Abstract
In order to assess the resistance of travertine against salt crystallization, 15 travertine samples were selected from Iran’s mines. Petrographic, physical and mechanical properties of the travertine samples were determined, and then salt crystallization test was carried out by using magnesium sulfate (MgSO4) solution up to 60 cycles. Dry weight increment, dry weight loss, Brazilian tensile strength (BTS), point load strength index and P-wave velocity were calculated at 10, 20, 30, 40, 50 and 60 number of cycles. Two weathering forms (granular disintegration, and alveolaring) were observed in the samples as a result of salt crystallization pressure. Onyx travertine samples were more resistant than travertine samples. It was found out that the deterioration rate at elementary cycles was lower. The results showed that durability of samples has a positive relationship with initial BTS and a negative relationship with initial effective porosity. It was concluded non-destructive tests are good technique for assessment of travertine deterioration in salt crystallization test.
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References
Akin M, Özsan A (2011) Evaluation of the long-term durability of yellow travertine using accelerated weathering tests. Bull Eng Geol Environ 70:101–114
Akyol E, Yagiz S, Ozkul M, Sen G, Kato S (2005) Physical properties of hot spring travertines related to lithotypes at Pamukkale region in Denizli, Turkey. In: International symposium on Travertine, September 21–25, 2005, Denizli Turkey, pp 286–290
Angeli M, Bigas JP, Menendez B, Hebert R, David C (2006) Influence of capillary properties and evaporation on salt weathering of sedimentary rocks. In: Fort R, Alvarez de Buergo M, Gomez-Heras M, Vazquez-Calvo C (eds) Heritage, weathering and conservation. Taylor & Francis/Balkema, AK Leiden, The Netherlands, pp 253–259
Angeli M, Bigas JP, Benavente D, Menendez B, Hebert R, David C (2007) Salt crystallization in pores: quantification and estimation of damage. Environ Geol 52:187–195
Bell FG (1993) Durability of carbonate rock as building stone with comments on its preservation. Environ Geol 21:187–200
Benavente D, García del Cura MA, Fort R, Ordóñez S (2004) Durability estimation of porous building stones from pore structure and strength. Eng Geol 74:113–127
Benavente D, Cueto N, Martínez-Martínez J, García del Cura MA, Cañaveras JC (2007a) The influence of petrophysical properties on the salt weathering of porous building rocks. Environ Geol 52:215–224
Benavente D, Martínez-Martínez J, Cueto N, García del Cura MA (2007b) Salt weathering in dual-porosity building dolostones. Eng Geol 94:215–226
Cardell C, Delalieux F, Roumpopoulos K, Moropoulou A, Auger F, Van Griekena R (2003) Salt-induced decay in calcareous stone monuments and buildings in a marine environment in SW France. Constr Build Mater 17:165–179
Chafetz HS, Folk RL (1984) Travertines: depositional morphology and the bacterially constructed constituents. Sediment Res 54:289–316
Choquette PW, Pray LC (1970) Geologic nomenclature and classification of porosity in sedimentary carbonates. Am Assoc Pet Geol Bull 54:207–250
Espinosa-Marzal RM, Scherer GW (2010) Advances in understanding damage by salt crystallization. Acc Chem Res 43:897–905
Flatt RJ (2002) Salt damage in porous materials: how high supersaturations are generated. Cryst Growth 242:435–454
García-del-Cura M, Benavente D, Martínez-Martínez J, Cueto N (2012) Sedimentary structures and physical properties of travertine and carbonate tufa building stone. Constr Build Mater 28:456–467
Ghobadi MH, Babazadeh R (2015) Experimental studies on the effects of cyclic freezing–thawing, salt crystallization, and thermal shock on the physical and mechanical characteristics of selected sandstones. Rock Mech Rock Eng 48:1001–1016
