Skip to main content
SpringerLink
Log in

Conductometric study of complexation reaction between 15-crown-5 and Cr3+, Mn2+ and Zn2+ metal cations in pure and binary mixed organic solvents

  • Original Article
  • Published:
Journal of Inclusion Phenomena and Macrocyclic Chemistry Aims and scope Submit manuscript

Abstract

The stability constants (Kf) for the complexation reactions of Cr3+, Mn2+ and Zn2+ metal cations with macrocyclic ligand, 15-crown-5 (15C5), in acetonitrile (AN), ethanol (EtOH) and also in their binary solutions (AN–EtOH) were determined at different temperatures, using conductometric method. 15C5 forms 1:1 complexes with Cr3+, Mn2+ and Zn2+ cations in solutions. A non-linear behaviour was observed for changes of logKf of the metal ion complexes versus the composition of the mixed solvent. The order of stability of the metal–ion complexes in pure AN and in a binary solution of AN–EtOH (mol% AN = 52) at 25 °C was found to be: (15C5Zn)2+ > (15C5·Mn)2+ > (15C5·Cr)3+, but in the case of pure EtOH at the same temperature, it changes to: (15C5·Zn)2+ > (15C5·Cr)3+ > (15C5·Mn)2+. The results also show that the stability sequence of the complexes in the other binary solutions of AN–EtOH (mol% AN = 26 and mol% AN = 76) varies in order: (15C5·Cr)3+ ~ (15C5·Zn)2+ > (15C5·Mn)2+. The values of the standard thermodynamic quantities (ΔHC°, ΔSC°) for formation of (15C15-Cr3+), (15C5-Mn2+) and (15C5-Zn2+) complexes were obtained from the temperature dependence of the stability constants and the results show that the thermodynamics of complexation reactions is affected by nature and composition of the solvent systems and in most solution systems, the complexes are enthalpy stabilized but entropy destabilized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Pedersen, C.J.: J. Am. Chem. Soc. 89, 7071 (1967)

    Google Scholar 

  2. Hancock, R.D., Martell, A.E.: Chem. Rev. 89, 1875 (1989)

    Article  CAS  Google Scholar 

  3. Izatt, R.M., Pawlak, K., Bradshaw, J.S., Bruening, R.L.: Chem. Rev. 95, 2529 (1995)

    Article  CAS  Google Scholar 

  4. Rounaghi, G.H., Mohajeri, M., Ashrafi, Sh., Ghasemi, H., Sedaghat, S.: J. Inc. Phenom. Macrocycl. Chem. 58, 1 (2007)

    Article  CAS  Google Scholar 

  5. Rounaghi, G.H., Arbab Zavvar, M.H., Badiee, K., Boosaidi, F., Kazemi, M.S.: J. Inc. Phenom. Macrocycl. Chem. 59, 363 (2007)

