Abstract
The instability of solid–liquid interface (ISLI) during the liquid-phase sintering was studied using carbide–Ni composites. Of the various transitional metal carbides TiC of 4th period is the only carbide that exhibits a strong ISLI with negative curvatures in molten Ni. No ISLI was observed for other carbides in the 5th and 6th periods. The origin of ISLI is strain developed at the interface between the carbides and the newly formed solid solutions. The difference in the size of the atoms involved can be used to predict the formation of a carbide–Ni solid solution when the Hume-Rothery rules are applied. Aside from the size factor, other factors in the rules are not effective in predicting this phenomenon.
Similar content being viewed by others
References
Hillert M (1983) Scripta Met 17:237
Song Y-D, Yoon DN (1984) Metall Trans A 15A:1503
Lee K-R, Baik Y-J, Yoon DN (1987) Acta Met 35(8):2145
Chae K-W, Chun D-Il, Kim D-Y, Baik Y-J, Eun K-Y (1990) J Am Ceram Soc 73(7):1979
Chun D-Il, Kim D-Y, Eun K-Y (1993) J Am Ceram Soc 76(8):2049
Yoon DY (1995) Int Mat Rev 40(4):149
Park S-D, Park J-K, Kang S, Kim D-Y (1998) J Mat Syn Pro 6(4):255
Ahn S-Y, Kim S-W, Kang S (2001) J Am Ceram Soc 84(4):843
Ahn S, Kang S (2001) Int J Ref Met Hard Mat 19:539
Hume-Rothery W (1963) In: Atoms metals and alloys, Dover Publications, Inc., New York, pp 284–293
Acknowledgements
This research was sponsored by KISTEP (Korean Institute of S&T Evaluation and Planning) research fund through New Frontier Projects of the 21st Century (2002) via KIMM (Korean Institute of Machine and Machinery).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kwon, HJ., Kang, S. Instability of solid–liquid interface in transitional metal–carbide systems. J Mater Sci 41, 4649–4653 (2006). https://doi.org/10.1007/s10853-006-0058-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-0058-z