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Efficient fluoride-selective receptor: experiment and theory

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Abstract

A novel artificial receptor, (3′-nitrobenzo)[2,3-d]-(3′′-nitrobenzo)[9,10-d]-1,4,8,11-tetraazacyclotetradecane-5,7,12,14-tetraone, has been synthesized and shows high selective and recognitive ability for F- among F−, Cl−, Br−, AcO−, H2PO −4 by UV-vis and 1H NMR titration experiments. Theoretical investigations suggest that the fluoride selectivity among various anions comes from the fact that the fluoride approaches much closer to the amide protons than other anions located above the cavity. The interaction energies support the large binding ability difference between F− and Cl−/Br−/AcO−/H2PO −4 .

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Acknowledgement

This work was supported by a project 20371028 from the National Natural Science Foundation of China and a project 023605811 from the Natural Science Foundation of Tianjin.

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, P.R. China

    Xue-Fang Shang, Xiu-Fang Xu, Jie Shao & Hua-Kuan Lin

  2. State Key Laboratory of Functional Polymer Materials for Absorption and Separation, Nankai University, Tianjin, 300071, P.R. China

    Hai Lin

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  1. Xue-Fang Shang
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  2. Xiu-Fang Xu
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  3. Hai Lin
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  4. Jie Shao
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  5. Hua-Kuan Lin
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Correspondence to Hua-Kuan Lin.

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Shang, XF., Xu, XF., Lin, H. et al. Efficient fluoride-selective receptor: experiment and theory. J Incl Phenom Macrocycl Chem 58, 275–281 (2007). https://doi.org/10.1007/s10847-006-9154-6

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  • DOI: https://doi.org/10.1007/s10847-006-9154-6

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