    Article  CAS  Google Scholar 

  6. Hiraoka, M.: Crown compounds: their characteristics and applications, kodansha, Tokyo and Elsevier, Amsterdam (1982)

  7. Singh, L.P., Bhatnagar, J.M., Tanaka, S., Tsu, H., Mori, M.: Anal. Chim. Acta 546, 199 (2005)

    Article  CAS  Google Scholar 

  8. Jaylakshmi, M., Radhika, P., Rao, M.M.: J. Power Source 158, 801 (2006)

    Article  Google Scholar 

  9. Tsurubou, S., Mizatani, M., Kodota, Y.: Anal. Chem. 67, 1465 (1995)

    Article  CAS  Google Scholar 

  10. Wienk, M.M., Stowijk, T.B., Reinhoudt, D.N.: J. Am. Chem. Soc. 112, 797 (1990)

    Article  CAS  Google Scholar 

  11. Yuan, K., Jiazan, N.: J. Nucl. Radiochem. 05, 146 (1983)

    Google Scholar 

  12. Dail, S., Juy, H., Banes, C.E.: J. Chem. Soc. Dalton Trans. 1201 (1999)

  13. Cai, L., Gong, S., Chen, M., Wu, C.: Anal. Chim. Acta 559, 89 (2006)

    Article  CAS  Google Scholar 

  14. Kim, D.W., Jean, Y.S., Jean, Y.K., Suh, M.Y., Joe, K.S.: J. Radioanal. Nucl. Chem. 189, 219 (1995)

    Article  CAS  Google Scholar 

  15. Ban, Y., Nomura, M., Fujii, Y.: J. Nucl. Sci. Technol. 39, 279 (2002)

    CAS  Google Scholar 

  16. Ding, X., Nomura, M., Suzuki, T., Sugiyama, Y., Kaneshiki, T., Fujii, Y.: J. Chromatogr. A 1113, 182 (2006)

    Article  CAS  Google Scholar 

  17. Blair, T.L., Cynkowski, T., Bachas, L.G.: Anal. Chem. 65, 945 (1993)

    Article  CAS  Google Scholar 

  18. Chen, Z., Echegoyen, L.: J. Phys. Org. Chem. 5, 711 (1992)

    Article  CAS  Google Scholar 

  19. Kohn, R., Riest, D., Fleckenstein, B., Wiesmuller, K.H.: J.Chromatogr. A 716, 371 (1995)

    Article  Google Scholar 

  20. Yoshio, M., Noguchi, H.: Anal. Lett. 15, 1197 (1982)

    Article  CAS  Google Scholar 

  21. Mehta, H.S., Parikh, V.B., Pal, U., Menon, S.K.: J. Fluorine Chem. 127, 1228 (2006)

    Article  CAS  Google Scholar 

  22. Rounaghi, G.H., Mohammad Zade Kakhki, R.: J. Inc. Phenom. Macrocycl. Chem. 63, 117 (2009)

    Article  CAS  Google Scholar 

  23. Rounaghi, G.H., Zavar, M.H., Mohammad Zadeh Kakhki, R.: Russ. J. Coord. Chem. 34, 167 (2008)

    Article  CAS  Google Scholar 

  24. Genplot, Computer Graphic Service, USA (1989)

  25. Rounaghi, G.H., Eshaghi, Z., Ghiamati, E.: Talanta 44, 275 (1997)

    Article  CAS  Google Scholar 

  26. Chen, L., Bos, M., Grootenhuis, P.D.J., Christenhusz, A., Hoogendam, E., Reinhoudt, D.N., Van Der Linden, W.E.: Anal. Chim. Acta 201, 117–125 (1987)

    Article  CAS  Google Scholar 

  27. Ijeri, V.S., Srivastava, A.K.: Eur. J. Inorg. Chem. 943–947 (2001)

  28. Ijeri, V.S., Srivastava, A.K.: Polyhedron 22, 569–574 (2003)

    Article  CAS  Google Scholar 

  29. Gutmann, V.: Coordination chemistry in non-aqueous solutions. Springer, New York (1968)

    Book  Google Scholar 

  30. Cavgun, N.V., Zaitseva, I.S., Kabakova, E.N., Bodarew, N.V.: Russ. J. Gener. Chem. 68, 1209 (1988)

    Google Scholar 

  31. Mosier-Boss, P.A.: Spectrochim. Acta A 61, 527 (2005)

    Article  CAS  Google Scholar 

  32. Gordon, A.J., Ford, R.A.: The Chemist’s Companion. A Handbook Of Practical Data, Techniques And References. Wiley, New York (1972)

    Google Scholar 

  33. Rounaghi, G.H., Mohajeri, M., Ashrafi, Sh.: J. Incl. Phenom. Macrocycl. Chem. 58, 1 (2007)

    Article  CAS  Google Scholar 

  34. Ansarifard, M., Rounaghi, G.H.: J. Incl. Phenom. Macrocycl. Chem. 52, 39 (2005)

    Article  CAS  Google Scholar 

Download references

Acknowledgment

The authors gratefully acknowledge the support of this work by Islamic Azad University of Mashhad, Mashhad Branch, Mashhad, Iran.

Author information

Authors and Affiliations

  1. Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

    Gholamhossein Rounaghi, Massoumeh Mohajeri, Zahra Atashi & Roya Mohammadzadeh kakhki

Authors
  1. Gholamhossein Rounaghi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Massoumeh Mohajeri
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zahra Atashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Roya Mohammadzadeh kakhki
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Gholamhossein Rounaghi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rounaghi, G., Mohajeri, M., Atashi, Z. et al. Conductometric study of complexation reaction between 15-crown-5 and Cr3+, Mn2+ and Zn2+ metal cations in pure and binary mixed organic solvents. J Incl Phenom Macrocycl Chem 73, 435–441 (2012). https://doi.org/10.1007/s10847-011-0081-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10847-011-0081-9

Keywords

Search

Navigation