Abstract
In this study, cellulose nanocrystals (CNC) were produced with different sizes; they were then carboxymethylated to generate carboxymethylated CNC (CCNC) to be used as dispersants for a kaolinite suspension at different pH. It was observed that larger CNC rendered CCNC with a higher surface charge. The largest CCNC (CCNC3) adsorbed more on kaolinite particles and impacted the surface charge density of the particles more dramatically than did other CCNCs. Furthermore, CCNC3 stabilized the kaolinite suspension at a lower dosage and to a higher degree than other CCNCs, and the strength of stability was greater for CCNC3 compared to the other ones. Also, CCNC was a much better dispersant than CNC as it impacted the level and strength of kaolinite system’s stability more pronouncedly. Furthermore, a larger CCNC, which can be produced under milder hydrolysis reactions of pulp, can respond to carboxymethylation more effectively and make a more efficient dispersant for the kaolinite suspension, which is advantageous for industrial applications.
Similar content being viewed by others
References
Aras A (2004) The change of phase composition in kaolinite-and illite-rich clay-based ceramic bodies. Appl Clay Sci 24(3–4):257–269
Beck-Candanedo S, Roman M, Gray DG (2005) Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions. Biomacromol 6(2):1048–1054
Bharti B, Meissner J, Findenegg GH (2011) Aggregation of silica nanoparticles directed by adsorption of lysozyme. Langmuir 27(16):9823–9833
Brunelli A, Zabeo A, Semenzin E, Hristozov D, Marcomini A (2016) Extrapolated long-term stability of titanium dioxide nanoparticles and multi-walled carbon nanotubes in artificial freshwater. J Nanopart Res 18(5):113–125
Cao X, Habibi Y, Lucia LA (2009) One-pot polymerization, surface grafting, and processing of waterborne polyurethane-cellulose nanocrystal nanocomposites. J Mater Chem 19(38):7137–7145
Chang JKW, Duret X, Berberi V, Zahedi-Niaki H, Lavoie JM (2018) Two-step thermochemical cellulose hydrolysis with partial neutralization for glucose production. Front Chem 6:1–11
Chen D, van de Ven TG (2016) Flocculation kinetics of precipitated calcium carbonate (PCC) with sterically stabilized nanocrystalline cellulose (SNCC). Colloids Surf A 506:789–793
Chen J, Eraghi Kazzaz A, AlipoorMazandarani N, Hosseinpour Feizi Z, Fatehi P (2018) Production of flocculants, adsorbents, and dispersants from lignin. Molecules 23(4):868–893
Cheng H, Liu Q, Zhang J, Yang J, Frost RL (2010) Delamination of kaolinite–potassium acetate intercalates by ball-milling. J Colloid Interface Sci 348(2):355–359
Dodi G, Hritcu D, Popa MI (2011) Carboxymethylation of guar gum: synthesis and characterization. Cellul Chem Technol 45(3):171–176
Feizi ZH, Kazzaz AE, Kong F, Fatehi P (2019) Evolving a flocculation process for isolating lignosulfonate from solution. Sep Purif Technol 222:254–263
Ferek RJ, Reid JS, Hobbs PV, Blake DR, Liousse C (1998) Emission factors of hydrocarbons, halocarbons, trace gases and particles from biomass burning in Brazil. J Geophys Res Atmos 103(D24):32107–32118
Gan L, Zhou M, Yang D, Qiu X (2013) Preparation and evaluation of carboxymethylated lignin as dispersant for aqueous graphite suspension using Turbiscan Lab analyzer. J Dispersion Sci Technol 34(5):644–650
Gharanjig H, Gharanjig K, Khosravi A (2019) Effects of the side chain density of polycarboxylate dispersants on dye dispersion properties. Color Technol 135:160–168
Gharehkhani S, Ghavidel N, Fatehi P (2018) Kraft lignin-tannic acid as a green stabilizer for oil/water emulsion. ACS Sustainable Chem Eng 7(2):2370–2379
Hamedi MM, Hajian A, Fall AB, Hakansson K, Salajkova M, Lundell F, Wagberg L, Berglund LA (2014) Highly conducting, strong nanocomposites based on nanocellulose-assisted aqueous dispersions of single-wall carbon nanotubes. ACS Nano 8(3):2467–2476
