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Impact of urbanization coupled with drought situations on groundwater quality in shallow (basalt) and deeper (granite) aquifers with special reference to fluoride in Nanded-Waghala Municipal Corporation, Nanded District, Maharashtra (India)

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Abstract

Rapid expansion in urbanization and industrialization coupled with recent drought conditions has triggered unplanned groundwater development leading to severe stress on groundwater resources in many urban cities of India, particularly cities like Nanded, Maharashtra. In the quest of tapping drinking water requirement, due to recent drought conditions, people from the city are piercing through entire thickness of shallow basalt aquifers to reach productive deeper granite aquifers. Earlier reports from Nanded and surrounding districts suggest that deeper granite aquifer is contaminated with fluoride (geogenic). The study aimed to find out variations in fluoride concentration in shallow basalt (10–167 m) and deeper granite aquifers (below 167 m) and to find out the relationship between fluoride and other ions. Study suggests that concentration of fluoride in shallow basalt aquifer is within maximum permissible limits of Bureau of Indian Standards and deeper granite aquifer contains as high as 4.9 mg/l of fluoride and all samples from granite aquifers are unfit for human consumption. The groundwater from basalt aquifer is mainly Ca-HCO3−Cl type, and from granite aquifer, it is Ca-Na-Cl type. The correlation plot between F vs. pH, Na+ and HCO3 shows a positive correlation and an inverse relationship with Ca2+ in both aquifers. As recommendations, it is suggested that granite aquifers should not be tapped for drinking purposes; however, in drought situations, water from this aquifer should be blended with treated surface water before supplying for drinking purposes. Efforts may be made to utilize 1.35 MCM of rainwater from available rooftop, which is sufficient to cater for the needs of ~40,800 people annually. Most effective defluoridation techniques like electrolytic de-fluoridation (EDF), ion exchange and reverse osmosis may be adopted along with integrated fluorosis mitigation measures.

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References

  • Agrawal, V., Vaish, A. K., & Vaish, P. (1997). Groundwater quality: focus on fluoride and fluorosis in Rajasthan. Current Science, 73(9), 743–746.

    CAS  Google Scholar 

  • Alcocer, J., Lugo, A., Marín, L. E., & Escobar, E. (1998). Hydrochemistry of waters from five cenotes and evaluation of their suitability for drinking-water supplies, northeastern Yucatan, Mexico. Hydrogeology Journal, 6(2), 293–301.

  • Apambire, W. B., Boyle, D. R., & Michel, F. A. (1997). Geochemistry, genesis and health implications of floriferous ground waters in the upper region of Ghana. Environmental Geology, 33, 13–24.

    Article  CAS  Google Scholar 

  • APHA. (1998). Standard methods for the examination of water and waste water (20th ed.pp. 10–161). Washington, DC: American Public Health Association.

    Google Scholar 

  • Ayoob, S., & Gupta, A. K. (2006). Fluoride in drinking water: a review on the status and stress effects. Critical Reviews in Environmental Science and Technology, 36, 433–487.

    Article  CAS  Google Scholar 

  • Back, W. (1966). Hydrochemical facies and groundwater flow patterns in northern part of Atlantic Coastal Plain. U.S. Geological Survey Professional Paper, 498-A.

  • Barnes, C. J., Jacobson, G., & Smith, G. D. (1992). The origin of high nitrate ground waters in the Australian arid zone. Journal of Hydrology, 137, 181–197.

    Article  CAS  Google Scholar 

  • BIS. (2012). Drinking Water Specification (second revision of IS 10500:2012). Bureau of Indian Standards, Manak Bhavan, 9 Bahadur Shah Zafar Marg, New Delhi. 11p.

  • Brigatti M. F. and Guggenheim S. (2002). Mica crystal chemistry and the influence of pressure, temperature, and solid solution on atomistic models. In: Mottana A., Sassi F. P., Thompson, Jr. J. B. and Guggenheim S. (ed.). Micas: crystal chemistry & metamorphic petrology. Mineralogical Society of America, 1–98.

  • CGWB. (1998). Ground water exploration in Maharashtra and Union Territory of Dadra Nagar and Haveli. Unpub. Report, Central Ground Water Board, Ministry of Water Resources, Government of India, Nagpur, Un pub. Report, 44–46.

  • CGWB. (1999).High fluoride groundwater in India: occurrences, genesis and remedies. Unpub. Report Central Ground Water Board,Ministry of Water Resources, Govt. of India, 29p.

  • Dudley, N. (1990). Nitrates: The threat to food and water. London: Green Print. 118p.

  • Faillat, J. P., & Rambaud, A. (1991). Deforestation and leaching of nitrogen as nitrates into underground water in intertropical zones: The example of Côte d'lvoire. Environmental Geology and Water Sciences, 17(2), 133–140.

  • Gabriela Maria Varcia and Laura Borgnino. (2015). Fluoride in the context of the environment, in fluorine: chemistry, analysis, function and effects, pp.3–21 DOI:10.1039/9781782628507-00003.

