen G, Lai Y (2017) A review on special wettability textiles: theoretical models, fabrication technologies and multifunctional applications. J Mater Chem A 5(1):31–55. https://doi.org/10.1039/c6ta07984a

    Article  Google Scholar 

  10. Sasaki K, Tenjimbayashi M, Manabe K, Shiratori S (2016) Asymmetric superhydrophobic/superhydrophilic cotton fabrics designed by spraying polymer and nanoparticles. ACS Appl Mater Interfaces 8(1):651–659. https://doi.org/10.1021/acsami.5b09782

    Article  Google Scholar 

  11. Zhou X, Zhang Z, Xu X, Guo F, Zhu X, Men X, Ge B (2013) Robust and durable superhydrophobic cotton fabrics for oil/water separation. ACS Appl Mater Interfaces 5(15):7208–7214. https://doi.org/10.1021/am4015346

    Article  Google Scholar 

  12. Gunatilake UB, Bandara J (2017) Efficient removal of oil from oil contaminated water by superhydrophilic and underwater superoleophobic nano/micro structured TiO2 nanofibers coated mesh. Chemosphere 171:134–141. https://doi.org/10.1016/j.chemosphere.2016.12.031

    Article  Google Scholar 

  13. Zhu Y, Zhang F, Wang D, Pei XF, Zhang W, Jin J (2013) A novel zwitterionic polyelectrolyte grafted PVDF membrane for thoroughly separating oil from water with ultrahigh efficiency. J Mater Chem A 1(18):5758–5765. https://doi.org/10.1039/c3ta01598j

    Article  Google Scholar 

  14. Liu Q, Patel AA, Liu L (2014) Superhydrophilic and underwater superoleophobic poly(sulfobetaine methacrylate)-grafted glass fiber filters for oil–water separation. ACS Appl Mater Interfaces 6(12):8996–9003. https://doi.org/10.1021/am502302g

    Article  Google Scholar 

  15. Yang H-C, Hou J, Chen V, Xu Z-K (2016) Janus membranes: exploring duality for advanced separation. Angew Chem Int Ed 55(43):13398–13407. https://doi.org/10.1002/anie.201601589

    Article  Google Scholar 

  16. Tian X, Jin H, Sainio J, Ras RHA, Ikkala O (2014) Droplet and fluid gating by biomimetic Janus membranes. Adv Func Mater 24(38):6023–6028. https://doi.org/10.1002/adfm.201400714

    Article  Google Scholar 

  17. Wang Z, Wang Y, Liu G (2016) Rapid and efficient separation of oil from oil-in-water emulsions using a Janus cotton fabric. Angew Chem Int Ed 55(4):1291–1294. https://doi.org/10.1002/anie.201507451

    Article  Google Scholar 

  18. Gao Y, Wang J, Xia W, Mou X, Cai Z (2018) Reusable hydrophilic-superhydrophobic patterned weft backed woven fabric for high-efficiency water-harvesting application. ACS Sustain Chem Eng 6(6):7216–7220. https://doi.org/10.1021/acssuschemeng.8b01387

    Article  Google Scholar 

  19. Liu Y-Q, Han D-D, Jiao Z-Z, Liu Y, Jiang H-B, Wu X-H, Ding H, Zhang Y-L, Sun H-B (2017) Laser-structured Janus wire mesh for efficient oil–water separation. Nanoscale 9(45):17933–17938. https://doi.org/10.1039/c7nr06110b

    Article  Google Scholar 

  20. Wang Z, Yang X, Cheng Z, Liu Y, Shao L, Jiang L (2017) Simply realizing “water diode’’ Janus membranes for multifunctional smart applications. Mater Horiz 4(4):701–708. https://doi.org/10.1039/c7mh00216e

    Article  Google Scholar 

  21. Yang X, Wang Z, Shao L (2018) Construction of oil-unidirectional membrane for integrated oil collection with lossless transportation and oil-in-water emulsion purification. J Membr Sci 549:67–74. https://doi.org/10.1016/j.memsci.2017.11.071

    Article  Google Scholar 

  22. Chen JW, Liu YM, Guo DW, Cao MY, Jiang L (2015) Under-water unidirectional air penetration via a Janus mesh. Chem Commun 51(59):11872–11875. https://doi.org/10.1039/c5cc03804a

    Article  Google Scholar 

  23. Manna U, Lynn DM (2015) Synthetic surfaces with robust and tunable underwater superoleophobicity. Adv Func Mater 25(11):1672–1681. https://doi.org/10.1002/adfm.201403735

    Article  Google Scholar 

  24. Wang ZJ, Lehtinen M, Liu GJ (2017) Universal Janus filters for the rapid separation of oil from emulsions stabilized by ionic or nonionic surfactants. Angew Chem Int Ed 56(42):12892–12897. https://doi.org/10.1002/anie.201706158

    Article  Google Scholar 

  25. Gao Y, Wang J, Mou X, Cai Z (2017) Textile-inspired methodology toward asymmetric fabric based on weft-backed weave for oil/water separation. J Mater Sci 53(6):4683–4692. https://doi.org/10.1007/s10853-017-1857-0

    Article  Google Scholar 

  26. Liu Q, Li X, Cai Z (2016) Facile fabrication of asymmetric wettable fabric with weft backed weave for oil/water separation. RSC Adv 6(111):109769–109777. https://doi.org/10.1039/c6ra24515c

    Article  Google Scholar 

  27. Wang H, Ding J, Dai L, Wang X, Lin T (2010) Directional water-transfer through fabrics induced by asymmetric wettability. J Mater Chem 20(37):7938–7940. https://doi.org/10.1039/c0jm02364g

    Article  Google Scholar 

  28. Zhou H, Wang HX, Niu HT, Lin T (2013) Superphobicity/philicity Janus fabrics with switchable, spontaneous, directional transport ability to water and oil fluids. Sci Rep 3:2964. https://doi.org/10.1038/srep02964

    Article  Google Scholar 

  29. Wu J, Wang N, Wang L, Dong H, Zhao Y, Jiang L (2012) Unidirectional water-penetration composite fibrous film via electrospinning. Soft Matter 8(22):5996–5999. https://doi.org/10.1039/c2sm25514f

    Article  Google Scholar 

  30. Guo DY, Hou K, Xu SP, Lin YG, Li L, Wen XF, Pi PH (2018) Superhydrophobic-superoleophilic stainless steel meshes by spray-coating of a POSS hybrid acrylic polymer for oil–water separation. J Mater Sci 53(9):6403–6413. https://doi.org/10.1007/s10853-017-1542-3

    Article  Google Scholar 

  31. Xiang Y, Shen J, Wang Y, Liu F, Xue L (2015) A pH-responsive PVDF membrane with superwetting properties for the separation of oil and water. RSC Adv 5(30):23530–23539. https://doi.org/10.1039/c5ra00739a

    Article  Google Scholar 

Download references

Acknowledgements

The work was supported by a Grant from the National Key R&D Program of China (2017YFB0309400), (2017YFB0309100).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zaisheng Cai.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yao, C., Luo, M., Wang, H. et al. Asymmetric wetting Janus fabrics with double-woven structure for oil/water separation. J Mater Sci 54, 5942–5951 (2019). https://doi.org/10.1007/s10853-018-03241-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-018-03241-6

Navigation