Skip to main content
Log in

Deterioration of Travertine Samples Due to Magnesium Sulfate Crystallization Pressure: Examples from Iran

  • Original paper
  • Published:
Geotechnical and Geological Engineering Aims and scope Submit manuscript

Abstract

In order to assess the resistance of travertine against salt crystallization, 15 travertine samples were selected from Iran’s mines. Petrographic, physical and mechanical properties of the travertine samples were determined, and then salt crystallization test was carried out by using magnesium sulfate (MgSO4) solution up to 60 cycles. Dry weight increment, dry weight loss, Brazilian tensile strength (BTS), point load strength index and P-wave velocity were calculated at 10, 20, 30, 40, 50 and 60 number of cycles. Two weathering forms (granular disintegration, and alveolaring) were observed in the samples as a result of salt crystallization pressure. Onyx travertine samples were more resistant than travertine samples. It was found out that the deterioration rate at elementary cycles was lower. The results showed that durability of samples has a positive relationship with initial BTS and a negative relationship with initial effective porosity. It was concluded non-destructive tests are good technique for assessment of travertine deterioration in salt crystallization test.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Akin M, Özsan A (2011) Evaluation of the long-term durability of yellow travertine using accelerated weathering tests. Bull Eng Geol Environ 70:101–114

    Article  Google Scholar 

  • Akyol E, Yagiz S, Ozkul M, Sen G, Kato S (2005) Physical properties of hot spring travertines related to lithotypes at Pamukkale region in Denizli, Turkey. In: International symposium on Travertine, September 21–25, 2005, Denizli Turkey, pp 286–290

  • Angeli M, Bigas JP, Menendez B, Hebert R, David C (2006) Influence of capillary properties and evaporation on salt weathering of sedimentary rocks. In: Fort R, Alvarez de Buergo M, Gomez-Heras M, Vazquez-Calvo C (eds) Heritage, weathering and conservation. Taylor & Francis/Balkema, AK Leiden, The Netherlands, pp 253–259

    Google Scholar 

  • Angeli M, Bigas JP, Benavente D, Menendez B, Hebert R, David C (2007) Salt crystallization in pores: quantification and estimation of damage. Environ Geol 52:187–195

    Article  Google Scholar 

  • Bell FG (1993) Durability of carbonate rock as building stone with comments on its preservation. Environ Geol 21:187–200

    Article  Google Scholar 

  • Benavente D, García del Cura MA, Fort R, Ordóñez S (2004) Durability estimation of porous building stones from pore structure and strength. Eng Geol 74:113–127

    Article  Google Scholar 

  • Benavente D, Cueto N, Martínez-Martínez J, García del Cura MA, Cañaveras JC (2007a) The influence of petrophysical properties on the salt weathering of porous building rocks. Environ Geol 52:215–224

    Article  Google Scholar 

  • Benavente D, Martínez-Martínez J, Cueto N, García del Cura MA (2007b) Salt weathering in dual-porosity building dolostones. Eng Geol 94:215–226

    Article  Google Scholar 

  • Cardell C, Delalieux F, Roumpopoulos K, Moropoulou A, Auger F, Van Griekena R (2003) Salt-induced decay in calcareous stone monuments and buildings in a marine environment in SW France. Constr Build Mater 17:165–179

    Article  Google Scholar 

  • Chafetz HS, Folk RL (1984) Travertines: depositional morphology and the bacterially constructed constituents. Sediment Res 54:289–316

    Google Scholar 

  • Choquette PW, Pray LC (1970) Geologic nomenclature and classification of porosity in sedimentary carbonates. Am Assoc Pet Geol Bull 54:207–250

    Google Scholar 

  • Espinosa-Marzal RM, Scherer GW (2010) Advances in understanding damage by salt crystallization. Acc Chem Res 43:897–905

    Article  Google Scholar 

  • Flatt RJ (2002) Salt damage in porous materials: how high supersaturations are generated. Cryst Growth 242:435–454

    Article  Google Scholar 

  • García-del-Cura M, Benavente D, Martínez-Martínez J, Cueto N (2012) Sedimentary structures and physical properties of travertine and carbonate tufa building stone. Constr Build Mater 28:456–467

    Article  Google Scholar 

  • Ghobadi MH, Babazadeh R (2015) Experimental studies on the effects of cyclic freezing–thawing, salt crystallization, and thermal shock on the physical and mechanical characteristics of selected sandstones. Rock Mech Rock Eng 48:1001–1016

    Article  Google Scholar 

  • Guo L, Riding R (1998) Hot-spring travertine facies and sequences, late pleistocene, Rapolano Terme, Italy. Sedimentology 45:163–180

