Skip to main content
SpringerLink
Log in

Texture in solid-state reactions

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The crystallography and texture of solid-state reactions have been studied using electron backscatter diffraction (EBSD) in a scanning electron microscope (SEM). The crystallography of both the reaction interfaces and the grain boundaries plays an important role in the kinetics of the formation of the reaction products. The growth of the reaction products is dependent upon the transport of ions through the material, which is, in turn, affected by both the orientation of the reactants and by grain boundaries in the reactants and in the reaction products. In order to predict or control the behavior of the reactions, the crystallography of all the interfaces present in the reaction must be more fully understood. In the present study, MgIn2O4 was formed by the reaction between a single-crystal MgO substrate and a thin film of In2O3 with and without an applied electric field.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17

Similar content being viewed by others

References

  1. Worrell WL (1988) Solid State Ionics 28–30:1215

    Article  Google Scholar 

  2. Julien C (2003) Solid State Ionics 157:57

    Article  CAS  Google Scholar 

  3. Mackenzie KJD, Ryan MJ (1981) J Mater Sci 16:579

    Article  CAS  Google Scholar 

  4. Brown IWM, Mackenzie KJD (1982) J Mater Sci 17:3663

    Article  CAS  Google Scholar 

  5. Schmalzried H, Smolin S (1998) Ber Bunsen-Gesell-Phys Chem, Chem Phys 102:1740

    CAS  Google Scholar 

  6. Johnson MT, Schmalzried H, Carter CB (1997) Solid State Ionics 101–103:1327

    Article  Google Scholar 

  7. Johnson MT, Gilliss SR, Carter CB (1998) Microsc Microanal 4:158

    CAS  Google Scholar 

  8. Johnson MT, Carter CB (1999) Phil Mag Lett 79:609

    Article  CAS  Google Scholar 

  9. Korte C, Ravishankar N, Carter CB, Schmalzried H (2002) Solid State Ionics 148:111

    Article  CAS  Google Scholar 

  10. Korte C, Farrer JK, Ravishankar N, Schmalzried H, Michael JR, Carter CB (2000) Mater Res Soc Symp Proc 586:151, MRS, Warendale, PA, Boston, MA

  11. Schmalzried H (1995) Chemical kinetics of solids, VCH

  12. Schmalzried H (1981) Solid state reactions, 2nd edn. Verlag Chemie

  13. Pfeiffer T, Schmalzried H (1989) Z Phys Chem Neue Folge 161:1

    CAS  Google Scholar 

  14. Wagner C (1936) Z Phys Chem B34:309

    CAS  Google Scholar 

  15. Simpson YK, Carter CB (1987) Mater Res Soc Symp Proc 94:45

    CAS  Google Scholar 

  16. Becker KD (1994) In: d’Heurle FM, Gas P, Martin M, Philibert J (eds) Reactive formation of phases at interfaces and diffusive processes, vol 155–156. Trans Tech Publications

  17. Kotula PG, Johnson MT, Carter CB (1998) Z Phys Chem 206:73

    CAS  Google Scholar 

  18. Wagner C (1938) Z Anorg Allgem Chem NF148:21

    Google Scholar 

  19. Schmalzried H (1962) Z Phys Chem Neue Folge 33:111

    CAS  Google Scholar 

  20. Simpson YK (1989) Grain Boundaries, Phase Boundaries and Reactions in Ceramic Oxides. Ph.D. Thesis, Cornell University

  21. Kotula PG, Carter CB (1998) J Am Ceram Soc 81:2869

    Article  CAS  Google Scholar 

  22. Kotula PG, Carter CB (1995) Proceedings of the 53rd Annual Meeting of MSA, 338

  23. Thirsk HR, Whitmore EJ (1940) Trans Faraday Soc 36:565

    Article  CAS  Google Scholar 

  24. Kotula PG, Carter CB (1995) Scripta Metall 32:863

    Article  CAS  Google Scholar 

  25. Johnson MT, Carter CB (1997) Solid State Ionics 101–103:1327

    Article  Google Scholar 

  26. Johnson MT, Carter CB (1998) Microsc Microanal 4(2):141

    CAS  Google Scholar 

  27. Senz S, Blum W, Hesse D (2001) Phil Mag A 81:109

    Article  CAS  Google Scholar 

  28. Jing S-Y, Lin L-B, Huang N-K, Zhang J, Lu Y (2000) J Mater Sci Lett 19:225

    Article  CAS  Google Scholar 

  29. Huang M-R, Lin C-W, Lu H-Y (2001) Appl Surf Sci 177:103

    Article  CAS  Google Scholar 

  30. Susnitzky DW, Carter CB (1991) J Mater Res 6:1958

    Article  CAS  Google Scholar 

  31. Kotula PG, Carter CB (1998) J Am Ceram Soc 81:2877

    Article  CAS  Google Scholar 

  32. Johnson MT, Heffelfinger JR, Kotula PG, Carter CB (1997) J Microsc 185:225

    Article  CAS  Google Scholar 

  33. Johnson MT, Kotula PG, Carter CB (1997) In: Pond CEA (ed) Boundaries and Interfaces in Materials: David A. Smith Symposium. Proceedings of the Memorial Symposium. TMS, Indiannapolis, 141 pp