  • Godfrey, S. (2007). Guidance manual on integrated fluorosis mitigation. NEERI, UNICEF, 98.

  • Gupta, S. K., & Sharma, P. (1995). An approach to tackling fluoride problem in drinking water. Current Science, 68(8) 774p.

  • Gupta, S. K., & Deshpande, R. D. (2003). High fluoride in groundwater of North Gujarat-Cambay region: origin, community perception and remediation. In V. P. Singh & R. N. Yadava (Eds.), Groundwater pollution (pp. 368–388). New Delhi: Allied Pub. Pvt. Ltd..

    Google Scholar 

  • Handa, B.K. (1974). Methods of collection and analysis of water samples and interpretation of water analysis. Central Ground Water Board, Ministry of Agriculture. Technical Manual No.1.

  • Handa, B.K. (1975). Natural waters, their geochemistry, pollution and treatment with a chapter on saline water. Central Ground Water Board, Technical Manual No.2, Ministry of Agriculture and Irrigation, 246–252.

  • Hem, J.D. (1991). Study and interpretation of chemical characteristics of natural waters. Scientific pub. Jodhapur ,India, 339p.

  • Hill, R. A. (1940). Geochemical patterns in Coachella Valley. Transactions of the American Geophysical Union, 21, 46–49.

    Article  Google Scholar 

  • Jacks, G., Bhattacharya, P., Chaudhary, V., & Singh, K. P. (2005). Controls on the genesis of some high-fluoride ground waters in India. Applied Geochemistry, 20, 221–228.

    Article  CAS  Google Scholar 

  • Kakkar, Y.P., Lal, R., Kumar, A., Singh, B. and Dass, J. (1987) Chemistry of ground water in north-western India (Punjab, Haryana, Himachal Pradesh, Jammu and Kashmir, Union Territory of Delhi and Chandigarh. Central Ground Water Board, Ministry of Water Resources, Government of India, Chandigarh, 87p.

  • Karanth, K.R. (1987). Ground water assessment: development and management. Tata McGraw-Hill Education, 720p.

  • Kross, B. C., Hallberg, G. R., Bruner, D. R., Sherry Holmes, K., & Johnson, J. K. (1993). The nitrate contamination of private well water in Iowa. American Journal of Public Health, 83, 270–272.

    Article  CAS  Google Scholar 

  • Kruse, E., & Ainchil, J. (2003). Fluoride variations in groundwater of an area in Buenos Aires Province Argentina. Environmental Geology, 44, 86–89.

    CAS  Google Scholar 

  • Kundu, N., Panigrahi, M. K., Tripathy, S., Munshi, S., Powell, M. A., & Hart, B. R. (2001). Geochemical appraisal of fluoride contamination of groundwater in the Nayagarh District of Orissa. India Environmental Geology, 41(3–4), 451–460.

    CAS  Google Scholar 

  • Madhnure, P. (2003). Basic data report of Exploratory well drilled at Vishnupuri village, District Nanded. Un-published report. Central Ground Water Board, Nagpur.

  • Madhnure, P. (2004). Impact of urbanization on the ground water regime in Nanded-Waghala City, Nanded district, Maharashtra. Un-published report. Central Ground Water Board, Nagpur. Pg61.

  • Madhnure, P. (2014). Groundwater exploration and drilling problems encountered in basaltic and granitic terrains of Nanded District, Maharashtra. Journal of the Geological Society of India, (84), 341–351.

  • Madhnure, P., Sirsikar, D. Y., Tiwari, A. N., Ranjan, B., & Malpe, D. B. (2007). Occurrence of fluoride in the groundwaters of Pandharkawada area, Yavatmal district, Maharashtra. India. Curr. Sci., 92(5), 675–679.

  • Madhnure, P., Malpe, D.B. and N.V. Chalapathi Rao (2011). Electron probe micro analyzer (EPMA) studies of basalt rocks from fluoride rich ground waters of Pandharkwada, Yavatmal district, Maharashtra” is published in the Journal of Applied Geochemistry Vol.13 No. 2 (2011) pp.192–197.

  • Madhnure, P., Malpe, D. B., & Rao, A. D. (2016). Aquifer wise seasonal variations and spatial distribution of major ions with focus on fluoride contamination, Pandharkawada block, Yavatmal district, Maharashtra, India. Journal Environmental Monitoring and Assessment, 188, 1–20. doi:10.1007/s10661-015-5027z.

    Article  Google Scholar 

  • Pan Y. and M. E. Fleet (2002). Compositions of the apatite-group minerals: substitution mechanisms and controlling factors. In: Kohn, M. L., Rakovan, J. and Hughes, J. M. (ed.) Phosphates. Mineralogical Society of America: pp. 13–50.

  • Piper, A. M. (1944). A graphic procedure in the geochemical interpretation of water analysis. Transactions of the American Geophysical Union, 25, 914–923.