    Article  Google Scholar 

  • ISRM (1981) Suggested method for rock characterization, testing and monitoring, ISRM Commission on Testing Methods. Pergamon Press, Oxford, p 211

    Google Scholar 

  • Jefferson DP (1993) Building stone: the geological dimension. Q J Eng Geol Hydrogeol 26:305–319

    Article  Google Scholar 

  • Ludovico-Marques M, Chastre C (2012) Effect of salt crystallization ageing on the compressive behavior of sandstone blocks in historical buildings. Eng Fail Anal 26:247–257

    Article  Google Scholar 

  • Martínez-Martínez J, Benavente D, García-del-Cura MA (2011) Spatial attenuation: the most sensitive ultrasonic parameter for detecting petrographic features and decay processes in carbonate rocks. Eng Geol 119:84–95

    Article  Google Scholar 

  • Momeni A, Khanlari GR, Heidari M, Bagheri R, Bazvand E (2015) Assessment of physical weathering effects on granitic ancient monuments, Hamedan, Iran. Environ Earth Sci. doi:10.1007/s12665-015-4536-y

    Google Scholar 

  • Nicholson DT (2001) Pore properties as indicators of breakdown mechanisms in experimentally weathered limestones. Earth Surf Process Landf 26:819–838

    Article  Google Scholar 

  • Pedley HM (1990) Classification and environmental models of cool freshwater tufas. Sediment Geol 68:143–154

    Article  Google Scholar 

  • RILEM (1980) Recommended tests to measure the deterioration of stone and to assess the effectiveness of treatment methods. Mater Struct 13:175–253

    Google Scholar 

  • Rodriguez-Navarro C, Doehne E, Sebastian E (2000) How does sodium sulfate crystallize? Implications for the decay and testing of building materials. Cem Concr Res 30:1527–1534

    Article  Google Scholar 

  • Ruedrich J, Siegesmund S (2007) Salt and ice crystallization in porous sandstones. Environ Geol 52:369–381

    Article  Google Scholar 

  • Ruiz-Agudo E, Mees F, Jacobs P, Rodriguez-Navarro C (2007) The role of saline solution properties on porous limestone salt weathering by magnesium and sodium sulfates. Environ Geol 52:269–281

    Article  Google Scholar 

  • Scherer GW (1999) Crystallization in pores. Cem Concr Res 298:1347–1358

    Article  Google Scholar 

  • Scherer GW (2004) Stress from crystallization of salt. Cem Concr Res 34:1613–1624

    Article  Google Scholar 

  • Silva ZSG, Simão JAR (2009) The role of salt fog on alteration of dimension stone. Constr Build Mater 23:3321–3327

    Article  Google Scholar 

  • Sousa LM, Suárezdel Río LM, Calleja L, Ruiz de Argandoña VG, Rey AR (2005) Influence of microfractures and porosity on the physico-mechanical properties and weathering of ornamental granites. Eng Geol 77:153–168

    Article  Google Scholar 

  • Theoulakis P, Moropoulou A (1999) Salt crystal growth as weathering mechanism of porous stone on historic masonry. J Porous Mater 6:345–358

    Article  Google Scholar 

  • Topal T, Sözmen B (2003) Deterioration mechanisms of tuffs in Midas monument. Eng Geol 68:201–223

    Article  Google Scholar 

  • Vajdová V, Přikryl R, Pros Z, Klıma K (1999) The effect of rock fabric on P-wave velocity distribution in amphibolites. Phys Earth Planet Int 114:39–47

    Article  Google Scholar 

  • Weiss T, Rasolofosaon PNJ, Siegesmund S (2002) Ultrasonic wave velocities as a diagnostic tool for the quality assessment of marble. Geol Soc 205:149–164

    Article  Google Scholar 

  • Yavuz AB, Topal T (2007) Thermal and salt crystallization effects on marble deterioration: examples from Western Anatolia, Turkey. Eng Geol 90:30–40

    Article  Google Scholar 

  • Yu S, Oguchi CT (2010) Role of pore size distribution in salt uptake, damage, and predicting salt susceptibility of eight types of Japanese building stones. Eng Geol 115:226–236

    Article  Google Scholar 

Download references

Acknowledgements

The authors are thankful to the mining companies in Azarshar, Mahallat and Firouzkouh.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mashala Khamehchiyan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zalooli, A., Khamehchiyan, M., Nikudel, M.R. et al. Deterioration of Travertine Samples Due to Magnesium Sulfate Crystallization Pressure: Examples from Iran. Geotech Geol Eng 35, 463–473 (2017). https://doi.org/10.1007/s10706-016-0120-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10706-016-0120-9

Keywords

Navigation