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Cyclodextrin-intercalated layered double hydroxides for fragrance release

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Abstract

In order to attain the controlled release of fragrance, the intercalation of cyclodextrins (CDs) and fragrance in layered double hydroxides (LDHs) was examined. Carboxymethyl-β-CDs (CMCDs) of various degrees of substitution as well as Mg–Al support were synthesized. CMCDs were intercalated into LDH by the reconstruction method. Powder X-ray diffraction, thermal gravimetric analyses and Fourier transform infrared indicated a successful intercalation of CMCDs into the LDH gallery. The retention capacities of the hybrid materials were investigated in aqueous phase and in gaseous solution by static headspace gas chromatography and multiple headspace extraction. The functionalization of the LDH with CMCD allowed the encapsulation of various organic guests and could prolong the fragrance release time in comparison to that from LDH without CMCD, which can be attributed to the inclusion of the fragrance compound in the CMCD cavity.

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Abbreviations

β-CD:

β-Cyclodextrin

CDs:

Cyclodextrins

CMCD:

Carboxymethyl-β-cyclodextrin

DS:

Degree of substitution

FT-IR:

Fourier transform infrared

LDH:

Layered double hydroxides

MHE:

Multiple headspace extraction

SHGC:

Static headspace gas chromatography

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Acknowledgments

UCEIV participates in the Institut de Recherche en ENvironnement Industriel (IRENI) which is financed by the Communauté Urbaine de Dunkerque, the Région Nord Pas-de-Calais, the Ministère de l’Enseignement Supérieur et de la Recherche, the CNRS and European Regional Development Fund (ERDF).

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Authors and Affiliations

  1. Univ Lille Nord de France, 59000, Lille, France

    A. Ciobanu, S. Ruellan, I. Mallard, D. Landy, C. Gennequin, S. Siffert & S. Fourmentin

  2. ULCO, UCEIV, 59140, Dunkerque, France

    A. Ciobanu, S. Ruellan, I. Mallard, D. Landy, C. Gennequin, S. Siffert & S. Fourmentin

  3. University Vasile Alecsandri, 600115, Bacau, Romania

    A. Ciobanu

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  1. A. Ciobanu
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  2. S. Ruellan
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  3. I. Mallard
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  4. D. Landy
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  5. C. Gennequin
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  6. S. Siffert
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  7. S. Fourmentin
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Correspondence to S. Fourmentin.

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Ciobanu, A., Ruellan, S., Mallard, I. et al. Cyclodextrin-intercalated layered double hydroxides for fragrance release. J Incl Phenom Macrocycl Chem 75, 333–339 (2013). https://doi.org/10.1007/s10847-012-0227-4

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  • DOI: https://doi.org/10.1007/s10847-012-0227-4

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