Abstract
The results of combined radiochemical procedure for the determination of plutonium, americium and90Sr (via measurement of90Y) in the soil samples from SNTS are presented. The processes of co-precipitation of these nuclides with calcium fluoride in the strong acid solutions have been investigated. The conditions for simultaneous separation of americium and yttrium using extraction chromatography have been studied. It follows from analyses of real soil samples that the procedure developed provides the chemical recovery of plutonium and yttrium in the range of 50–95% and 60–95%, respectively. The execution of the procedure requires 3.5 working days including a sample decomposition study.
Similar content being viewed by others
References
J. J. LaRosa et al.: J. Environ. Radioactivity17 (1992) 183.
A. E. Nevissi: J. Radioanal. Nucl. Chem., Articles,156 (1992) 243.
Preliminary patent of Kazakhstan:The method for separation and concentration of plutonium from soils, application for invention rights N 951051.1, 02.04.96.
F. Rahn, A. Adamantiades, J. Kenton, C. Braun:A Guide to Nuclear Power Technology, New York 1984, p. 32.
Pavlotskaya F. I. et al.: Radiokhimiya,3 (1996) 193.
V. Mikulaj, V. Svec: J. Radioanal. Nucl. Chem., Letters175 (1993) 317.
L. Matel, V. Mikulaj, P. Rajec: J. Radioanal. Nucl. Chem., Letters175 (1993) 41.
K. Sekine, T. Imai, A. Kasai: Talanta34 (1987) 567.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kazachevskii, I.V., Lukashenko, S.N., Chumikov, G.N. et al. Combined radiochemical procedure for determination of plutonium, americium and strontium-90 in the soil samples from SNTS. Czech J Phys 49 (Suppl 1), 445–460 (1999). https://doi.org/10.1007/s10582-999-0060-1
Issue Date:
DOI: https://doi.org/10.1007/s10582-999-0060-1