Abstract
Dye-sensitized solar cells (DSSCs) were fabricated using TiO2 mesoporous layers obtained by very simple method—transformation of TiO2 nanotube (NT) films grown by electrochemical oxidation to nanoparticle (NP) films. This transformation is based on thermal annealing of TiO2 NT arrays formed by anodization of titanium foil in fluorine ambient. Performance of DSSCs fabricated with different size NPs was studied in the range from 35 to 350 nm. Highest nominal efficiency (9.05%) was achieved for DSSC with NP size 65 nm while the lowest nominal efficiency (1.48%) was observed for DSSCs with NP size 350 nm. The dependence of the solar cell parameters with NP size is discussed.
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References
Grätzel M (2001) Nature 414:338
Grätzel M (2005) Inorg Chem 44:6841
Nazeeruddin MK, De Angelis F, Fantacci S, Selloni A, Viscardi G, Liska P, Ito S, Takeru B, Grätzel M (2005) J Am Chem Soc 127:16835
Nishino J, Teekateerawej S, Nosaka Y (2004) J Mater Sci 39:3813. doi:10.1023/B:JMSC.0000030746.52141.55
Han H, Zan L, Zhong J, Zhao X (2005) J Mater Sci 40:4291. doi:10.1007/s10853-005-3880-9
Alivov Y, Fan ZY (2009) J Phys Chem C 113:12954
Zwilling V, Aucouturier M, Darque-Ceretti E (1991) Electrochim Acta 45:921
Macak JM, Schmuki P (2006) Electrochim Acta 52:1258
Alivov Y, Pandikunta M, Nikishin S, Fan ZY (2009) Nanotechnology 20:225602
Paulose M, Shankar K, Yoriya S, Prakasam HE, Varghese OK, Mor GK (2006) J Phys Chem B 110:16179
Shankar K, Mor GK, Prakasam HE, Yoriya S, Paulose M, Varghese OK, Grimes CA (2007) Nanotechnology 18:065707
Alivov Y, Fan ZY (2009) Nanotechnology 20:405610
Bisquert J, Cahen D, Hodes G, Rühle S, Zaban A (2004) J Phys Chem B 108:8106
Gregg BA, Pichot F, Ferrere S, Fields CL (2001) J Phys Chem B 105:1422
Kay A, Grätzel M (2002) Chem Mater 14:2930
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Alivov, Y., Fan, Z.Y. Dye-sensitized solar cells using TiO2 nanoparticles transformed from nanotube arrays. J Mater Sci 45, 2902–2906 (2010). https://doi.org/10.1007/s10853-010-4281-2
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DOI: https://doi.org/10.1007/s10853-010-4281-2