Abstract
Poly(4-vinylpyridine) (P4VP) was used as the macromolecular curing agent to prepare epoxy networks. The crosslinking structures were investigated by means of Fourier transform infrared spectroscopy (FTIR). It is identified that depending on the ratios of DGEBA to P4VP, different reactions dominated the formation of the crosslinking networks, which were involved the formation of pyridone (or cyclic amide) resulting from epoxide groups of DGEBA and pyridine rings of P4VP, the Diels-Alder reaction of in situ formed conjugated 3,5-diene in a 6-member ring and the homopolymerization of DGEBA initiated by pyridine moiety of P4VP. Differential scanning calorimetry (DSC) showed that all the DGEBA-P4VP co-crosslinked thermosets displayed single glass transition temperature (Tg), suggesting that the crosslinked networks are homogenous. In addition, it is noted that the Tg's of the DGEBA-rich network are greatly dependent on the molecular weight of P4VP used.
Similar content being viewed by others
References
J. P. PASCAULT and R. J. J. WILLIAMS, in “Polymer Blends” edited by D. R. Paul C. B. Bucknall (Wiley, New York, 2000) Vol. 1, p. 379.
R. J. J. WILLIAMS, B. A. ROZENBERG and J. P. PASCAULT, Adv. Polym. Sci. 128 (1997) 95.
X. LUO, S. ZHENG, N. ZHANG and D. MA, Polymer 35 (1994) 2619.
S. ZHENG, N. ZHANG, X. LUO and D. MA, ibid. 36 (1995) 3609.
Q. GUO, C. HARRATS, G. GROENINCKS and M. H. J. KOCH, ibid. 42 (2001) 4127.
Q. GUO, C. HARRATS, G. GROENINCKS, H. REYNAERS and M. H. J. KOCH, ibid. 42 (2001) 6031.
Q. GUO and G. GROENINCKS, ibid. 42 (2001) 8647.
S. ZHENG, H. ZHENG and Q. GUO, J. Polym. Sci., Part B: Polym. Phys. 41 (2003) 1085.
S. ZHENG, Q. GUO and C.-M. CHAN, ibid. 41 (2003) 1099.
M. C. CHEN, D. J. HOURSTON and W. B. SUN, Eur. Polym. J. 28 (1992) 1471.
E. MARTUCELLI, P. MUSTO, G. RAGOSTA and G. SCARINZI, Angew. Makromol. Chem. 204 (1993) 153.
M. ABBATE, E. MARTUCELLI, P. MUSTO, G. ROGOSTA and G. SCARINZI, J. Polym., Sci., Part B: Polym. Phys. 32 (1992) 395.
Y. YU and J. P. BELL, J. Polym. Sci., Part A: Polym. Chem. 26 (1988) 247.
C. C. SU and E. M. WOO, Macromolecules 28 (1995) 6779.
M.-S. LI, C.-C. M. MA, J.-L. CHEN, M.-L. LIN and F.-C. CHANG, ibid. 26 (1996) 499.
Y. P. HUANG and E. M. WOO, Polymer 43 (2002) 6795.
B. S. GORTON, J. App. Polym. Sci. 8 (1964) 1287.
R. I. BUTT and J. L. COTTER, J. Adhesion 8 (1976) 11.
Y. Y. WANG and S. A. CHEN, Polym. Eng. Sci. 20 (1980) 823.
Z. ZHU, R. XUE and Y. C. YU, Angew. Makromol. Chem. 171 (1989) 65.
M. R. HOMER and F. J. BOERIO, J. Adhesion 32 (1990) 141.
Z. ZHONG and Q. GUO, Polymer 39 (1998) 3541.
S.-M. OH, L. R. FAULKNER, J. Electroanal. Chem. 269 (1989) 77.
J.-M. ZEN, H.-H. CHUNG and G. ILANGOVAN, Electroanalysis 11 (1999) 108.
Idem., Anal. Chem. 67 (1995) 3571.
H. IHARA, W. DONG, T. MIMAKI, M. NISHIHARA, T. SAKURAI, M. TAKAFUJI and S. NAGAOKA, J. Liquid Chromatography & Related Tech. 26 (2003) 2473.
S. POLOWINSKI, Prog. Polym. Sci. 27 (2002) 537.
F. RICCIARDI and M. M. JOULLIE, J. Polym. Sci., Polym. Lett. Ed. 20 (1982) 127.
G. XUE, H. ISHIDA and J. L. KONIG, Makromol. Chem., Rapid Commun. 7 (1986) 37.
Idem., Angew. Makromol. Chem. 142 (1986) 17.
M. M. COLEMAN, J. F. GRAF and P. C. PAINTER, “Specific Interactions and the Miscibility of Polymer Blends”, Technomic Publishing, Lancaster, PA, 1991.
F. GONZALEZ, P. ORTIZ, and N. GALEGO, Polym. Int. 42 (1997) 163.
J. BERGER and F. LOHSE, Eur. Polym., J. 21 (1985) 435.
M. J. DEILARUJA, J. IRUIN and M. J. FERNANDEZ-BERRIDI, Macromolecules 28 (1995) 3707.
S. ZHENG and Y. MI, Polymer 42 (2003) 1067.
K. F. PURCELL and R. S. DRAGO, J. Am. Chem. Soc. 24 (1968) 251.
M. M. COLEMAN and P. C. PAINTER, Appl. Spectrosc. Rev. 20 (1984) 225.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Meng, F., Zhang, W. & Zheng, S. Epoxy resin cured with poly(4-vinyl pyridine). J Mater Sci 40, 6367–6373 (2005). https://doi.org/10.1007/s10853-005-1732-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-005-1732-2