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Preparation and structure elucidation of two minor products from reaction of arglabin with chloroform in the presence of a crown ether

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Abstract

A pentachloro derivative, the structure of which was proved by x-ray structure analysis, in addition to a new dichlorocarbene derivative were obtained for the first time by dichlorocyclopropanation of arglabin guaianolide. The stereochemistry of the principal reaction product was established.

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Correspondence to R. I. Jalmakhanbetova.

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Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 450–452, September–October, 2007.

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Jalmakhanbetova, R.I., Atazhanova, G.A., Raldugin, V.A. et al. Preparation and structure elucidation of two minor products from reaction of arglabin with chloroform in the presence of a crown ether. Chem Nat Compd 43, 548–551 (2007). https://doi.org/10.1007/s10600-007-0188-9

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  • DOI: https://doi.org/10.1007/s10600-007-0188-9

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