Acylation by suberic acid chloride of chlorin with two oximated isosteviol groups on its periphery produced for the first time a macrocyclic system containing a porphyrin ring and two tetracyclic ent-beyerane frameworks.
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Acknowledgment
The work was supported by the Federal Agency for Science and Innovation (State Contract No. 02.740.11.0081); the Russian Academy of Sciences (Basic Research in Collaboration with the Siberian and Far-East Branches of the Russian Academy of Sciences, Russian State Academies of Science, CIS National Academies of Science and Branch Academies, Program No. 18 of the RAS Presidium “Development of Organic Synthetic Methods and Creation of Compounds with Valuable Applied Properties”, RAS Presidium Program No. 21 “Fundamental Sciences – Medicine”); and the RFBR (Grant 10-03-00499-a).
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Translated from Khimiya Prirodnykh Soedinenii, No. 4, July–August, 2011, pp. 542–544.
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Belykh, D.V., Mal’shakova, M.V., Korochkina, M.G. et al. First macrocycle based on chlorin and isosteviol structural elements. Chem Nat Compd 47, 612 (2011). https://doi.org/10.1007/s10600-011-0008-0
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DOI: https://doi.org/10.1007/s10600-011-0008-0