Hanif Z, Ahmed FR, Shin SW, Kim YK, Um SH (2014) Size-and dose-dependent toxicity of cellulose nanocrystals (CNC) on human fibroblasts and colon adenocarcinoma. Colloids Surf B 119:162–165
He W, Gao W, Fatehi P (2017) Oxidation of kraft lignin with hydrogen peroxide and its application as a dispersant for kaolin suspensions. ACS Sustainable Chem Eng 5(11):10597–10605
Kamiya H, Fukuda Y, Suzuki Y, Tsukada M, Kakui T, Naito M (1999) Effect of polymer dispersant structure on electrosteric interaction and dense alumina suspension behavior. J Am Ceram Soc 82(12):3407–3412
Kaombe DD, Lenes M, Toven K, Glomm WR (2013) Turbiscan as a tool for studying the phase separation tendency of pyrolysis oil. Energy Fuels 27(3):1446–1452
Kazzaz AE, Fatehi P (2020) Fabrication of amphoteric lignin and its hydrophilicity/oleophilicity at oil/water interface. J Colloid Interf Sci 561:231–243
Kazzaz AE, Feizi ZH, Fatehi P (2018a) Interaction of sulfomethylated lignin and aluminum oxide. Colloid Polym Sci 296(11):1867–1878
Kazzaz AE, Feizi ZH, Kong F, Fatehi P (2018b) Interaction of poly (acrylic acid) and aluminum oxide particles in suspension: particle size effect. Colloids Surf A 556:218–226
Kazzaz AE, Feizi ZH, Fatehi P (2019) Grafting strategies for hydroxy groups of lignin for producing materials. Green Chem 21(21):5714–5752
Klosek-Wawrzyn E, Małolepszy J, Murzyn P (2013) Sintering behavior of kaolin with calcite. Procedia Eng 57:572–582
Koci K, Matějka V, Kovář P, Lacný Z, Obalová L (2011) Comparison of the pure TiO2 and kaolinite/TiO2 composite as catalyst for CO2 photocatalytic reduction. Catal Today 161(1):105–109
Konduri MK, Fatehi P (2016) Synthesis and characterization of carboxymethylated xylan and its application as a dispersant. Carbohydr Polym 146:26–35
Konduri MK, Fatehi P (2018a) Designing anionic lignin based dispersant for kaolin suspensions. Colloids Surf A 538:639–650
Konduri MK, Fatehi P (2018b) Adsorption and dispersion performance of oxidized sulfomethylated kraft lignin in coal water slurry. Fuel Process Technol 176:267–275
Lee HV, Hamid SBA, Zain SK (2014) Conversion of lignocellulosic biomass to nanocellulose: structure and chemical process. Sci World J 2014:1–20
Lee HJ, Lee HS, Seo J, Kang YH, Kim W, Kang THK (2019) State-of-the-art of cellulose nanocrystals and optimal method for their dispersion for construction-related applications. Appl Sci 9(3):426–440
Ma X, Cheng Y, Qin X, Guo T, Deng J, Liu X (2017) Hydrophilic modification of cellulose nanocrystals improves the physicochemical properties of cassava starch-based nanocomposite films. LWT-Food Sci Technol 86:318–326
Malaspina DC, Faraudo J (2019) Molecular insight into the wetting behavior and amphiphilic character of cellulose nanocrystals. Adv Colloid Interface Sci 267:15–25
Mariano M, El Kissi N, Dufresne A (2015) Melt processing of cellulose nanocrystal reinforced polycarbonate from a masterbatch process. Eur Polym J 69:208–223
Ming S, Chen G, Wu Z, Su L, He J, Kuang Y, Fang Z (2016) Effective dispersion of aqueous clay suspension using carboxylated nanofibrillated cellulose as dispersant. RSC Adv 6(44):37330–37336
Moayedi H, Huat BB, Kazemian S, Daneshmand S, Moazami D, Niroumand H (2011a) Electrophoresis of suspended kaolinite in multivalent electrolyte solution. Int J Electrochem Sci 6:6514–6524
Moayedi H, Asadi A, Moayedi F, Huat BB (2011b) Zeta potential of tropical soil in presence of polyvinyl alcohol. Int J Electrochem Sci 6(5):1294–1306
Montanari S, Roumani M, Heux L, Vignon MR (2005) Topochemistry of carboxylated cellulose nanocrystals resulting from TEMPO-mediated oxidation. Macromolecules 38(5):1665–1671
Murray HH, Lyons SC (1956) Correlation of paper-coating quality with degree of crystal perfection of kaolinite. Clays Clay Miner 4:31–40
Naderi A, Lindström T, Sundström J (2014) Carboxymethylated nanofibrillated cellulose: rheological studies. Cellulose 21(3):1561–1571
