Abstract
The effect of large concentration of oxygen on the microstructural development of Zr–Cu–Al–Ni bulk metallic glass (BMG) alloys, prepared from commercially available Zr sponge, has been studied. Apart from promoting crystallization, increased concentration of oxygen (∼8000 ppm) spawns additional phases. In particular, we report the appearance of α-Zr, dendritic Zr2Cu phase and the Zr2Ni type cubic phases. Addition of oxygen scavenger like Yttrium only partially solves the problem. Phase evolution was also found to be sensitive to the cooling rate and hence to the thickness of the cast sample. Thus it is possible to produce a gradient microstructure with predominantly amorphous phase at the outer layer.
Similar content being viewed by others
References
Lin XH, Johnson WL, Rhim WK (1997) Mater Trans JIM 38:473
Eckert J, Mattern N, Zinkevitch M, Seidel M (1998) Mater Trans JIM 39:623
Gebert A, Eckert J, Schultz L (1998) Acta Mater 46:5475
Murty BS, Ping DH, Hono K, Inoue A (2000) Acta Mater 48:3985
Zhang Y, Zhao DQ, Wang RJ, Pan MX, Wang WH (2000) Mater Trans JIM 41:1410
Liu CT, Chisholm MF, Miller MK (2002) Intermetallics 10:1105
Conner RD, Maire RE, Johnson WL (2006) Mater Sci Engg A 419:148
Ping DH, Hono K, Inoue A (1999) In: Johnson WL, Inoue A, Liu CT (eds) Bulk metallic glasses, vol. 554, MRS, Warren dale, PA, p 3
Kuebler A, Eckert J, Gebert A, Schultz L (1998) J Appl Phys 83:3438
Koester U, Meinhardt J, Ross S, Ruedigger A (1996) Mater Sci Forum 225–227:311
Inoue A, Shinohara Y, Yokoyama Y, Masumoto T (1995) Mater Trans JIM 36:1276
Frankwicz PS, Ram S, Fecht HJ (1996) Mater Lett 28:77
Inoue A, Zhang T, Nishiyama N, Ohba K, Masumoto T (1993) Mater Trans JIM 34:1234
Zhang T, Inoue A, Masumoto T (1991) Mater Trans JIM 32:1005
Zhang Y, Pan MX, Zhao DeQ, Wang RJ, Wang WH (2000) Mater Trans JIM 41:1410
Altounian Z, Guo-hua T, Strom-Olsen JO (1983) J Appl Phys 54:3111
Inoue A, Zhang T, Kim YH (1997) Mater Trans JIM 38:749
Basu J, Nagendra N, Li Y, Ramamurty U (2003) Phil Mag 83:1747
Greer AL (2001) Mater Sci Engng A304–A306:68
Nagendra N, Ramamurty U, Goh TT, Li Y (2000) Acta Mater 48:2603
Jana S, Ramamurty U, Chattopadhyay K, Kawamura Y (2004) Mater Sci Eng A 375–377:1191
Jana S, Bhowmik R, Kawamura Y, Chattopadhyay K, Ramamurty U (2004) Intermetallics 12:1097
Koester U, Meinhardt J, Roos S, Busch R (1997) Mater Sci Engg A226–228:995
Koester U, Meinhardt J (1994) Mater Sci Engg A 178:271
Altounian Z, Shank RJ, Strom-Olsen JO (1985) J Appl Phys 58:1192
Mitra S (2000) M.E. Thesis, Indian Institute of Science, Bangalore
Acknowledgment
Financial support for this work was provided by a grant to IISc by the Defence Research and Development Organization (DRDO), Government of India.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bhowmick, R., Majumdar, B., Misra, D.K. et al. Synthesis of bulk metallic glass composites using high oxygen containing Zr sponge. J Mater Sci 42, 9359–9365 (2007). https://doi.org/10.1007/s10853-007-1856-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-007-1856-7