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Photo- and thermochromic spiranes. 31.* Photochromic cationic spiropyrans with a pyridinium fragment in the aliphatic side chain*2

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Chemistry of Heterocyclic Compounds Aims and scope

Syntheses are reported for cationic indoline spiropyrans with a quaternized pyridinium fragment in the aliphatic side chain, which display photochromic properties in solution. The major effect of introducing a quaternized pyridinium fragment into the benzopyran part of the spiropyran entails a significant decrease in the rate of thermal relaxation processes.

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Authors and Affiliations

  1. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-the-Don, 344006, Russia

    N. A. Voloshin & S. O. Bezugliy

  2. Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-the-Don, 344090, Russia

    E. V. Solov’eva, A. V. Metelitsa & V. I. Minkin

Authors
  1. N. A. Voloshin
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  2. S. O. Bezugliy
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  3. E. V. Solov’eva
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  4. A. V. Metelitsa
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  5. V. I. Minkin
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Correspondence to E. V. Solov’eva.

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*2Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee.

*For Communication 30 see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1513-1522, October, 2008.

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Voloshin, N.A., Bezugliy, S.O., Solov’eva, E.V. et al. Photo- and thermochromic spiranes. 31.* Photochromic cationic spiropyrans with a pyridinium fragment in the aliphatic side chain*2 . Chem Heterocycl Comp 44, 1229–1237 (2008). https://doi.org/10.1007/s10593-009-0175-0

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  • DOI: https://doi.org/10.1007/s10593-009-0175-0

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