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Double clathrate hydrates of cross-linked tetrabutylammonium polyacrylate and noble gases at high pressures

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Abstract

Temperatures of hydrate decomposition were measured by means of the differential thermal analysis at a pressures up to 800–900 Mpa in the systems: cross-linked tetrabutylammonium polyacrylate–water and cross-linked tetrabutylammonium polyacrylate–water–noble gas (He, Ne, Ar, Kr, Xe). The effect of the deformation of D- cavities of the hydrates on the temperature of their decomposition is discussed on the basis of the experimental data.

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References

  1. Jeffrey, G.A.: Hydrate inclusion compounds. In: Atwood, J.L., Davies, J.E.D., MacNicol, D.D., Vogtle, F. (eds.) Comprehensive Supramolecular Chemistry, vol. 6, pp. 757–788. Pergamon Press, Oxford (1996)

    Google Scholar 

  2. Dyadin, Y.A., Udachin, K.A.: Clathrate polyhydrates of peralkylonium salts and their analogs. J. Struct. Chem. 28(3), 394–432 (1987)

    Article  Google Scholar 

  3. Bogatyryov, V.L.: Clathrate-forming ion exchangers. In: Muraviev, D., Gorshkov, V., Warshawsky, W. (eds.) Ion Exchange, vol. 1, p. 223. Marcel Dekker, New York (1998)

    Google Scholar 

  4. Terekhova, I.S., Bogatyryov, V.L., Dyadin, Yu.A.: Clathrate hydrates of cross-linked tetraisoamylammonium polyacrylates. J. Supramol. Chem. 2, 393–399 (2002)

    Article  CAS  Google Scholar 

  5. Nakayama, H.: Hydrates of organic compounds. XIII. The confirmation of the formation of clathrate-like hydrates of tetrabutylammonium and of tetraisopentylammonium polyacrylates. Bull. Chem. Soc. Jpn. 60, 2319–2326 (1987)

    Article  CAS  Google Scholar 

  6. Bella, J., Brodsky, B., Berman, H.: Hydration structure of a collagen peptide. Structure 3(9), 893–906 (1995)

    Article  CAS  Google Scholar 

  7. Nakasako, M.: Structural characteristics in protein hydration investigated by cryogenic X-ray crystal structure analyses. J. Biolog. Phys. 28, 129–137 (2002)

    Article  CAS  Google Scholar 

  8. Shataeva, L.K., Kuznetsova, N.N., El’kin, G.E.: Karboxyl’nye kationity v biologii (The use of Carboxylic Cation-Exchange Resins in Biology). Nauka, Leningrad (1979). (in Russian)

    Google Scholar 

  9. Chapoy, A., Anderson, R., Tohidi, B.: Low pressure molecular hydrogen storage in semi-clathrate hydrates of quaternary ammonium compounds. J. Am. Chem. Soc. 129, 746–747 (2007)

    Article  CAS  Google Scholar 

  10. Skiba, S.S., Terekhova, I.S., Larionov, E.G., Manakov, A.Y.: Incorparation of gas molecules into the frameworks of clathrate hydrates of ion-exhange resins in tetraalkylammonium form. Mendeleev Commun. 18, 126–127 (2008)

    Article  CAS  Google Scholar 

  11. Terekhova, I.S., Manakov, A.Yu., Feklistov, V.V., Dyadin, Yu.A., Komarov, V.Yu., Naumov, D.Yu.: X-ray powder diffraction studies of polyhydrates of cross-linked tetraisoamylammonium polyacrylates. J. Incl. Phenom. Macro. Chem. 52, 207–211 (2005)

    Article  CAS  Google Scholar 

  12. Udachin, K.A., Ripmeester, J.A.: A polymer guest transforms clathrate cages into channels: the single-crystal X-ray structure of tetra-n-butylammonium polyacrylate hydrate, nBu4NPA·40 H2O. Angew. Chem. Int. Ed. 38(13/14), 1983–1984 (1999)

    Article  CAS  Google Scholar 

  13. Soldatov, D.V., Suwinska, K., Terekhova, I.S., Manakov, A.Y.: Structural study of hydrate compounds of polyacrylate resins in tetraisoamylammonium form. crystal structure of a clathrate hydrate of linear polyacrylate in tetraisoamylammonium form. J. Struct. Chem. 49(4), 712–718 (2008)

    Article  CAS  Google Scholar 

  14. Glew, D.N., Mak, H.D., Rath, N.S.: Aqueous non-electrolyte solutions: Part VII. Water shell stabilization by interstitial nonelectrolytes. In: Covington, A.K., Jones, P. (eds.) Hydrogen-Bonded Solvent Systems, pp. 185–193. Taylor & Francis Ltd, London (1968)

    Google Scholar 

  15. Dyadin, Y.A., Larionov, E.G., Manakov, A.Y., Zhurko, F.V.: Double clathrate hydrate of tetrahydrofuran and xenon at pressures up to 15 kbar. Mendeleev Commun. 2, 80–81 (1999)

    Article  Google Scholar 

  16. Dyadin, A.Yu., Larionov, E.G., Mirinskij, D.S., Mikina, T.V., Aladko, E.Ya., Starostina, L.I.: Phase diagram of the Xe-H2O system up to 15 kbar. J. Incl. Phenom. 28, 271–285 (1997)

    Article  CAS  Google Scholar 

  17. Dyadin, Yu.A., Larionov, E.G., Mikina, T.V., Starostina, L.I.: Clathrate hydrate of xenon at high pressure. Mendeleev Commun. 6, 44–45 (1996)

    Article  Google Scholar 

  18. Dyadin, A.Yu., Zelenin, Yu.M., Bezuglov, S.G., Bondaryuk, I.V.: Clathrate hydrates and phase diagram of the system water-acetone under pressure to 10 kbar. Izv Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk 7, 70 (1978)

    Google Scholar 

  19. Larionov, E.G., Manakov, A.Y., Zhurko, F.V., Dyadin, Y.A.: Double clathrate hydrate CS-II at pressures up to 15 kbar. J. Struct. Chem. 41(3), 476–482 (2000)

    Article  CAS  Google Scholar 

  20. Larionov, E.G., Zhurko, F.V., Dyadin, Y.A.: Gas-hydrate packing and stability at high pressures. J. Struct. Chem. 43(6), 985–989 (2002)

    Article  CAS  Google Scholar 

  21. Batsanov, S.S.: Atomic radii of elements. Zhurnal Neorganicheskoi Khimii 36(12), 3015–3047 (1991)

    CAS  Google Scholar 

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Acknowledgements

This work was financially supported by the Integration project of the Presidium of SB RAS No 62.

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Authors and Affiliations

  1. A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrent’ev Av. 3, 630090, Novosibirsk, Russian Federation

    E. Ya. Aladko, E. G. Larionov, A. Yu. Manakov & I. S. Terekhova

  2. Novosibirsk State University, Pirogova Str. 2, Novosibirsk, 630090, Russian Federation

    A. Yu. Manakov

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  1. E. Ya. Aladko
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  2. E. G. Larionov
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  3. A. Yu. Manakov
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  4. I. S. Terekhova
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Correspondence to E. G. Larionov.

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Aladko, E.Y., Larionov, E.G., Manakov, A.Y. et al. Double clathrate hydrates of cross-linked tetrabutylammonium polyacrylate and noble gases at high pressures. J Incl Phenom Macrocycl Chem 67, 13–18 (2010). https://doi.org/10.1007/s10847-009-9662-2

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  • DOI: https://doi.org/10.1007/s10847-009-9662-2

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