Abstract
One of the most attractive features of solid oxide fuel cells is their flexibility for fuels so that internal reforming and/or simple external reforming may be possible. In this study, equilibria in various possible fuel gases are considered, and C–H–O diagrams are constructed. Power generation characteristics for these fuels are measured and compared with those for simulated reformed gas in equilibrium compositions. We have succeeded to demonstrate direct-alcohol SOFCs for e.g. methanol, ethanol, and propanol. Mixtures of CH4 and CO2 are used as simulated biogas, and iso-octane (C8H18) and n-dodecane (C12H26) are highlighted as simulated gasoline and kerosene, respectively. Influence of fuel impurities on power generation characteristics is also discussed.
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References
B.C.H. Steele and A. Heinzel, Nature, 414, 345 (2001).
R. Craciun, S. Park, R.J. Gorte, J.M. Vohs, C. Wang, and W.L. Worrell, J. Electrochem. Soc., 144, 4019 (1999).
J. Larminie and A. Dicks, Fuel Cell Systems Explained (John Wiley & Sons, Chichester, 2000).
K. Sasaki and Y. Teraoka, J. Electrochem. Soc., 150(7), A878 (2003).
K. Sasaki and Y. Teraoka, J. Electrochem. Soc., 150(7), A885 (2003).
K. Sasaki and Y. Teraoka in Proc. 8th Intl. Symp. Solid Oxide Fuel Cells, Electrochem. Soc. Proc. (Electrochem. Soc., NJ Pennington 2003), Vol. 2003-07, p. 1225.
K. Sasaki and Y. Teraoka in Proc. 11th Symp. Solid Oxide Fuel Cells Japan, (SOFC Society of Japan, Tokyo, 2002), p. 45.
K. Sasaki and Y. Teraoka in 10th FCDIC Fuel Cell Symp. Proc. (Fuel Cell Development Information Center, Tokyo, 2003), p. 381.
K. Sasaki, H. Kojo, Y. Hori, R. Kikuchi, and K. Eguchi, Electrochemistry, 70(1), 18 (2002).
H. Yokokawa, N. Sakai, T. Kawada M. Dokiya in Proc. 2nd Intl. Symp. Solid Oxide Fuel Cells (Commission of European Communities, Brussels, 1991), p. 663.
H. Yokokawa, T. Horita N. Sakai M. Dokiya T. Kawada in Ceramic Interfaces Properties and Applications, (IOM Communications, London UK, 1998), p. 171.
K. Sasaki and J. Maier, J. Appl. Phys., 86(10), 5422 (1999).
K. Sasaki, J. Claus, and J. Maier, Solid State Ionics, 121, 51 (1999).
K. Sasaki, J.P. Wurth, R. Gschwend, M. Gödickemeier, and L.J. Gauckler, J. Electrochem. Soc., 143(2), 530 (1996).
K. Sasaki, K. Watanabe K. Shiosaki K. Susuki Y. Teraoka in Proc. 8th Intl. Symp. Solid Oxide Fuel Cells, Electrochem. Soc. Proc. (Electrochem. Soc., NJ Pennington 2003), Vol. 2003-07, p. 1295.
K. Sasaki, K. Watanabe, and Y. Teraoka, J. Electrochem. Soc., submitted.
K. Sasaki, K. Watanabe K. Shiosaki Y. Teraoka in 10th FCDIC Fuel Cell Symp. Proc. (Fuel Cell Development Information Center, Tokyo, 2003), p. 244.
K. Watanabe, K. Sasaki Y. Teraoka in Proc. 11th Symp. Solid Oxide Fuel Cells Japan (SOFC Society of Japan, Tokyo, 2002), p. 53.
K. Shiozaki, K. Sasaki Y. Teraoka in Proc. 11th Symp. Solid Oxide Fuel Cells Japan (SOFC Society of Japan, Tokyo, 2002), p. 64.
K. Sasaki, Y. Hori, R. Kikuchi, K. Eguchi, A. Ueno, H. Takeuchi, M. Aizawa, K. Tsujimoto, H. Tajiri, H. Nishikawa, and Y. Uchida, J. Electrochem. Soc., 149(3), A227 (2002).
K. Susuki, K. Sasaki, Y. Teraoka, K. Tsujimoto, and Y. Uchida, in 10th FCDIC Fuel Cell Symp. Proc. (Fuel Cell Development Information Center, Tokyo, 2003), p. 249.
K. Susuki, K. Sasaki, Y. Teraoka, K. Tsujimoto, and Y. Uchida, in Proc. 11th Symp. Solid Oxide Fuel Cells Japan (SOFC Society of Japan, Tokyo, 2002), p. 68.
K. Tsujimoto, Y. Uchida, K. Sasaki, K. Susuki, Y. Hori, Y. Teraoka, K. Eguchi, A. Ueno, K. Hiwatashi, and M. Aizawa, in Proc. 5th Europ. Solid Oxide Fuel Cell Forum (European Fuel Cell Forum, Luzern Switzerland, 2002), p. 1114.
K. Susuki, K. Sasaki, Y. Teraoka, K. Tsujimoto, and Y. Uchida, in 9th FCDIC Fuel Cell Symp. Proc. (Fuel Cell Development Information Center, 2002), p. 197.
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Sasaki, K., Watanabe, K., Shiosaki, K. et al. Multi-Fuel Capability of Solid Oxide Fuel Cells. J Electroceram 13, 669–675 (2004). https://doi.org/10.1007/s10832-004-5174-z
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DOI: https://doi.org/10.1007/s10832-004-5174-z