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Determination of the degree of crystallinity of poly(vinyl alcohol) by FTIR spectroscopy

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Journal of Applied Spectroscopy Aims and scope

Quantitative correlations between the intensity of the crystalline band at 1144 cm−1 (A 1144) normalized to the intensity of the C–O stretching band at 1094 cm−1 (A 1094) in IR spectra of PVA films and the degree of crystallinity (α) of these films measured by an x-ray diffraction method were investigated. It was found that α and A 1144/A 1094 were related by the linear dependence α (%) = a + b(A 1144/A 1094) with correlation coefficient 0.999 for α values in the range 18–60%.

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Authors and Affiliations

  1. B. I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, 68 Nezavisimost’ Ave., Minsk, 220072, Belarus

    O. N. Tretinnikov & S. A. Zagorskaya

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  1. O. N. Tretinnikov
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  2. S. A. Zagorskaya
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Correspondence to O. N. Tretinnikov.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 79, No. 4, pp. 538–543, July–August, 2012.

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Tretinnikov, O.N., Zagorskaya, S.A. Determination of the degree of crystallinity of poly(vinyl alcohol) by FTIR spectroscopy. J Appl Spectrosc 79, 521–526 (2012). https://doi.org/10.1007/s10812-012-9634-y

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  • DOI: https://doi.org/10.1007/s10812-012-9634-y

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