Quercetin and rutin upon adsorption on alumina were found to form colored chelate complexes with alumina surface groups similar to complexes with Al(III) ions in solution. The optical density of the alumina dispersion in the presence of these hydroxyflavones is greatest in neutral media and linearly dependent on their concentration in the initial solution. The conditional molar absorption coefficients of the surface quercetin (εS434 = 4386 g/(mole·cm)) and rutin complexes (εS403 = 5280 g/(mole·cm)) were determined. Highly dispersed alumina can be proposed as a solidphase reagent for the determination of quercetin and rutin in preparations of medicinal plants by a spectrophotometric or visual test method.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. Andersen and K. R. Markham, Flavonoids. Chemistry, Biochemistry and Applications, Boca Raton CRC Press, New York (2006).
A. Wach, K. Pyrzyska, and M. Biesaga, Food Chem., 100, No. 2, 699–704 (2007).
Ya. I. Yashin, V. Yu. Ryzhnev, A. Ya. Yashin, and N. I. Chernousova, Natural Antioxidants. Content in Food Products and Their Effect on Human Health and Aging [in Russian], TransLit, Moscow (2009).
Yu. S. Tarakhovskii, Yu. A. Kim. B. S. Abdrasilov, and E. N. Muzafarov, Flavonoids: Biochemistry, Biophysics, Medicine [in Russian], Synchrobook, Pushchino (2013).
W. Wang, C. Sun, L. Mao, P. Ma, F. Liu, J. Yang, and Y. Gao, Trends Food Sci. Technol., 56, 21–38 (2016).
C. Chen, J. Zhou, and C. Ji, Life Sci., 87, 333–338 (2010).
E. Rijke, P. Out, W. M. Niessen, F. Ariese, C. Gooijer, and U. A. Brinkman, J. Chromatogr. A, 1112, 31–63 (2006).
S. G. Dmitrienko, V. A. Kudrinskaya, and V. V. Apyari, Zh. Analit. Khim., 67, No. 4, 340–353 (2012).
M. Naczk and F. Shahidi, J. Chromatogr. A, 1054, 95–111 (2004).
F. R. P. Rocha, I. M. Raimundo, Jr., and L. S. G. Teixeira, Anal. Lett., 44, 528–559 (2011).
O. A. Zaporozhets, O. A. Krushynska, N. A. Lipkovska, and V. N. Barvinchenko, J. Agric. Food Chem., 52, 21–25 (2004).
O. A. Zaporozhets, O. A. Krushynska, N. A. Lipkovska, and V. M. Barvinchenko, Farmakom, Nos. 1/2 , 51–58 (2006).
N. A. Lipkovska, O. A. Zaporozhets, O. A. Krushynska, V. M. Barvinchenko, and O.O. Dovbii, Farmakom, No. 4, 69–74 (2008).
A. Pęnkal and K. Pyrzynska, Food Anal. Methods, 7, 1776–1782 (2014).
J. P. Cornard and J. C. Merlin, J. Inorg. Biochem., 92, No. 1, 19–27 (2002).
N. Ya. Bernshtein and Yu. L. Kaminskii, Spectrophotometric Analysis in Organic Chemistry [in Russian], Khimiya, Leningrad (1986).
N. A. Lipkovska, V. N. Barvinchenko, T. V. Fedyanina, and A. A. Rugal, Zh. Prikl. Spektrosk., 81, No. 4, 589–593 (2014) [J. Appl. Spectrosc., 81, 644–648 (2014)].
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 86, No. 4, pp. 614–619, July–August, 2019.
Rights and permissions
About this article
Cite this article
Lipkovska, N.A., Barvinchenko, V.N. Spectral Characteristics of Hydroxyflavones Adsorbed on an Alumina Surface. J Appl Spectrosc 86, 666–670 (2019). https://doi.org/10.1007/s10812-019-00876-4
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-019-00876-4