Skip to main content
Log in

Formicary-like carbon nanotube/copper hybrid nanostructures for carbon fiber-reinforced composites by electrophoretic deposition

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

An electrophoretic deposition process has been applied to produce unique carbon nanotube (CNT)/copper nanostructures on the carbon fiber surfaces. During the deposition process, ionized copper and positively charged CNTs are accelerated towards the carbon fiber under applied electric fields. An interconnected formicary-like network of nanotubes and nanoparticles is formed where copper nucleation and growth occurs predominantly at nanotube crossing and edge-contact locations. When embedded in a structural composite the CNT/copper structures create a highly conductive and strongly bonded network shown by significant enhancements in both electrical conductivity and interlaminar shear strength as compared to composites without the CNT/copper nanostructures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Thostenson ET, Ren Z, Chou TW (2001) Compos Sci Technol 61:1899

    Article  CAS  Google Scholar 

  2. Lia J, Luo R (2008) Composites Part A 39:1700

    Article  Google Scholar 

  3. Bekyarova E, Thostenson ET, Yu A, Kim H, Gao J, Tang J, Hahn HT, Chou TW, Itkis ME, Haddon RC (2007) Langmuir 23:3970

    Article  CAS  Google Scholar 

  4. Cho J, Boccaccini AR, Shaffer MSP (2009) J Mater Sci 44:1934. doi:10.1007/s10853-009-3262-9

    Article  CAS  Google Scholar 

  5. Zhu J, Imam A, Crane R, Lozano K, Khabashesku VN, Barrera EV (2007) Compos Sci Technol 67:1509

    Article  CAS  Google Scholar 

  6. Qiu J, Zhang C, Wang B, Liang R (2007) Nanotechnology 18:275708

    Article  Google Scholar 

  7. Grimmer CS, Dharan CKH (2008) J Mater Sci 43:4487. doi:10.1007/s10853-008-2651-9

    Article  CAS  Google Scholar 

  8. Sandler J, Shaffer MSP, Prasse T, Bauhofer W, Schulte K, Windle AH (1999) Polymer 40:5967

    Article  CAS  Google Scholar 

  9. Gojny FH, Wichmann MHG, Fiedler B, Bauhofer W, Schulte K (2005) Composites Part A 36:1525

    Article  Google Scholar 

  10. Thostenson ET, Chou TW (2006) Adv Mater 18:2837

    Article  CAS  Google Scholar 

  11. Kuzumaki T, Ujiie O, Ichinose H, Ito K (2000) Adv Eng Mater 2:416

    Article  CAS  Google Scholar 

  12. Lau KT, Hui D (2002) Carbon 40:1605

    Article  CAS  Google Scholar 

  13. Li CY, Thostenson ET, Chou TW (2007) Appl Phys Lett 91:223114

    Article  Google Scholar 

  14. Cha SI, Kim KT, Arshad SN, Mo CB, Hong SH (2005) Adv Mater 17:1377

    Article  CAS  Google Scholar 

  15. Wang J, Chen G, Wang M, Chatrathi MP (2004) Analyst 129:512

    Article  CAS  Google Scholar 

  16. Kuzumaki T, Miyazawa K, Ichinose H, Ito K (1998) J Mater Res 13:2445

    Article  CAS  Google Scholar 

  17. Zhan GD, Kuntz JD, Wan J, Mukherjee AK (2002) Nat Mater 2:38

    Article  Google Scholar 

  18. Kim KT, Eckert J, Menzel SB, Gemming T, Hong SH (2008) Appl Phys Lett 92:121901

    Article  Google Scholar 

  19. Lee SB, Matsunaga K, Ikuhara Y, Lee SK (2007) Mater Sci Eng A 449–451:778

    Google Scholar 

  20. Besra L, Liu M (2007) Prog Mater Sci 52:1

    Article  CAS  Google Scholar 

  21. Boccaccini AR, Cho J, Roether JA, Thomas BJC, Minay EJ, Shaffer MSP (2006) Carbon 44:3149

    Article  CAS  Google Scholar 

  22. Park JK, Do IH, Askeland P, Drzal LT (2008) Compos Sci Technol 68:1734

    Article  CAS  Google Scholar 

  23. Zhang G, Sun S, Yang D, Dodelet J, Sacher E (2008) Carbon 46:196

    Article  CAS  Google Scholar 

  24. Silvain JF, Vincent C, Heintz JM, Chandra N (2009) Compos Sci Technol 69:2474

    Article  CAS  Google Scholar 

  25. Lee SB, Choi O, Lee W, Yi JW, Kim BS, Byun JH, Yoon MK, Fong H, Thostenson ET, Chou TW (2010) Composites Part A doi:10.1016/j.compositesa.2010.10.016

Download references

Acknowledgements

This work was supported by the Korea Foundation for International Cooperation of Science & Technology (KICOS) through a Grant provided by the Korean Ministry of Education, Science & Technology (MEST) in 2007 (No. K20704000090) and also supported by the Principal Research Program in the Korea Institute of Materials Science (KIMS).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Joon-Hyung Byun.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lee, W., Lee, SB., Choi, O. et al. Formicary-like carbon nanotube/copper hybrid nanostructures for carbon fiber-reinforced composites by electrophoretic deposition. J Mater Sci 46, 2359–2364 (2011). https://doi.org/10.1007/s10853-010-5082-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-010-5082-3

Keywords

Navigation