Abstract
Plasticized poly(vinyl chloride)/poly(ethyl methacrylate) PVC/PEMA-based blend polymer electrolyte films containing lithium perchlorate (LiClO4) as a salt were prepared by solvent casting technique. The effects of the plasticization on structural, thermal and electrical properties of the plasticized polymer blend electrolytes were investigated. The changes in the structural and complex formation properties of the materials were studied by XRD and FTIR techniques. Dielectric relaxation studies of the polymer electrolyte have been undertaken, and the results are discussed. TG/DTA technique is used to study the thermal stability. Complex impedance analysis is used to calculate the bulk resistance of the complexes. The effect of different plasticizer on the structural and physical properties of polymer blend electrolyte is well correlated.
Similar content being viewed by others
References
Appetecchi GB, Croce F, Dautzenberg G, Scrosati B (1997) J Power Sour 66:77
Abraham KM, Choe HS, Pasquariello D (1998) Electrochim Acta 43:2399
Sanchez JY, Alloin F, Lepmi CP (1998) Mol Cryst Liq Cryst 324:257
Abraham KM (1993) In: Scrosati B (ed) Application of electroactive polymers, Chap 3. Chapman & Hall, London
Abraham KM, Alamgir M (1990) J Electrochem Soc 137:1657
Alamgir M, Moulton RD, Abraham KM (1991) In: Abraham KM, Salomon M (eds) Primary and secondary lithium batteries. The Electrochemical Society, Pennington, NJ, p 131
Abraham KM, Alamgir M (1993) J Power Sour 43/44:195
Cazzanelli E, Mariotto G, Croce F, Appetecchi GB, Scrosati B (1995) Electrochim Acta 40:2379
Cazzanelli E, Mariotto G, Appetecchi GB, Croce F (1996) Ionics 2:81
Ostrovskii O, Torell LM, Appetecchi GB, Scrosati B (1998) Solid State Ionics 106:19
Peramunage D, Pasquariello DM, Abraham KM (1995) J Electrochem Soc 42:1789
Tsunemi TK, Ohno H, Tsuchida E (1983) Eletrochim Acta 28(6):833
Tsuchida E, Ohno H, Tsunemi TK (1983) Electrochim Acta 28(5):591
Sukeshini M, Nishimoto A, Watanabe M (1996) Solid State Ionics 86:385
Pistoia G, Antonini A, Wang G (1996) J Power Sour 58(2):139
Fahmy T, Ahmed MT (2001) Polym Test 20:477
Han HS, Kang HR, Kim SW, Kim HT (2002) J Power Sour 122:461
Rajendran S, Ramesh Prabhu M, Usha Rani M (2008) Int J Electrochem Sci 3:282
Nicotera I, Oliviero C, Ranieri GA, Spadafora A, Castriota M (2002) J Chem Phys 117(15):7373
Alamgir M, Abraham KM (1993) J Electrochem Soc 140(6):L96
Rhoo HJ, Kim HT, Park JK, Hwang TS (1997) Electrochim Acta 42:1571
Ostrovski D, Brodin A, Torell M, Appetecchi GB, Scrosati B (1998) J Chem Phys 109:7618
Jacob MME, Prabaharan SRS, Radhakrishna S (1997) Solid State Ionics 104:267
Armand MB, Chabagno JM, Duclot MJ (1979) In: Vashishta P, Mundy LN, Shenoy G (eds) Fast-ion transport in solids. North-Holland, Amsterdam, p 131
Miyamoto T, Shibayama K (1973) J Appl Phys 44:5372
MacCallum JA, Vincent CA (1987) Polymer electrolyte reviews-I. Elsevier, London
Morita M, Tanaka H, Ishikawa M, Matsuda Y (1996) Solid State Ionics 86:401
Vogel H (1922) Z Phys 22:645
Tamman VG, Hesse HZ (1926) Anorg Allg Chem 19:245
Fulcher GS (1925) J Am Ceram Soc 8:339
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rajendran, S., Ramesh Prabhu, M. Effect of different plasticizer on structural and electrical properties of PEMA-based polymer electrolytes. J Appl Electrochem 40, 327–332 (2010). https://doi.org/10.1007/s10800-009-9979-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10800-009-9979-y