    Article  Google Scholar 

  • Piskin, R. (1973). Evaluation of nitrate content of groundwater in Hall County, Nebraska. Ground Water, 11(6), 4–13.

    Article  Google Scholar 

  • Babu, P., Gonade, G., Bhai, H. Y., & Sinha, M. (2004). Fluoride contamination in groundwater in Ghatanji taluka, Yavatmal district, Maharashtra. Geological Survey of India, Special Publication, 83, 96–101.

    Google Scholar 

  • Ramamohana Rao, N. V., Rao, N., Surya Prakash Rao, K., & Schuiling, R. D. (1993). Fluorine distribution in waters of Nalgonda District, Andhra Pradesh India. Journal of Environmental Geology, 21, 84–89.

    Article  Google Scholar 

  • Ramesam, V., & Rajagopalan, K. (1985). Fluoride ingestion into the natural waters of hard-rock areas, Peninsular India. Journal Geological Society of India, 26, 125–132.

    CAS  Google Scholar 

  • Reddy, A. G. S., Reddy, D. V., Rao, P. N., & Prasad, K. M. (2010). Hydrogeochemicalcharacterization of fluoride rich groundwater of Wailapalli watershed, Nalgonda district,Andhra Pradesh,India. Environmental Monitoring and Assessment, 171, 561–577.

    Article  CAS  Google Scholar 

  • Reddy, A. G. S. (2014). Zeochemical evaluation of nitrate and fluoride contamination in varied hydrogeological environs of Prakasam district, Southern India. Journal for Environmental Earth Sciences, 71(10), 4473–4495. doi:10.1007/s12665-013-2841-x.

    Article  CAS  Google Scholar 

  • Ritter, W. F., & Chirnside, A. E. M. (1984). Impact of land use on groundwater quality in Southern Delaware. Ground Water, 22(1), 38–47.

    Article  CAS  Google Scholar 

  • Rode, Sanjay (2009).Drinking water supply management in Municipal Corporation of Maharashtra. Pg.31.

  • Shaji, E., Bindu, J., & Thambi, D. S. (2007). High fluoride in groundwater of Palaghat district Kerala. Current Science, 92(2), 240–245.

    CAS  Google Scholar 

  • Saxena, V., & Ahmed, S. (2001). Dissolution of fluoride in groundwater: a water-rock interaction study. Environmental Geology Journal, 40(9), 1084–1087. doi:10.1007/s002540100290.

    Article  CAS  Google Scholar 

  • Sayeed Juned, A., Bhosle Arjun B, Lolage Yogesh P., Zafar S Khan and Bembrekar Shivraj K. (2015). Seasonal variation of fluoride content in ground water and its environmental impact at South Nanded City in Maharashtra. Special Vol on ‘Clean Earth-Green Earth’, SRTM University’s Research Journal of Science Vol.no.1, pp.25–29.

  • Subba Rao, N., Krishna Rao, G., & John Devadas, D. (1998). Variation of fluoride in groundwater of crystalline terrain. Journal of Environmental Hydrology, 6(paper 3), 1–5.

    Google Scholar 

  • Subba Rao, N., & Rao, A. T. (2003). Fluoride in groundwater in a developing area of Guntur district, Andhra Pradesh India. Journal of Applied Geochemistry, 5(2), 94–100.

    Google Scholar 

  • Subba Rao, N. (2006). Seasonal variation of groundwater quality in a part of Guntur District, Andhra Pradesh, India. Environmental Geology, 49, 413–429. doi:10.1007/s00254-005-0089-9.

    Article  Google Scholar 

  • UN. (1991). Year book of the United Nations (Vol. 45, 317). New York: Department of Public Information United Nations.

    Google Scholar 

  • Walker, W. H. (1973). Ground-Water Nitrate Pollution in Rural Areas. Ground Water, 11(5), 19–22.

  • Wedepohl, K. H. (Ed.). (1969). Handbook of geochemistry (Vol. II-1). Berlin: Springer.

    Google Scholar 

  • Wetselar, R., Fox, J. J., Smith, G. D., Rum, A. M., Moermanto, R.J. & Ahmed, I. (1993). Ground water nitrate in East Java, Indonesia. Australian Geological Survey Organization, Journal Geology and Geophysics, 14, 273–277.

  • Wodeyar, B. K., & Sreenivasan, G. (1996). Occurrence of fluoride in the ground waters and its impact in Peddavankahalla Basin, Bellary District, Karnataka—a preliminary study. Journal Current Science, 70(1), 71–74.

    CAS  Google Scholar 

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Pandith, M., Kaplay, R., Potdar, S.S. et al. Impact of urbanization coupled with drought situations on groundwater quality in shallow (basalt) and deeper (granite) aquifers with special reference to fluoride in Nanded-Waghala Municipal Corporation, Nanded District, Maharashtra (India). Environ Monit Assess 189, 428 (2017). https://doi.org/10.1007/s10661-017-6098-9

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