Skip to main content
Log in

Concentration trends of metals in ambient air in the UK: a review

  • Published:
Environmental Monitoring and Assessment Aims and scope Submit manuscript

Abstract

The monitoring of metals in ambient air has been undertaken for over 40 years on a national basis in the UK. During this period, the UK pollution landscape has continued to evolve in terms of emission sources, and the measurement framework for metals in ambient air, the UK Heavy Metals Monitoring Network, has also been subject to significant configuration changes. Therefore, this work provides a timely review of more recent concentration trends in the context of current emission profiles. Overall, throughout this time period, there has been a significant downward trend in the emissions and consequently, the measured concentrations of most metals in UK ambient air. Ambient concentrations were generally found to be well correlated with emission estimates. Analysis of the sensitivity of measured concentrations to emissions suggests that concentrations have fallen faster than the reduction in emission estimates would have predicted at typical median urban background sites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  • Air Quality Strategy for England, Scotland, Wales and Northern Ireland, 2007, Cmd paper No 7169 NIA 61/06-07.

  • Arden Pope III, C. (2000). Epidemiology of fine particulate air pollution and human health: biologic mechanisms and who’s at risk? Environmental Health Perspectives, 108(suppl 4), 713–723.

    Article  Google Scholar 

  • Bell, M. L., & Davis, D. L. (2001). Reassessment of the lethal London fog of 1952: novel indicators of acute and chronic consequences of acute exposure to air pollution. Environmental Health Perspectives, 109(suppl 3), 389–394.

    Article  CAS  Google Scholar 

  • Brimblecombe, P. (1987). The big smoke. London: Methuen.

    Google Scholar 

  • Brown, R. J. C. (2010). Comparison of estimated annual emissions and measured annual ambient concentrations of metals in the UK 1980–2007. Journal of Environmental Monitoring, 12, 665–671.

    Article  CAS  Google Scholar 

  • Brown, R. J. C., Yardley, R. E., Muhunthan, D., Butterfield, D. M., Williams, M., Woods, P. T., Brown, A. S., & Goddard, S. L. (2008). Twenty-five years of nationwide ambient metals measurement in the United Kingdom: concentration levels and trends. Environmental Monitoring and Assessment, 142, 127–140.

    Article  CAS  Google Scholar 

  • Brown, R. J. C., Goddard, S. L., Butterfield, D. M., Brown, A. S., Robins, C., Mustoe, C. L., & McGhee, E. A. (2015). Ten years of mercury measurement at urban and industrial air quality monitoring stations in the UK. Atmospheric Environment, 109, 1–8.

    Article  CAS  Google Scholar 

  • BS EN 12341. (2014). Ambient air - standard gravimetric measurement method for the determination of the PM10 or PM2,5 mass concentration of suspended particulate matter. European Committee for Standardization (CEN).

  • BS EN 14902. (2005). Ambient air quality - standard method for the measurement of Pb, Cd, As and Ni in the PM10 fraction of suspended particulate matter. European Committee for Standardization (CEN).

  • BS EN 15852. (2010). Ambient air quality - standard method for the determination of total gaseous mercury. European Committee for Standardization (CEN).

  • Calderóm-Garcidueñas, l., & Villarreal-Ríos, R. (2017). Living close to heavy traffic roads, air pollution, and dementia. The Lancet., 389(10070), 675–677.

    Article  Google Scholar 

  • Carslaw, D. (2013). The openair manual open-source tools for analysing air pollution data, King’s College. London.

  • Cobalt Institute. (2017). https://www.cobaltinstitute.org/cobalt-in-the-atmosphere.html (last accessed December 2018)

  • DEFRA UK-AIR website.(2018). https://uk-air.defra.gov.uk/ (last accessed December 2018)

  • DEFRA UK-AIR website, Metals Network page.(2018). https://uk-air.defra.gov.uk/networks/network-info?view=metals (last accessed December 2018)

  • EEC Motor fuel (lead content of petrol) regulations (1976)

  • European Commission. (2005). Council Directive 2004/107/EC of the European Parliament and of the Council of 15 December 2004 relating to arsenic, cadmium, mercury, nickel and polycyclic aromatic hydrocarbons in ambient air. Official Journal of the European Union, L023_3, 3–16.

    Google Scholar 

  • European Commission. (2008). Council Directive 2008/50/EC of the European Parliament and of the Council of 21 May 2008 on ambient air quality and cleaner air for Europe. Official Journal of the European Union, L152_1, 1, –44.

  • Fowler, D., McDonald, A. G., Crossley, A., Nemitz, E., Leaver, D., Cape, J. N., Smith, R. I., Anderson, D., Rowland, P., Ainsworth, G., Lawlor, A. J., Guyatt, H., & Harmens, H. (2006). UK Heavy Metals Monitoring Network. In Centre for Ecology and Hydrology.

    Google Scholar 

  • Goddard, S. L., Brown, R. J. C., Butterfield, D. M., McGhee, E. A., Robins, C., Brown, A., Beccaceci, S., Lilley, A., Bradshaw, C., & Brennan, S. (2015). Annual Report for 2014 on the UK Heavy Metals Monitoring Network. Teddington: Queen’s Printer and Controller of HMSO.

    Google Scholar 

  • Grigoratos, T., & Martini, G. (2015). Brake wear particle emissions: a review. Environmental Science and Pollution Research, 22, 2491–2504.

    Article  CAS  Google Scholar 

  • Ha, E., Hong, Y., Lee, B., Woo, B., Schwartz, J., & Christiani, D. C. (2001). Is Air Pollution a risk factor for low birth weight in Seoul? Epidemiology., 12(6), 643–648.

    Article  CAS  Google Scholar 

  • Harrison, R. M., Jones, A. M., Gietl, J., Yin, J., & Green, D. C. (2012). Estimation of the contributions of brake dust, tire wear, and resuspension to nonexhaust traffic particles derived from atmospheric measurements. Environmental Science & Technology, 46, 6523–6529.

    Article  CAS  Google Scholar 

  • HMSO. (1956). Ministry of housing and local government and department of health for Scotland: Clean Air Act. London: HMSO.

    Google Scholar 

  • National Atmospheric Emissions Inventory .(2018). http://naei.beis.gov.uk/data/ (last accessed December 2018)

  • National Atmospheric Emissions Inventory .(2019). http://naei.beis.gov.uk/data/ (last accessed August 2019).

  • Smith, I. M. (2010). NPL Report MS 11, Software for determining polynomial calibration functions by generalised least squares: user manual. NPL: Teddington.

    Google Scholar 

  • Theil, H. (1950). A rank-invariant method of linear and polynomial regression analysis. I, II, III. Nederl. Akad. Wetensch., Proc., 53, 386–392 521–525, 1397–1412, MR 0036489.

    Google Scholar 

  • Tilgenkamp, A. Theil-Sen estimator. 1994 –. (2018). The MathWorks, Inc. https://www.mathworks.com/matlabcentral/fileexchange/34308-theil-sen-estimator (last accessed November 2018)

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sharon L. Goddard.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

ESM 1

(DOCX 2513 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Goddard, S.L., Williams, K.R., Robins, C. et al. Concentration trends of metals in ambient air in the UK: a review. Environ Monit Assess 191, 683 (2019). https://doi.org/10.1007/s10661-019-7824-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10661-019-7824-2

Keywords

Navigation