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Apatite-forming ability of hydrothermally deposited rutile nano-structural arrays with exposed {101} facets on Ti foil

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Abstract

Highly ordered TiO2 nano-pillar arrays were deposited on the Ti foils by a hydrothermal method, using aqueous solutions of TiOSO4. The vertical nano-pillars with diameters in tens of nanometers strongly attached on the Ti foil and densely covered the whole surface. The structural studies clearly showed that the nano-pillars were pure tetragonal rutile TiO2 phase. [001] was the preferential growth direction. Based on the experimental results, a model for the in situ deposition of TiO2 with high-energy facet exposed is given. The growth mechanism was interpreted in terms of the lattice matching between the growing nano-structural titania and Ti, and the thermodynamic stability of the rutile lattice planes. The obtained TiO2 crystallographic plane with high energy induced apatite nucleation in less than 1 day and exhibited good in vitro bioactivity.

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Acknowledgements

This work was supported by National Natural Science Foundation of China (50702050), the Natural Science Foundation of Zhejiang Province, China (LY15E020010), and Okayama University, Japan.

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Authors and Affiliations

  1. Zhejiang University of Technology, Hangzhou, 310014, Zhejiang, People’s Republic of China

    Fan Xiao, Guang-Qiang Jiang, Jin-Yu Chen, Zhen-Lan Jiang & Xiao-Chun Ma

  2. Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama-shi, 700-8530, Japan

    Xing-Zhu Liu

  3. School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang, 471023, Henan, People’s Republic of China

    Akiyoshi Osaka

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  1. Fan Xiao
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  2. Guang-Qiang Jiang
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Correspondence to Xiao-Chun Ma.

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Xiao, F., Jiang, GQ., Chen, JY. et al. Apatite-forming ability of hydrothermally deposited rutile nano-structural arrays with exposed {101} facets on Ti foil. J Mater Sci 53, 285–294 (2018). https://doi.org/10.1007/s10853-017-1513-8

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  • DOI: https://doi.org/10.1007/s10853-017-1513-8

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