Abstract
A validated adsorptive cathodic stripping voltammetry method is described for simultaneous determination of Al(III), Cu(II) and Cd(II) in water samples. In acetate buffer (pH 5) containing 10 μM oxine, these metal ions were determined as oxine complexes following adsorptive accumulation onto the HMDE at −0.05 V versus Ag/AgCl/KCls. The best signal to noise ratio was obtained using a square wave of scan increment 10 mV, frequency 120 Hz, and pulse-amplitude 25 mV. Limits of detection as low as 0.020 μg L−1 Al(III), 0.012 μg L−1 Cu(II) and 0.028 μg L−1 Cd(II) were achieved. Interference due to various cations (K(I), Na(I), Mg(II), Ca(II), Mn(II), Fe(III), Bi(III), Sb(III), Se(IV), Pb(II), Zn(II), Ni(II), Co(II)), anions (Cl−, NO3−, SO4 2−, PO4 3−) and ascorbic acid was minimal as the measured signals change by 4% at the maximum. The stripping voltammetry method was successfully applied for simultaneous determination of Al(III), Cu(II) and Cd(II) in tap and natural bottled water samples.
Similar content being viewed by others
References
ATSDR “Agency for Toxic Substances, Disease Registry” (1999) Public health service. US Department of Health and Human Services, Atlanta, GA
Mary A, Rogers G, David M (1999) Age Ageing 28:205
Goodman WG (1990) In: de Broe ME, Coburn JW (eds) Aluminum and renal failure. Kluwer Academic Publishers, Dordrecht
Van de Vyver F, Visser WJ (1990) In: Priest ND, Van de Vyver F (eds) Trace metals and fluoride in bones and teeth. CRC Press, Boca Raton
Hem JD (1960) Study and interpretation of the chemical characteristics of natural water, 2nd edn. US Department of the Interior, US Government Printing Office, Washington
Crompton TR (1997) Toxicants in the aqueous ecosystem. Wiley, Chichester
Bocca B, Alimonti A, Petrucci F, Violante N, Sancesario G, Forte G, Senofonte O (2004) Spectrochim Acta B 59:559
Roberts NB, Clough A, Bellia JP, Kim JY (1998) J Inorg Biochem 69:171
Beniz Gündüz S, Küçükkolbaşý S, Atakol O, Kýlýç E (2005) Spectrochim Acta A 61:913
Nguyen KL, Lewis DM, Jolly M, Robinson J (2004) Water Res 38:4039
Narin I, Tuzen M, Soylak M (2004) Talanta 63:411
Razniewska G, Trzcinka-Ochocka M (2003) Chem Anal 48:107
Ozkan MH, Akcay M (2002) Turk J Chem 26:711
Wieteska E, Drzewinska A (2002) Chem Anal 47:31
Campillo N, Vinas P, Lopez-Garcia I, Hernandez-Cordoba M (1999) Talanta 48:905
Fairman B, SanzMedel A (1996) Fresenius J Anal Chem 355:757
Sabermahani F, Taher MA (2007) Microchim Acta 159:117
Zacharia A, Gucer S, Izgi B, Chebotarev A, Karaaslan H (2007) Talanta 72:825
Caballo-Lopez A, de Castro MDL (2007) Talanta 71:2074
Jahromi EZ, Bidari A, Assadi Y, Hosseini MRM, Jamali MR (2007) Anal Chim Acta 585:305
Matusiewicz H, Krawczyk M (2006) Microchem J 83:17
Minamisawa H, Okunugi R, Minamisawa M, Tanaka S, Saitoh K, Arai N, Shibukawa M (2006) Anal Sci 22:709
Tarley CRT, Figueiredo ED, Matos GD (2005) Anal Sci 21:1337
Ghaedi M, Ahmadi F, Shokrollahi A (2007) J Hazard Mater 142:272
Ghaedi M, Fathi MR, Marahel F, Ahmadi F (2005) Fresen Environ Bull 14:1158
Minami T, Sohrin Y, Ueda J (2005) Anal Sci 21:1519
Zeiner M, Steffan I, Cindric IJ (2005) Microchem J 81:171
Karadjova I, Izgi B, Gucer S (2002) Spectrochim Acta 57:581
Wang J (2001) Analytical electrochemistry, 2nd edn. Wiley-VCH, New York
van den Berg CMG, Murphy K, Riley JP (1986) Anal Chim Acta 188:177
de Carvalho LM, do Nascimento PC, Bohrer D, Stefanello R, Bertagnoli D (2005) Anal Chim Acta 546:79
Wang J, Farias PAM, Mahmoud JS (1985) Anal Chim Acta 172:57
