Abstract
Extraction of nitric acid, perchloric acid, americium, and europium with dialkyldiarylamides of 2,6-pyridinecarboxylic (dipicolinic) acid in polar fluorinated solvents (diluents) was analysed. Among the extractants studied N, N′-diethyl-N, N′-ditolylamide dipicolinate is characterized by the best extraction properties. On passing from nitric to perchloric acid solutions extraction of metals sharply increases. Extraction of americium from nitric acid solutions is significantly greater as compared with europium (separation coefficient reaches 6), whereas extraction of americium and europium from perchloric acid solutions is nearly similar. The effect of diluent on the extraction was analyzed; for different diluents the maximum of extraction from perchloric acid solutions shifts form 3 to 6 M.
Similar content being viewed by others
References
Nigond L. et al.: Sep. Sci. & Technol. 30 (1995) 2075.
Mowafy E.A., Shalash A.M., and El-Naggar I.M.: Ind. J. of Chem. A 42 (12) (2003) 3012.
Shimada A., Yaita T., Narita H., Tachimori S., and Okuno K.: Solv. Extr. Ion Exch. 22 (2) (2004) 147.
Alyapyshev M. Yu., Babain V. A., and Smirnov I. V.: Radiochemistry (Radiokhimiya), Engl.Ed. 46 (3) (2004) 270.
Babain V. A. et al.: In: Proc. of ISEC-2005 Int. Conf., paper A310.
Peterman D. R. et al.: Proc. of Global 2005 Int. Conf., Tsukuba, Japan, 9–13 Oct., 2005, paper 211.
Chmutova M. K., Litvina M. N., Nesterova N. P., Myasoedov B. F., and Kabachnik M. I.: Solv. Extr. Ion Exch. 10 (3) (1992) 439.
Rais J., Tachimori S., Selucky P, and Kadlecova L.: Sep. Sci. & Tech. 29 (2) (1994) 261.
Alyapyshev M. Yu., Babain V. A., Smirnov I. V., and Shadrin A. Yu.: Radiochemistry (Radiokhimiya) Engl.Ed., 48 (4) (2006), 331.
Nikitskaya E. S., Usovskaya V. S., and Rubtsov M. V.: Zh.Obsch.Khimii (Russian J. General Chem.), 28 (1958), 161.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Alyapyshev, M., Babain, V.A., Smirnov, I.V. et al. Separation of americium and europium from solutions of nitric and perchloric acid using dipicolinic acid diamides. Czech J Phys 56, D469–D475 (2006). https://doi.org/10.1007/s10582-006-1053-y
Issue Date:
DOI: https://doi.org/10.1007/s10582-006-1053-y