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Catalytic activity of carbon-sphere/Co3O4/RuO2 nanocomposite for Li-air batteries

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Abstract

A carbon-sphere/Co3O4/RuO2 nanocomposite was fabricated as part of a new approach to develop advanced Li–air batteries. The nanocomposite showed homogeneously dispersed Co3O4 and RuO2 nanoparticles on the surface of carbon spheres, whose shape was effective in increasing the catalytic surface area and enhancing the stability of carbon and the catalyst. A high discharge capacity, relatively stable reversibility, and low overpotential were observed in electrochemical tests of an electrode containing this carbon-sphere/Co3O4/RuO2 nanocomposite. The results showed that the nanocomposite can be introduced as a promising catalyst in Li–air cells.

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References

  1. H.G. Song, S.B. Kim, Y.J. Park, J. Electroceram. 29, 163 (2012)

    Article  CAS  Google Scholar 

  2. H.-S. Kim, M. Kong, K. Kim, I.-J. Kim, H.-B. Gu, J. Electroceram. 23, 219 (2009)

    Article  CAS  Google Scholar 

  3. J.-H. Lee, Y.-M. Choi, U. Paik, J.-G. Park, J. Electroceram. 17, 657 (2006)

    Article  CAS  Google Scholar 

  4. T. Ohzuku, R.J. Brodd, J. Power Sources 174, 449 (2007)

    Article  CAS  Google Scholar 

  5. C.G. Son, D.R. Chang, H.S. Kim, Y.S. Lee, J Electrochemical Electrochem Sci Technol 2, 103 (2011)

    Article  CAS  Google Scholar 

  6. H.G. Song, J.Y. Kim, Y.J. Park, Electrochim. Acta 56, 6896 (2011)

    Article  CAS  Google Scholar 

  7. S. Ahn, H.-S. Kim, S. Yang, J.Y. Do, B.H. Kim, K. Kim, J. Electroceram. 23, 289 (2009)

    Article  CAS  Google Scholar 

  8. H.J. Lee, K.S. Park, Y.J. Park, J. Power Sources 195, 6122 (2010)

    Article  CAS  Google Scholar 

  9. K.M. Shaju, P.G. Bruce, J. Power Sources 174, 1201 (2007)

    Article  CAS  Google Scholar 

  10. M.S. Park, S.H. Hyun, S.C. Nam, J. Electroceram. 17, 651 (2006)

    Article  CAS  Google Scholar 

  11. H.G. Song, Y.J. Park, Mater Res Bull 47, 2843 (2012)

    Article  CAS  Google Scholar 

  12. Y.-U. Park, R.A. Shakoor, K.Y. Park, K. Kang, J Electrochem Sci Technol 2, 14 (2011)

    Article  CAS  Google Scholar 

  13. J.-M. Kim, J.-H. Jeong, B.-S. Jin, H.-S. Kim, J Electrochem Sci Technol 2, 97 (2011)

    Article  Google Scholar 

  14. S. Kim, J.K. Noh, S.H. Yu, W. Chang, K.Y. Chung, B.W. Cho, J. Electroceram. 30, 159 (2013)

    Article  CAS  Google Scholar 

  15. H.J. Jeon, C.S. Kang, G.W. Yoo, C. Kim, J.T. Son, J. Electroceram. 30, 172 (2013)

    Article  CAS  Google Scholar 

  16. J.W. Shin, J.H. Ryu, J. Jeong, D.H. Yoon, J. Electroceram. 28, 178 (2012)

    Article  CAS  Google Scholar 

  17. T. Ogasawara, A. Débart, M. Holzapfel, P. Novák, P.G. Bruce, J. Am. Chem. Soc. 128, 1390 (2006)

    Article  CAS  Google Scholar 

  18. A. Débart, A.J. Paterson, J. Bao, P.G. Bruce, Angew. Chem. Int. Ed. 47, 4521 (2008)

    Article  Google Scholar 

  19. F. Jiao, P.G. Bruce, Adv. Mater. 19, 657 (2007)

    Article  CAS  Google Scholar 

  20. R. Padbury, X. Zhang, J. Power Sources 196, 4436 (2011)

    Article  CAS  Google Scholar 

  21. A. Kraytsberg, Y. E-Eli, J. Power Sources 196, 886 (2011)

    Article  CAS  Google Scholar 

  22. J.S. Lee, S.T. Kim, R. Cao, N.S. Choi, M. Liu, K.T. Lee, J. Cho, Adv. Energy Mater. 1, 34 (2011)

    Article  CAS  Google Scholar 

  23. A. Débart, J. Bao, G. Armstrong, P.G. Bruce, J. Power Sources 174, 1177 (2007)

    Article  Google Scholar 

  24. X. Wang, L. Yu, X.L. Wu, F. Yuan, Y.G. Guo, Y. Ma, J. Yao, J. Phys. Chem. C 113, 15553 (2009)

    Article  CAS  Google Scholar 

  25. T.H. Yoon, Y.J. Park, Nanoscale Res. Lett. 7, 28 (2012)

    Article  Google Scholar 

  26. F. Teng, W. Yao, Y. Zheng, Y. Ma, T. Xu, G. Gao, S. Liang, Y. Teng, Y. Zhu, Talanta 76, 1058 (2008)

    Article  CAS  Google Scholar 

  27. K.S. Kim, Y.J. Park, Nanoscale Res. Lett. 7, 47 (2012)

    Article  Google Scholar 

  28. T.H. Yoon, Y.J. Park, J. Power Sources, on line publication (2013)

  29. H.G. Jung, J. Hassoun, J.B. Park, Y.K. Sun, B. Scrosati, Nat. Chem. 4, 579 (2012)

    Article  CAS  Google Scholar 

  30. C. Laoire, S. Mukerjee, E.J. Plichta, M.A. Hendrickson, K.M. Abraham, J. Electrochem. Soc. 158, 302 (2011)

    Article  Google Scholar 

  31. B.D. McCloskey, D.S. Bethune, R.M. Shelby, G. Girishkumar, A.C. Luntz, J. Phys. Chem. Lett. 2, 1161 (2011)

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the National Research Foundation of Korea Grant funded by the Korean Government(MEST) (NRF-2009-C1AAA001-0094219) and a basic research program (11_EN-03) through the Daegu-Gyeongbuk Institute of Science and Technology (DGIST) funded by the Ministry of Education, Science and Technology (MEST). This work was also supported by Kyonggi University's Graduate Research Assistantship 2012.”

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Correspondence to Yong Joon Park.

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Park, C.S., Kim, J.H. & Park, Y.J. Catalytic activity of carbon-sphere/Co3O4/RuO2 nanocomposite for Li-air batteries. J Electroceram 31, 224–230 (2013). https://doi.org/10.1007/s10832-013-9831-y

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  • DOI: https://doi.org/10.1007/s10832-013-9831-y

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