Wang X, Lei J, Bi S, Gan N, Wei Z (2001) Anal Chim Acta 449:35
Locatelly C (2003) Electroanalysis 15:1397
Downard AJ, Kipton H, Powell J, Xu S (1992) Anal Chim Acta 262:339
Wang J, Lu J, Setiadji R (1993) Talanta 40:351
Kefala G, Economou A, Sofoniou M (2006) Talanta 68:1013
Opydo J (1997) Talanta 44:1081
Abo El-Maali N, Temerk YM, Sh-Abd El-Aziz M (1997) Anal Chim Acta 353:313
Arancibia V, Muñoz C (2007) Talanta 73:546
Zhang F, Ji M, Xu Q, Yang L, Bi S (2005) J Inorg Biochem 99:1756
Hajian R, Shams E (2003) Anal Chim Acta 491:63
Ghoneim MM, Hassanein AM, Hammam E, Beltagi AM (2000) Fresenius J Anal Chem 367:378
Ensafi AA, Khayamian T, Benvidi A, Mirmomtaz E (2006) Anal Chim Acta 561:225
Colombo C, van den Berg CMG (1997) Anal Chim Acta 337:29
Jin L, Gogan NJ (2000) Anal Chim Acta 412:77
Locatelli C, Torsi G (2003) Microchem J 75:233
Ensafi AA, Khayamian T, Khaloo SS (2004) Anal Chim Acta 505:201
Ensafi AA, Khayamian T, Atabati M (2002) Talanta 57:785
Locatelli C, Torsi G (2000) Microchem J 65:293
Fogg AG, Rahim A, Yusoff HM, Ahmad R (1997) Talanta 44:125
Nedeltcheva T, Costadinnova L, Athanassova M (1994) Anal Chim Acta 291:75
Lucia M, Campos AM, van den Berg CMG (1994) Anal Chim Acta 284:481
Donat JR, Van den Berg CMG (1992) Mar Chem 38:69
Van den Berg CMG, Donat JR (1992) Anal Chim Acta 257:281
Van den Berg CMG (1986) J Electroanal Chem 215:111
Zhu WW, Li NB, Luo HQ (2007) Talanta 72:1733
Legeai S, Vittori O (2006) Anal Chim Acta 560:184
Brainina KZ, Stozhko NY, Belysheva GM, Inzhevatova OV, Kolyadina LI, Cremisini C, Galletti M (2004) Anal Chim Acta 514:227
Bonfil Y, Kirowa-Eisner E (2002) Anal Chim Acta 457:285
Locatelli C, Torsi G (2001) J Electroanal Chem 509:80
van Staden JF, Matoetoe MC (2000) Anal Chim Acta 411:201
Pacer RA, Ellis CKS, Peng R (1999) Talanta 49:725
Fischer E, van den Berg CMG (1999) Anal Chim Acta 385:273
Jurado-González JA, Galindo-Riaño MD, García-Vargas M (2003) Anal Chim Acta 487:229
Cerutti S, Silva MF, Gasquez JA, Olsina RA, Martinez LD (2003) Spectrochim Acta B 58:43
Garay F, Solis VM (1999) J Electroanal Chem 476:165
Arancibia V, Alarcón L, Segura R (2004) Anal Chim Acta 502:189
Giroussi ST, Voulgaropoulos AN, Ayiannidis A (1997) Fresenius J Anal Chem 357:429
Kelly MT, Blaise A (2006) J Chromatogr A 1134:74
Matus P, Kubova J (2006) Anal Chim Acta 573:474
Zhu XS, Bao L, Guo R, Wu J (2004) Anal Chim Acta 523:43
Sun YC, Mierzwa J, Lan CR (2000) Talanta 52:417
Adeloju SBO, Pablo F (1995) Electroanalysis 7:476
Yang ZP, Alafandy M, Boutakhrit K, Kauffmann JM, Arcos J (1996) Electroanalysis 8:25
Angulo M, Galvin RM, Montoya MR, Mellado JMR (1993) J Electroanal Chem 348:303
Ghoneim MM, El-Baradie KY, Tawfik A (2003) J Pharm Biomed Anal 33:673
Devol I, Bardez E (1998) J Colloid Interface Sci 200:241
Garay F, Solis VM (2001) J Electroanal Chem 505:109
Webber A, Shah M, Osteryoung J (1984) Anal Chim Acta 157:17
Swartz M, Krull IS (1997) Analytical method development and validation. Dekker (Marcel), p 62
Christian GD (1994) Analytical chemistry, 5th edn. Willey, USA
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Beltagi, A.M., Ghoneim, M.M. Simultaneous determination of trace aluminum (III), copper (II) and cadmium (II) in water samples by square-wave adsorptive cathodic stripping voltammetry in the presence of oxine. J Appl Electrochem 39, 627–636 (2009). https://doi.org/10.1007/s10800-008-9703-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10800-008-9703-3