Abstract
A series of glass comprising of SiO2–MgO–B2O3–Y2O3–Al2O3 in different mole ratio has been synthesized. The crystallization kinetics of these glasses was investigated using various characterization techniques such as differential thermal analysis (DTA), thermo gravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). Crystallization behavior of these glasses was markedly influenced by the addition of Y2O3 instead of Al2O3. Addition of Y2O3 increases the transition temperature, T g, crystallization temperature, T c and stability of the glasses. Also, it suppresses the formation of cordierite phase, which is very prominent and detrimental in MgO-based glasses. The results are discussed on the basis of the structural and chemical role of Y3+ and Al3+ ions in the present glasses.
Similar content being viewed by others
References
Ley KL, Krumpel M, Meisser TR, Bloom I (1996) J Mat Res 11:1449
Eichler K, Solow G, Otschil P, Schaffrath W (1999) J Eur Ceram Soc 19:1101
Sung YM (1996) J Mater Sci 31:5421. DOI: 10.1007/BF01159312
Lahl N, Singh K, Singheiser L, Hilpert K, Bahadur D (2000) J Mater Sci 35:3089. DOI: 10.1023/A: 1004851418274
Lahl N, Bahadur D, Singh K, Singheiser L, Hilpert K (2002) J Electrochem Soc 149:A607
Schwickert T, Sievering R, Geasee P, Conradt R (2002) Matt-wisu Werkstofftech 33:363
Lara C, Pauscal MJ, Duran A (2004) J Non-Cryst Solids 348:149
Zdaniewski W (1975) J Am Ceram Soc 58:163
Yun-Mo-Sung (2002) J Mater Res 17:517
Mac Dowell JF, Beall GH (1969) J Am Ceram Soc 52:17
Davis RF, Pask JA (1972) J Am Ceram Soc 55:525
Bahadur D, Lahl N, Singh K, Singheiser L, Hilpert K (2004) J Electrochem Soc 15:A558
Lee JD (1993) Concise inorganic chemistry, 4th edn. Chapman and Hall, London, p 683
Madras G, Coy BJ (2001) J Chem Phys 115:6699
Zimmermann M, Carrard M, Kurz W (1989) Acta Metall 37:3305
Zimmermann M, Carrard M, Gremand M, Kurz W (1995) Mat Sci Eng A 134:1278
Grimand M, Carrard M, Kurz W (1990) Acta Metall Mater 38:2587
Ito E, Akaogi M, Topor L, Navrotsky A (1990) Science 249:1275
Leinenweber K, Navrotsky A (1988) Phys Chem Minerals 15:588
Yagi T, Mao HK, Bell PM (1978) Phys Chem Minerals 3:97
Horiuchi H, Sawamoto H (1981) Am Mineral 66:568
Acknowledgement
For carrying out this research the financial assistance provided by All India Council for Technical Education (AICTE), New Delhi and Department of Science and Technology (DST) is highly acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Singh, K., Gupta, N. & Pandey, O.P. Effect of Y2O3 on the crystallization behavior of SiO2–MgO–B2O3–Al2O3 glasses. J Mater Sci 42, 6426–6432 (2007). https://doi.org/10.1007/s10853-006-1188-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-1188-z