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Recent developments in microextraction techniques based on crown ethers

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Abstract

Sample preparation is essential for isolating desired components from complex matrices and greatly influences their reliable and accurate analysis. Microextraction techniques such as solid phase micro extraction and liquid–liquid–liquid micro extraction based on hollow fiber and also single drop micro extraction methods are new and effective sample preparation techniques. Crown ethers are heterocyclic chemical compounds that consist of a ring containing several ether groups. Recently crown ethers have been applied in these methods and increase efficiency and selectivity of these techniques. Here we review the application of crown ethers in various micro extraction techniques.

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References

  1. Mohammad Zadeh Kakhki, R., Rounaghi, G.H.: Competitive bulk liquid membrane transport of heavy metal cations using the 18-crown-6 ligand as an ionophore. J. Chem. Eng. Data 56, 3169–3174 (2011)

    Article  Google Scholar 

  2. Rounaghi, G.H., Mohammad Zade Kakhki, R.: Thermodynamic study of complex formation between dibenzo-18-crown-6 and UO2 2+ cation in different non-aqueous binary solutions. J. Incl. Phenom. Macrocycl. Chem. 63, 117–122 (2009)

    Article  CAS  Google Scholar 

  3. Rounaghi, G.H., Zavar, M.H., Mohammad Zadeh Kakhki, R.: Thermodynamic Behaviour of Complexation Process Between DB18C6with K+, Ag+, NH4+ and Hg2+ cations in ethylacetate-dimethylformamide binary media. Russ. J. Coord. Chem. 34, 167–171 (2008)

    Article  CAS  Google Scholar 

  4. Rounaghi, G.H., Mohajeri, M., Soruri, F., Mohamadzadeh Kakhki, R.: Solvent influence upon complex formation between dibenzo-18-crown-6 with the Y3+ metal cation in pure and binary mixed organic solvents. J. Chem. Eng. Data 56, 2836–2840 (2011)

    Article  CAS  Google Scholar 

  5. Razghandi, F., Rounaghi, Gh, Mohammadzadeh Kakhki, R.: Complexation study of dibenzo-18-crown-6 with UO2 2+ cation in binary mixed non-aqueous solutions. J. Incl. Phenom. Macrocycl. Chem. (2011). doi:10.1007/s10847-011-0053-0

    Google Scholar 

  6. Rounaghi, G.H., Mohajeri, M., Atashi, Z.: Conductometric study of complexation reaction between 15-crown-5 and Cr3+, Mn2+ and Zn2+ metal cations in pure and binary mixed organic solvent. J. Incl. Phenom. Macrocycl. Chem. (2011). doi:10.1007/s10847-011-0081-9

    Google Scholar 

  7. Mohamadzadeh kakhki, R.: Application of crown ethers as stationary phase in the chromatographic methods. J. Incl. Phenom. Macrocycl. Chem. (2012). doi:10.1007/s10847-012-0158-0

    Google Scholar 

  8. Belardi, R.P., Pawliszyn, J.: The application of chemically modified fused silica fibers in the extraction of organics from water matrix samples and their rapid transfer to capillary columns. Water Pollut. Res. J. Can. 24, 179–191 (1989)

    CAS  Google Scholar 

  9. Arthur, C.L., Pawliszyn, J.: Solid phase microextraction with thermal desorption using fused silica optical fibers. J. Anal. Chem. 62, 2145–2148 (1990)

    Article  CAS  Google Scholar 

  10. Perez-Trujillo, J.P., Frias, S., Conde, J.E., Roderiguez-Delgao, M.A.: Comparison of different coatings in solid-phase microextraction for the determination of organochlorine pesticides in ground wáter. J. Chromatogr. A 963, 95–105 (2002)

    Article  CAS  Google Scholar 

  11. Lopez, F.J., Pitarch, E., Egea, S., Beltran, J., Hernandez, F.: Gas chromatographic determination of organochlorine and organophosphorus pesticides in human fluids using solid phase microextraction. Anal. Chim. Acta 433, 217–226 (2001)

