Abstract
Polychlorinated biphenyls (PCBs) were measured in raw and finished drinking water at seven Public Water Systems (PWSs) along the Hudson River as part of a baseline monitoring program prior to the extensive sediment dredging of the Upper Hudson River. Water samples were either analyzed using an Aroclor method (based on USEPA Method 508) or a congener method (Modified Green Bay Mass Balance Method). Using the congener-based method, raw water concentrations ranged from <9.3 to 164.3 ng/L and finished water concentrations ranged from <9.3 to 186.6 ng/L. Using the Aroclor method, finished water concentrations ranged from <5.0 to 200.9 ng/L. Most finished water samples above 73.0 ng/L were from a PWS with wells drilled near the river. Excluding the well data, total PCB concentrations in raw water at systems in the Upper River were similar to concentrations at systems in the Lower River, though the congener patterns differed. Paired comparison of total PCB concentrations using the two analytical methods showed good agreement, although raw water showed a different relationship than finished water.
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References
Albro, P. W., Corbett, J. T., & Schroeder, J. L. (1981). Quantitative characterization of polychlorinated biphenyl mixtures (Aroclors 1248, 1254, and 1260) by gas chromatography using capillary columns. Journal of Chromatography A, 205, 103–111.
Ballschmiter, K., & Zell, M. (1980). Analysis of polychlorinated biphenyls (PCB) by glass capillary gas chromatography. Fresenius’ Journal of Analytical Chemistry, 302, 20–31.
Bopp, R. F., Chillrud, S. N., Shuster, E. L., Simpson, H. J., & Estabrooks, F. D. (1998). Trends in chlorinated hydrocarbon levels in Hudson River Basin sediments. Environmental Health Perspectives, 106(S4), 1075–1081.
Bush, B., Connor, S., & Snow, J. (1982). Glass capillary gas chromatography for sensitive, accurate polychlorinated biphenyl analysis. Journal of Association of Official Analytical Chemists, 65, 555–566.
Chevreuil, M., & Granier, L. (1991). Drinking water pollution by polychlorinated biphenyls in the Paris area (France). Chemosphere, 23, 1637–1642.
Erickson, M. D. (1997). The analytical chemistry of PCBs (2nd ed.). Boca Raton: CRC.
Erickson, M. D., & Stanley, J. S. (1982). Methods of analysis for By-Product PCBs—Literature review and preliminary recommendations. Interim report no. 1. Washington: Office of Toxic Substances, USEPA. EPA 560/5-82-005; NTIS No. PB83 126 573.
Frame, G. M. (1997). A collaborative study of 209 PCB congeners and 6 Aroclors on 20 different HRGC columns 2. Semi-quantitative Aroclor congener distributions. Fresenius’ Journal of Analytical Chemistry, 357, 714–722.
Frame, G., Cochran, J., & Bowadt, S. (1996a). Complete PCB congener distributions for 17 Aroclor mixtures determined by 3 HRGC systems optimized for comprehensive, quantitative, congener-specific analysis. Journal of High Resolution Chromatography, 19(12), 657–668.
Frame, G. M., Wagner, R. E., Carnahan, J. C., Brown, J. F., Jr, May, R. J., Smullen, L. A., et al. (1996b). Comprehensive, quantitative, congener specific analyses of eight Aroclors and complete PCB congener assignments on DB-1 capillary GC columns. Chemosphere, 33(4), 603–623.
General Electric (2008). Hudson River PCBs superfund site October 2008 monthly status report. Albany, NY: General Electric.
Litten, S., Fowler, B., & Luszniak, D. (2002). Identification of a novel PCB source through analysis of 209 PCB congeners by U.S. EPA modified method 1668. Chemosphere, 46(9), 1457–1459.
Metcalf & Eddy (1989). Waterford drinking water supply evaluation. Wakefield, MA: Metcalf and Eddy.
Mullin, M. D., Pochini, C. M., McCrindle, S., Romkes, M., Safe, S. H., & Safe, L. M. (1984). High-resolution PCB analysis: Synthesis and chromatographic properties of all 209 PCB congeners. Environmental Science and Technology, 18, 468–476.
NYSDEC (2004). Record of decision, GE Hudson Falls Plant Site Operable Units No. 2A–2D, Village of Hudson Falls, Town of Kingsbury, Washington County, New York. Site Number 5-58-013.
NYSDOH (1986). Waterford water works: A status report. Albany, NY: NYSDOH.
O’Brien & Gere (1982). Hudson River water PCB treatability study. Syracuse, NY: O’Brien and Gere.
Samara, F., Tsai, C., & Aga, D. (2006). Determination of potential sources of PCBs and PBDEs in sediments of the Niagara River. Environmental Pollution, 139, 489–497.
Swackhamer, D. L. (1987). Quality assurance plan for Green Bay mass balance study. I. PCBs and Dieldrin. Chicago, Illinois: USEPA Great Lakes National Program Office.
USEPA (2002). EPA superfund record of decision, Hudson River PCBs Site, Hudson Falls to New York City, New York. Washington, D.C.: USEPA.
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Palmer, P.M., Wilson, L.R., Casey, A.C. et al. Occurrence of PCBs in raw and finished drinking water at seven public water systems along the Hudson River. Environ Monit Assess 175, 487–499 (2011). https://doi.org/10.1007/s10661-010-1546-9
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DOI: https://doi.org/10.1007/s10661-010-1546-9