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Electrochemical behavior of an inorganic–organic hybrid based on isopolymolybdate anions and ethylenediamine

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Abstract

The one-dimensional inorganic–organic compound, (C2H10N2)[Mo3O10], was synthesized hydrothermally, and characterized by single crystal X-ray diffraction. The compound was used as a bulk-modifier to fabricate a renewable three-dimensional chemically modified carbon paste electrode (Mo-CPE) by direct mixing. The electrochemical properties of (C2H10N2)[Mo3O10]-modified Mo-CPE were investigated with respect to their pH-dependence, stability and electrocatalytic activity. The hybrid material bulk modified Mo-CPE not only displays good electrocatalytic activity toward the reduction of BrO3 −, IO3 −, NO2 − and H2O2, but also exhibits good stability and multiple repeatability by simply polishing on the surface of a wet filter paper, a feature which is important for practical applications.

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Acknowledgements

This work was supported by the National Nature Science Foundation of China (No. 20771031) and the China Postdoctoral Science Foundation (No. 200503644).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin, 150080, People’s Republic of China

    Chunxiang Li & Huiyuan Ma

  2. College of Live and Environmental Sciences, Central University for Nationalities, Beijing, 100081, People’s Republic of China

    Yan Zhang

  3. Department of Chemistry, Emory University, Atlanta, GA, 30322, USA

    Kevin P. O’Halloran

Authors
  1. Chunxiang Li
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  2. Yan Zhang
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  3. Kevin P. O’Halloran
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  4. Huiyuan Ma
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Correspondence to Huiyuan Ma.

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Li, C., Zhang, Y., O’Halloran, K.P. et al. Electrochemical behavior of an inorganic–organic hybrid based on isopolymolybdate anions and ethylenediamine. J Appl Electrochem 39, 1011–1015 (2009). https://doi.org/10.1007/s10800-008-9748-3

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  • DOI: https://doi.org/10.1007/s10800-008-9748-3

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