Guo L, Riding R (1998) Hot-spring travertine facies and sequences, late pleistocene, Rapolano Terme, Italy. Sedimentology 45:163–180
ISRM (1981) Suggested method for rock characterization, testing and monitoring, ISRM Commission on Testing Methods. Pergamon Press, Oxford, p 211
Jefferson DP (1993) Building stone: the geological dimension. Q J Eng Geol Hydrogeol 26:305–319
Ludovico-Marques M, Chastre C (2012) Effect of salt crystallization ageing on the compressive behavior of sandstone blocks in historical buildings. Eng Fail Anal 26:247–257
Martínez-Martínez J, Benavente D, García-del-Cura MA (2011) Spatial attenuation: the most sensitive ultrasonic parameter for detecting petrographic features and decay processes in carbonate rocks. Eng Geol 119:84–95
Momeni A, Khanlari GR, Heidari M, Bagheri R, Bazvand E (2015) Assessment of physical weathering effects on granitic ancient monuments, Hamedan, Iran. Environ Earth Sci. doi:10.1007/s12665-015-4536-y
Nicholson DT (2001) Pore properties as indicators of breakdown mechanisms in experimentally weathered limestones. Earth Surf Process Landf 26:819–838
Pedley HM (1990) Classification and environmental models of cool freshwater tufas. Sediment Geol 68:143–154
RILEM (1980) Recommended tests to measure the deterioration of stone and to assess the effectiveness of treatment methods. Mater Struct 13:175–253
Rodriguez-Navarro C, Doehne E, Sebastian E (2000) How does sodium sulfate crystallize? Implications for the decay and testing of building materials. Cem Concr Res 30:1527–1534
Ruedrich J, Siegesmund S (2007) Salt and ice crystallization in porous sandstones. Environ Geol 52:369–381
Ruiz-Agudo E, Mees F, Jacobs P, Rodriguez-Navarro C (2007) The role of saline solution properties on porous limestone salt weathering by magnesium and sodium sulfates. Environ Geol 52:269–281
Scherer GW (1999) Crystallization in pores. Cem Concr Res 298:1347–1358
Scherer GW (2004) Stress from crystallization of salt. Cem Concr Res 34:1613–1624
Silva ZSG, Simão JAR (2009) The role of salt fog on alteration of dimension stone. Constr Build Mater 23:3321–3327
Sousa LM, Suárezdel Río LM, Calleja L, Ruiz de Argandoña VG, Rey AR (2005) Influence of microfractures and porosity on the physico-mechanical properties and weathering of ornamental granites. Eng Geol 77:153–168
Theoulakis P, Moropoulou A (1999) Salt crystal growth as weathering mechanism of porous stone on historic masonry. J Porous Mater 6:345–358
Topal T, Sözmen B (2003) Deterioration mechanisms of tuffs in Midas monument. Eng Geol 68:201–223
Vajdová V, Přikryl R, Pros Z, Klıma K (1999) The effect of rock fabric on P-wave velocity distribution in amphibolites. Phys Earth Planet Int 114:39–47
Weiss T, Rasolofosaon PNJ, Siegesmund S (2002) Ultrasonic wave velocities as a diagnostic tool for the quality assessment of marble. Geol Soc 205:149–164
Yavuz AB, Topal T (2007) Thermal and salt crystallization effects on marble deterioration: examples from Western Anatolia, Turkey. Eng Geol 90:30–40
Yu S, Oguchi CT (2010) Role of pore size distribution in salt uptake, damage, and predicting salt susceptibility of eight types of Japanese building stones. Eng Geol 115:226–236
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The authors are thankful to the mining companies in Azarshar, Mahallat and Firouzkouh.
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Zalooli, A., Khamehchiyan, M., Nikudel, M.R. et al. Deterioration of Travertine Samples Due to Magnesium Sulfate Crystallization Pressure: Examples from Iran. Geotech Geol Eng 35, 463–473 (2017). https://doi.org/10.1007/s10706-016-0120-9
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DOI: https://doi.org/10.1007/s10706-016-0120-9