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Characteristics of Heterophase Radical Graft Polymerization of Methyl Methacrylate on Polymer Fibres

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Abstract

Graft copolymers with graft PMMA were synthesized using the Cu2+—H2O2 redox system. The conditions for obtaining graft PCA—PMMA and HC-PMMA of 40–60 composite composition with grafting efficiency at the 85% level are found. The effect of the polymer matrix on the kinetic and thermodynamic properties of graft polymerization of MMA is revealed. Possible schemes of the reactions of graft polymerization of MMA to polycaproamide and hydrated cellulose are proposed based on quantum chemical calculations of the enthalpy of formation of the graft copolymers.

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Authors and Affiliations

  1. Moscow State Textile University, Moscow, Russia

    A. R. Bikkullova, T. V. Druzhinina & I. A. Abronin

Authors
  1. A. R. Bikkullova
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  2. T. V. Druzhinina
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  3. I. A. Abronin
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Additional information

The research was conducted under MNTPP Project No. 203 “Chemical Engineering” (Section 2 “ General Chemical Engineering”) in the scientific-industrial program “Higher-Education Research on Priority Directions in Science and Engineering.”

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Translated from Khimicheskie Volokna, No. 1) pp. 19–23, January–February, 2005.

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Bikkullova, A.R., Druzhinina, T.V. & Abronin, I.A. Characteristics of Heterophase Radical Graft Polymerization of Methyl Methacrylate on Polymer Fibres. Fibre Chem 37, 11–17 (2005). https://doi.org/10.1007/s10692-005-0042-4

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  • DOI: https://doi.org/10.1007/s10692-005-0042-4

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