Olivier C, Moreau C, Bertoncini P, Bizot H, Chauvet O, Cathala B (2012) Cellulose nanocrystal-assisted dispersion of luminescent single-walled carbon nanotubes for layer-by-layer assembled hybrid thin films. Langmuir 28(34):12463–12471
Ostolska I, Wiśniewska M (2014) Application of the zeta potential measurements to explanation of colloidal Cr2O3 stability mechanism in the presence of the ionic polyamino acids. Colloid Polym Sci 292(10):2453–2464
Palomino AM, Santamarina JC (2005) Fabric map for kaolinite: effects of pH and ionic concentration on behavior. Clays Clay Miner 53(3):211–223
Qin Y, Yu L, Wu R, Yang D, Qiu X, Zhu JY (2016) Biorefinery lignosulfonates from sulfite-pretreated softwoods as dispersant for graphite. ACS Sustainable Chem Eng 4(4):2200–2205
Reid MS, Villalobos M, Cranston ED (2017) The role of hydrogen bonding in non-ionic polymer adsorption to cellulose nanocrystals and silica colloids. Curr Opin Colloid Interface Sci 29:76–82
Rubio-Hernández FJ, Páez-Flor NM, Gómez-Merino AI, Sánchez-Luque FJ, Delgado-García R, Goyos-Pérez L (2016) The influence of high-concentration Na hexametaphosphate dispersant on the rheological behavior of aqueous kaolin dispersions. Clays Clay Miner 64(3):210–219
Santi C, Certini G, D’Acqui LP (2006) Direct determination of organic carbon by dry combustion in soils with carbonates. Commun Soil Sci Plant Anal 37(1–2):155–162
Singh BP, Nayak S, Samal S, Bhattacharjee S, Besra L (2012) Characterization and dispersion of multiwalled carbon nanotubes (MWCNTs) in aqueous suspensions: surface chemistry aspects. J Dispersion Sci Technol 33(7):1021–1029
Sjöberg M, Bergström L, Larsson A, Sjöström E (1999) The effect of polymer and surfactant adsorption on the colloidal stability and rheology of kaolin dispersions. Colloids Surf A 159(1):197–208
Tan C, Peng J, Lin W, Xing Y, Xu K, Wu J, Chen M (2015) Role of surface modification and mechanical orientation on property enhancement of cellulose nanocrystals/polymer nanocomposites. Eur Polym J 62:186–197
Tang J, Sisler J, Grishkewich N, Tam KC (2017) Functionalization of cellulose nanocrystals for advanced applications. J Colloid Interface Sci 494:397–409
Tombacz E, Szekeres M (2006) Surface charge heterogeneity of kaolinite in aqueous suspension in comparison with montmorillonite. Appl Clay Sci 34(1–4):105–124
Wågberg L, Decher G, Norgren M, Lindström T, Ankerfors M, Axnäs K (2008) The build-up of polyelectrolyte multilayers of microfibrillated cellulose and cationic polyelectrolytes. Langmuir 24(3):784–795
Wang Q, Li Y, Wang Y (2011) Optimizing the weight loss-on-ignition methodology to quantify organic and carbonate carbon of sediments from diverse sources. Environ Monit Assess 174(1–4):241–257
Wei Z, Gao Y (2016) Physicochemical properties of β-carotene emulsions stabilized by chitosan-chlorogenic acid complexes. LWT-Food Sci Technol 71:295–301
Yang L, Lu S, Li J, Zhang F, Cha R (2016) Nanocrystalline cellulose-dispersed AKD emulsion for enhancing the mechanical and multiple barrier properties of surface-sized paper. Carbohydr Polym 136:1035–1040
Yukselen Y, Kaya A (2003) Zeta potential of kaolinite in the presence of alkali, alkaline earth and hydrolyzable metal ions. Water Air Soil Pollut 145(1–4):155–168
Acknowledgments
This work was supported by NSERC, Canada Research Chairs, Canada Foundation for Innovations and Northern Ontario Heritage Fund Corporation.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare no competing financial interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Hosseinpour Feizi, Z., Fatehi, P. Carboxymethylated cellulose nanocrystals as clay suspension dispersants: effect of size and surface functional groups. Cellulose 27, 3759–3772 (2020). https://doi.org/10.1007/s10570-020-03024-w
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10570-020-03024-w