  34. Werner P, Sieber H, Hillebrand R, Hesse D (1997) Mater Res Soc Symp Proc 466:191, MRS, Warrendale, PA, USA, Boston, MA

  35. Hesse D (1997) Solid State Ionics 95:1

    Article  CAS  Google Scholar 

  36. Goehner RP, Michael JR (1996) J Res Nat Inst Standard Tech 101:301

    CAS  Google Scholar 

  37. Schwarzer RA (1996) Ultramicroscopy 67:19

    Article  Google Scholar 

  38. Randle V (1992) Microtexture determination. The Institute of Materials

  39. Adams BL (1997) Ultramicroscopy 67:11

    Article  CAS  Google Scholar 

  40. Farrer JK, Carter CB, Ravishankar N (2006) J Mater Sci 41:661

    Article  CAS  Google Scholar 

  41. Farrer JK, Carter CB (2006) J Mater Sci 41:779

    Article  CAS  Google Scholar 

  42. Pijolat C, Riviere B, Kamionka M, Viricelle JP, Breuil P (2003) J Mater Sci 38:4333

    Article  CAS  Google Scholar 

  43. Chopra KL (1983) Thin Solid Films 102:1

    Google Scholar 

  44. Sieber H, Senz S, Hesse D (1997) Thin Solid Films 303:216

    Article  CAS  Google Scholar 

  45. Kamei M, Shigesato Y, Takaki S (1995) Thin Solid Films 259:38

    Article  CAS  Google Scholar 

  46. Taga N, Odaka H, Shigesato Y, Yasui I, Kamei M, Haynes TE (1996) J Appl Phys 80:978

    Article  CAS  Google Scholar 

  47. Tarsa EJ, English JH, Speck JS (1993) Appl Phys Lett 62:2332

    Article  CAS  Google Scholar 

  48. Farrer JK, Michael JR, Carter CB (200) In: Schwartz AJ, Kumar M, Adams BL (eds) Electron backscatter diffraction in materials science. Kluwer Academic/Plenum Publishers, 299 pp

  49. Michael JR (2000) In: Schwartz AJ, Kumar M, Adams BL (eds) Electron backscatter diffraction in materials science. Kluwer Academic/Plenum Publishers, 75 pp

  50. Krieger-Lassen NC, Conradsen K, Juul Jensen D (1992) Scanning Microsc 6:115

    Google Scholar 

  51. Wright SI (2000) In: Schwartz AJ, Kumar M, Adams BL (eds) Electron backscatter diffraction in materials science. Kluwer Academic/Plenum Publishers, 51 pp

  52. Bunge H-J (1982) Texture analysis in materials science: mathematical methods. Butterworths

  53. Nowell MM, Wright SI (2004) J Microsc 213:296

    Article  CAS  Google Scholar 

  54. Kotula PG, Carter CB (1993) In: Proceedings of the 2nd International Conference on Laser Ablation, Knoxville, TN, 231 pp

Download references

Acknowledgements

The authors would like to thank Prof. N. Ravishankar, Dr. Carsten Korte and Dr. Matt Johnson for extensive discussions relating to this work. The experimental part of this study was carried out at the University of Minnesota and at the laboratories of TSL in Utah. This research has been supported by the 3M Heltzer Endowed Chair and the US Department of Energy under Grant Numbers DE-FG02-92ER45465-A004 and DE-FG02-01ER45883.

Author information

Authors and Affiliations

  1. Department of Physics and Astronomy, Brigham Young University, Provo, UT, 84602, USA

    Jeffrey K. Farrer

  2. Department of Chemical Engineering & Materials Science, University of Minnesota, Minneapolis, MN, 55455, USA

    C. Barry Carter

Authors
  1. Jeffrey K. Farrer
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Barry Carter
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to C. Barry Carter.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Farrer, J.K., Carter, C.B. Texture in solid-state reactions. J Mater Sci 41, 5169–5184 (2006). https://doi.org/10.1007/s10853-006-0428-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-006-0428-6

Keywords

Search

Navigation