    Article  CAS  Google Scholar 

  12. Chong, S.L., Wang, D.X., Hayes, J.D., Wilhite, B.W., Malik, A.: Sol-gel Coating Technology for the preparation of solid-phase microextraction fibers of enhanced thermal stability. Anal. Chem. 69, 3889–3898 (1997)

    Article  CAS  Google Scholar 

  13. Wang, Z.Y., Xiao, C.H., Wu, C.Y., Han, H.M.: High-performance polyethylene glycol-coated solid-phase microextraction fibers using sol-gel technology. J. Chromatogr. A 89, 157–168 (2000)

    Google Scholar 

  14. Yu, J.X., Dong, L., Wu, C.Y., Wu, L., Xing, J.: Hydroxyfullerene as a novel coating for solid phase microextraction fiber with sol-gel technology. J. Chromatogr. A 978, 37–48 (2002)

    Article  CAS  Google Scholar 

  15. Zeng, Z., Qiu, W., Huang, Z.: Solid-phase microextraction using fused-silica fibers coated with sol-gel-derived hydroxy-crown ether. Anal. Chem. 73, 2429–2436 (2001)

    Article  CAS  Google Scholar 

  16. Jianxin, Yu., Caiying, Wu, Xing, Jun: Development of new solid-phase microextraction fibers by sol–gel technology for the determination of organophosphorus pesticide multiresidues in food. J. Chromatogr. A 1036, 101–111 (2004)

    Article  Google Scholar 

  17. Zhaorui, Z., Wenli, Q., Huang, X., Zaifu, H.: Solid-phase microextraction using stationary phase for capillary gas chromatography. Anal. Sci. 8, 851–854 (2000)

    Google Scholar 

  18. US Environmental Protection Agency, National Survey of Pesticide in Drinking Water Wells, Phase Report EPA 570 9-91-0-021. National Technical Information Service, Springfield, VA, 1992

  19. Buchholz, K.D., Pawliszyn, J.: Determination of phenols by solid-phase microextraction and gas chromatographic analysis. J. Environ. Sci. Technol. 27, 2844–2848 (1993)

    Article  CAS  Google Scholar 

  20. Zeng, Zhaorui, Qiu, Wenli, Yang, Min, Wei, Xuan, Huang, Zaifu, Li, Fang: Solid-phase microextraction of monocyclic aromatic amines using novel fibers coated with crown ether. J. Chromatogr. A 934, 51–57 (2001)

    Article  CAS  Google Scholar 

  21. Weber, E., Vogtle, F.: Ligand Structure and Complexation, V. New crown ethers and their alkali metal ion. Complexes. Chem. Ber. 109, 1803–1831 (1976)

    Article  CAS  Google Scholar 

  22. Yun, Lei: High extraction efficiency solid-phase microextraction fibers coated with open crown ether stationary phase using sol-gel technique. Anal. Chim. Acta 486, 63–72 (2003)

    Article  CAS  Google Scholar 

  23. Cai, L., Gong, S., Chen, M., Caiying, W.: Vinyl crown ether as a novel radical crosslinked sol–gel SPME fiber for determination of organophosphorus pesticides in food samples. Anal. Chim. Acta 559, 89–96 (2006)

    Article  CAS  Google Scholar 

  24. Wang, Danhua, Xing, Jun, Peng, Jiagang, Caiying, Wu: Novel benzo-15-crown-5 sol–gel coating for solid-phase microextraction. J. Chromatogr. A 1005, 1–12 (2003)

    Article  CAS  Google Scholar 

  25. Zhou, Xin, Xie, P.-F., Wang, J., Zhang, B.-B., Liu, M.-M., Liu, H.-L., Feng, X.-H.: Preparation and characterization of novel crown ether functionalized ionic liquid-based solid-phase microextraction coatings by sol–gel technology. J. Chromatogr. A 1218, 3571–3580 (2011)

    Article  CAS  Google Scholar 

  26. Ebrahimzadeh, H., Yamini, Y., Gholizade, A., Sedighi, A., Kasraee, S.: Determination of fentanyl in biological and water samples using single-drop liquid–liquid–liquid microextraction coupled with high-performance liquid chromatography. Anal. Chim. Acta 626, 193–199 (2008)

