Tosylhydrazide was shown to be an effective reductant in protic solvents for the peroxide ozonolysis products of ∆3-carene, (–)-α-pinene, and (S)-limonene. Either α,ω-ditosylhydrazones or α,ω-ketotosylhydrazonoacids were formed depending on the nature of the trisubstituted cycloalkene.
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The work was supported financially by a grant from the Republic of Bashkortostan for Young Scientists and Young Scientific Groups (No. 48 dated Feb. 18, 2016).
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Translated from Khimiya Prirodnykh Soedinenii, No. 5, September–October, 2017, pp. 758–761.
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Legostaeva, Y.V., Garifullina, L.R., Nazarov, I.S. et al. Transformations by Tosylhydrazide of Peroxide Ozonolysis Products of ∆3-Carene, (–)-α-Pinene, and (S)-Limonene. Chem Nat Compd 53, 891–894 (2017). https://doi.org/10.1007/s10600-017-2149-2
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DOI: https://doi.org/10.1007/s10600-017-2149-2