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Comparison of different methods for extraction of polycyclic aromatic hydrocarbons (PAHs) from Sicilian (Italy) coastal area sediments

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Abstract

This paper describes a work aimed at improving the conditions of an extraction method, coupling GC-MS determination, for the analysis without cleanup phase, of polycyclic aromatic hydrocarbons (PAHs) from sediment samples. The automatic Soxhlet extraction in warm mode (using Extraction System B-811 Standard, Büchi) has demonstrated advantages for automation, reduced extraction time, and lower solvent use than for conventional Soxhlet extraction. Under these conditions, the recoveries are very good as they resulted greater than 85 % and, in most of the cases, near 100 %. The repeatability is also satisfactory (relative standard deviation less than 15 %). The detection limits are also acceptable and ranged from 0.001 to0.01 μg/kg dry weight. Fifty-four sediment samples were collected. The total concentration of the 17 compounds investigated, in samples of sediments collected from three Sicilian coastal areas, expressed as the sum of concentrations, varies from 99 to 11,557 μg/kg of dry matrix; concentrations of total PAHs in the sediments of Cala are two to three times higher than the other stations.

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Authors and Affiliations

  1. Dipartimento di Scienze della Terra e del Mare (DiSTeM), Università di Palermo, Via Archirafi 22, 90123, Palermo, Italy

    Sabrina Frenna & Nicola Tuzzolino

  2. Dipartimento di Scienze della terra e del Mare, Università di Palermo, Via Archirafi 22, 90123, Palermo, Italy

    Antonio Mazzola

  3. Dipartimento di Chimica, Università di Palermo, Viale delle Scienze, Ed. 17, 90128, Palermo, Italy

    Santino Orecchio

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  1. Sabrina Frenna
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  2. Antonio Mazzola
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  3. Santino Orecchio
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  4. Nicola Tuzzolino
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Correspondence to Santino Orecchio.

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Frenna, S., Mazzola, A., Orecchio, S. et al. Comparison of different methods for extraction of polycyclic aromatic hydrocarbons (PAHs) from Sicilian (Italy) coastal area sediments. Environ Monit Assess 185, 5551–5562 (2013). https://doi.org/10.1007/s10661-012-2966-5

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  • DOI: https://doi.org/10.1007/s10661-012-2966-5

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