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Magnetic solid phase extraction based on poly(β-cyclodextrin-ester) functionalized silica-coated magnetic nanoparticles (NPs) for simultaneous extraction of the malachite green and crystal violet from aqueous samples

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Abstract

In this research, an efficient sorbent based on poly(β-cyclodextrin-ester)-functionalized silica-coated magnetic nanoparticles (MNPs-CDP) was prepared and used for magnetic solid-phase extraction of the malachite green (MG) and crystal violet (CV) from water samples prior to their determination by high-performance liquid chromatography-ultra violet detection (HPLC-UV). The synthesized nanoparticles were characterized by the field emission-scanning electron microscopy (FE-SEM) and Fourier transform infrared spectroscopy (FT-IR). Of course, the factors, which could influence the extraction efficiency like pH, sorbent amount, salt content, extraction time, desorption time, eluent type, and volume and sample volume, were optimized by response surface methodology. Then, for both of MG and CV, good linearity (0.1–200 μg L−1, r2 ≥ 0.99) was achieved under the optimized conditions. The limits of detection (LODs) and the limits of quantification (LOQs), for both of MG and CV, were 0.03 μg L−1 and 0.1 μg L−1, respectively. Precision of the method expressed as the relative standard deviations (RSDs) at concentration level of 100 μg L−1 was 5.6 and 4.2 for MG and CV, respectively. Ultimately, usability of proposed method was investigated by analysis of CV and MG in tap water, fish pond water, and the lake water, and the satisfactory recoveries were obtained in the range of 92–100.5%.

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Authors and Affiliations

  1. Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran

    Sepideh Moradi Shahrebabak, Mohammad Saber-Tehrani & Parviz Aberoomand-Azar

  2. Research Group of Food, Halal and Agricultural Products, Research Department of Food Technology and Agricultural Products, Standard Research Institute (SRI), P.O. Box 31745-139, Karaj, Iran

    Mohammad Faraji

  3. Research Group of Petrochemistry and Polymer, Research Department of Chemistry and Petrochemistry, Standard Research Institute (SRI), P.O. Box 31745-139, Karaj, Iran

    Meisam Shabanian

Authors
  1. Sepideh Moradi Shahrebabak
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  2. Mohammad Saber-Tehrani
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  3. Mohammad Faraji
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  4. Meisam Shabanian
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  5. Parviz Aberoomand-Azar
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Correspondence to Mohammad Saber-Tehrani or Mohammad Faraji.

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Moradi Shahrebabak, S., Saber-Tehrani, M., Faraji, M. et al. Magnetic solid phase extraction based on poly(β-cyclodextrin-ester) functionalized silica-coated magnetic nanoparticles (NPs) for simultaneous extraction of the malachite green and crystal violet from aqueous samples. Environ Monit Assess 192, 262 (2020). https://doi.org/10.1007/s10661-020-8185-6

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