    Article  CAS  Google Scholar 

  27. Tao, Y., Liu, J.F., Wang, T., Jiang, G.B.: Simultaneous conduction of two- and three-phase hollow-fiber-based liquid-phase microextraction for the determination of aromatic amines in environmental water samples. J. Chromatogr. A 1216, 756–762 (2009)

    Article  CAS  Google Scholar 

  28. Sarafraz Yazdi, A., Es’haghi, Z.: Two-step hollow fiber-based, liquid-phase microextraction combined with high-performance liquid chromatography: A new approach to determination of aromatic amines in water. J. Chromatogr. A 1082, 136–142 (2005)

    Article  Google Scholar 

  29. Zhu, L., Tay, C.B., Lee, H.K.: Liquid–liquid–liquid microextraction of aromatic amines from water samples combined with high-performance liquid chromatography. J. Chromatogr. A 963, 231–237 (2002)

    Article  CAS  Google Scholar 

  30. Sarafraz Yazdi, A., Es’haghi, Z.: Liquid–liquid–liquid phase microextraction of aromatic amines in water using crown ethers by high-performance liquid chromatography with monolithic column. Talanta 66, 664–669 (2005)

    Article  Google Scholar 

  31. Rosete-Luna, S., Medrano, F., Bernal-Uruchurtu, M.I., Godoy-Alcántar, C.: Crown ether ditopic receptors for ammonium salts with high affinity for amino acid ester salts. J. Mex. Chem. Soc. 53, 209–219 (2009)

    CAS  Google Scholar 

  32. Ashton, P.R., Chrystal, E.J.T., Glink, P.T., Menzer, S., Schiavo, C., Spencer, N., Stoddart, J.F., Tasker, P.A., White, A.J.P., Williams, D.J.: Pseudorotaxanes formed between secondary dialkylammonium salts and crown ethers. Chem. Eur. J. 2, 709–728 (1996)

    Article  CAS  Google Scholar 

  33. Oka, H., Ito, Y., Matsumoto, H.: Chromatographic analysis of tetracycline antibiotics in foods. J. Chromatogr. A 882, 109–133 (2000)

    Article  CAS  Google Scholar 

  34. Vanias, P., Balsalobre, N., Lopez-Erroz, C., Hernandez-Codoba, M.: Liquid chromatography with ultraviolet absorbance detection for the analysis of tetracycline residues in honey. J. Chromatogr. A 1022, 125–129 (2004)

    Article  Google Scholar 

  35. Borwankar, R.P., Wasan, D.T.: Effects of surfactants on interphase solute transport: a theory of interfacial resistance. Ind. Eng. Chem. Fundam. 25, 662–668 (1986)

    Google Scholar 

  36. Limian, Z., Limian, Z., Lee, H.K.: Analysis of aromatic amines in water samples by liquid–liquid–liquid microextraction with hollow fibers and high-performance liquid chromatography. J. Chromatogr. A 963, 239–248 (2002)

    Article  Google Scholar 

  37. Buschmann, H.J., Mutihac, L., Jansen, K., Schollmeyer, E.: Self-complexation of aminobenzo crown others. An. Quim. Int. Ed. 94, 211–213 (1998)

    CAS  Google Scholar 

  38. Sarafraz-Yazdi, A., Mofazzeli, F., Es’haghi, Z.: A new high-speed hollow fiber based liquid phase microextraction method using volatile organic solvent for determination of aromatic amines in environmental water samples prior to high-performance liquid chromatography. Talanta 79, 472–478 (2009)

    Article  CAS  Google Scholar 

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  1. Department of Chemistry, Faculty of Sciences, University of Zabol, Zabol, Iran

    Roya Mohammadzadeh kakhki

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  1. Roya Mohammadzadeh kakhki
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Correspondence to Roya Mohammadzadeh kakhki.

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Mohammadzadeh kakhki, R. Recent developments in microextraction techniques based on crown ethers. J Incl Phenom Macrocycl Chem 76, 253–261 (2013). https://doi.org/10.1007/s10847-012-0256-z

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  • DOI: https://doi.org/10.1007/s10847-012-0256-z

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