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Effective bimetallic composite catalysts for the synthesis of arylated furans and thiophenes in aqueous media

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Chemistry of Heterocyclic Compounds Aims and scope

N-(4,6-Dimethylpyrimidin-2-yl)-5-phenylisoxazole-3-carboxamide was used as a ligand for obtaining bimetallic boron-containing heterogeneous catalysts Pd–Ni(Co)–B–L (Ni(Co):Pd = 9:1). The obtained composites were highly active as catalysts of Suzuki reaction in aqueous media, allowing to develop convenient methods for the synthesis of heterobiaryls containing furyl and thienyl rings.

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Notes

  1. TON (turnover number) – the number of catalytic cycles, determined as the number of product molecules formed on one molecule (or atom) of the catalyst (a dimensionless quantity). TOF (turnover frequency) – the number of catalytic cycles in a unit of time.

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This work was performed with financial support from the Russian Foundation for Basic Research (grant 18-5800013-Bel_a), the Belarusian Republican Foundation for Fundamental Research (grant Х18Р-010), and within the framework of RUDN University Program 5-100.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, 1 Build. 3 Leninskie Gory, Moscow, 119991, Russia

    Nikolay A. Bumagin & Roman S. Alekseyev

  2. Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, 13 Surganov St, 220072, Minsk, Belarus

    Sergey K. Petkevich & Vladimir I. Potkin

  3. RUDN University, 6 Miklukho-Maklaya St, Moscow, 117198, Russia

    Alexey V. Kletskov

Authors
  1. Nikolay A. Bumagin
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  2. Sergey K. Petkevich
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  3. Alexey V. Kletskov
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  4. Roman S. Alekseyev
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  5. Vladimir I. Potkin
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Correspondence to Nikolay A. Bumagin or Vladimir I. Potkin.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2019, 55(6), 508–516

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Bumagin, N.A., Petkevich, S.K., Kletskov, A.V. et al. Effective bimetallic composite catalysts for the synthesis of arylated furans and thiophenes in aqueous media. Chem Heterocycl Comp 55, 508–516 (2019). https://doi.org/10.1007/s10593-019-02492-8

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