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Simple benzothiazole chemosensor for detection of cyanide anions via nucleophilic addition

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Chemistry of Heterocyclic Compounds Aims and scope

A benzothiazolium salt containing carbazole group has been synthesized in a good yield via simple condensation reaction. Its photophysical properties and affinity for cyanide anion (tetrabutylammonium cyanide) have been investigated. The compound exhibited quick and well visible UV/Vis absorption and fluorescence responses to cyanide anion in MeCN, as the yellow color faded and the orange fluorescence disappeared. The in situ analysis by 1H NMR indicated that the cyanide anion was added to the C=N bond in the benzothiazolyl group.

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This work was supported by the National Natural Science Foundation of China (21672130, 51373069) and the Natural Science Foundation of Shandong Province (ZR2013BM005, ZR2015BL011), Colleges and Universities Science and Technology Foundation of Shandong Province (J16LA08), the Fund of Graduate Innovation Foundation of University of Jinan, GIFUJN (S1504).

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Authors and Affiliations

  1. School of Material Science and Engineering, Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, 336 Nanxinzhuang West St., Jinan, 250022, China

    Xueying Yu, Kangnan Wang, Duxia Cao, Qianqian Wu, Ruifang Guan, Yongxiao Xu & Yatong Sun

  2. State Key Laboratory of Crystal Materials, Shandong University, 27 Shanda South St., Jinan, 250100, China

    Zhiqiang Liu

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  1. Xueying Yu
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  2. Kangnan Wang
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  3. Duxia Cao
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  4. Qianqian Wu
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  5. Ruifang Guan
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  6. Yongxiao Xu
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  7. Yatong Sun
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  8. Zhiqiang Liu
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Correspondence to Duxia Cao or Zhiqiang Liu.

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Published in Khimiya Geterotsiklicheskikh Soedinenii, 2017, 53(1), 42–45

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Yu, X., Wang, K., Cao, D. et al. Simple benzothiazole chemosensor for detection of cyanide anions via nucleophilic addition. Chem Heterocycl Comp 53, 42–45 (2017). https://doi.org/10.1007/s10593-017-2019-7

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  • DOI: https://doi.org/10.1007/s10593-017-2019-7

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