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Heterocyclization of 1,3-Butadienethiolates

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Abstract

Condensation of derivatives of ethoxymethylenecyanoacetic acid with cyanothioacetamide with base catalysis gave butadienethiolates and mercaptopyridines. On interaction with alkyl halides, butadienethiolates are cyclized into alkylthiopyridines, but their reactions with phenacyl bromides give substituted thiazoles.

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Authors and Affiliations

  1. Taras Shevchenko Lugansk State Pedagogical University, Lugansk, 91011, Ukraine

    V. D. Dyachenko & R. P. Tkachev

  2. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, 02094, Ukraine

    A. N. Chernega

Authors
  1. V. D. Dyachenko
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  2. R. P. Tkachev
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  3. A. N. Chernega
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, 589–596, April, 2005.

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Dyachenko, V.D., Tkachev, R.P. & Chernega, A.N. Heterocyclization of 1,3-Butadienethiolates. Chem Heterocycl Compd 41, 503–510 (2005). https://doi.org/10.1007/s10593-005-0179-3

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  • DOI: https://doi.org/10.1007/s10593-005-0179-3

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