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Heterocyclic carbene complexes of nickel, palladium, and copper(I) as effective catalysts for the reduction of ketones*

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Chemistry of Heterocyclic Compounds Aims and scope

Carbene complexes of nickel, palladium, and copper(I) effectively catalyze the reduction of aromatic ketones under the influence of 2-propanol in the presence of potassium hydroxide. Bis(1,3-dimethylbenzimidazol-2-ylidene)copper(I) iodide and the polymeric complex of crown-biscarbene with copper(I) iodide show the highest catalytic efficiency.

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Authors and Affiliations

  1. L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, The National Academy of Sciences of Ukraine, 70, R. Luxemburg ul., Donetsk, 83114, Ukraine

    N. I. Korotkikh, V. Sh. Saberov, A. V. Kiselev, N. V. Glinyanaya, K. A. Marichev, T. M. Pekhtereva & O. P. Shvaika

  2. Institute of Macromolecular Chemistry, The National Academy of Sciences of Ukraine, 48 Kharkivske Highway, Kyiv, 02160, Ukraine

    G. V. Dudarenko

  3. M. V. Lomonosov Moscow State University, 1/3 Leninskie gory, Moscow, 119991, Russia

    N. A. Bumagin

Authors
  1. N. I. Korotkikh
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  2. V. Sh. Saberov
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  3. A. V. Kiselev
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  4. N. V. Glinyanaya
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  5. K. A. Marichev
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  6. T. M. Pekhtereva
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  8. N. A. Bumagin
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  9. O. P. Shvaika
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Correspondence to N. I. Korotkikh.

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*Dedicated to the memory of Academician E. Lukevics.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No.12, 1854-1864, December, 2011.

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Korotkikh, N.I., Saberov, V.S., Kiselev, A.V. et al. Heterocyclic carbene complexes of nickel, palladium, and copper(I) as effective catalysts for the reduction of ketones*. Chem Heterocycl Comp 47, 1551–1560 (2012). https://doi.org/10.1007/s10593-012-0947-9

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