Abstract
In this study, a superhydrophobic cotton nonwoven fabric for oil–water separation was prepared by graft polymerization of siloxane under atmospheric pressure plasma in the medium of Air, N2 or O2. The effects of different process conditions on the contact angle, surface morphology, stability of the hydrophobic coating and the growth of nano-particles were investigated. This modified cotton nonwoven was tested for self-cleaning and oil–water separation efficiency. The surface characteristics of the prepared cotton nonwoven were systematically analyzed using scanning electron microscopy, Energy Dispersive X-ray Spectroscopy, and Fourier transform infrared spectroscopy. The water contact angle of treated nonwoven was up to 155°, and the precursor and jet movement speed have great influences on the surface morphologies and stability of the coating. Separation efficiency for oil–water mixture is higher than 97% and can be repeated for at least 10 times. Moreover, the superhydrophobic nonwoven treatment showed excellent stability toward strong acid and alkaline conditions, the resulting fabrics may be used under harsh environmental conditions.
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References
Asadollahi S, Profili J, Farzaneh M, Stafford L (2019) Development of organosilicon-based superhydrophobic coatings through atmospheric pressure plasma polymerization of HMDSO in nitrogen plasma. Materials (Basel) 12:1. https://doi.org/10.3390/ma12020219
Bashir M, Bashir S (2015) Hydrophobic-hydrophilic character of hexamethyldisiloxane films polymerized by atmospheric pressure plasma jet. Plasma Chem Plasma Process 35:739–755. https://doi.org/10.1007/s11090-015-9623-z
Chauhan P, Kumar A, Bhushan B (2018) Self-cleaning, stain-resistant and anti-bacterial superhydrophobic cotton fabric prepared by simple immersion technique. J Colloid Interface Sci 535:66–74. https://doi.org/10.1016/j.jcis.2018.09.087
Cheng Q-Y, An X-P, Li Y-D, Huang C-L, Zeng J-B (2017) Sustainable and biodegradable superhydrophobic coating from epoxidized soybean oil and ZnO nanoparticles on cellulosic substrates for efficient oil/water separation. ACS Sustain Chem Eng 5:11440–11450. https://doi.org/10.1021/acssuschemeng.7b02549
Cheng Q-Y, Liu M-C, Li Y-D, Zhu J, Du A-K, Zeng J-B (2018) Biobased super-hydrophobic coating on cotton fabric fabricated by spray-coating for efficient oil/water separation. Polym Test 66:41–47. https://doi.org/10.1016/j.polymertesting.2018.01.005
Cho E-C et al (2017) Robust multifunctional superhydrophobic coatings with enhanced water/oil separation, self-cleaning, anti-corrosion, and anti-biological adhesion. Chem Eng J 314:347–357. https://doi.org/10.1016/j.cej.2016.11.145
Cortese B, Caschera D, Federici F, Ingo GM, Gigli G (2014) Superhydrophobic fabrics for oil–water separation through a diamond like carbon (DLC) coating. J Mater Chem A 2:6781–6789. https://doi.org/10.1039/c4ta00450g
Davis R, El-Shafei A, Hauser P (2011) Use of atmospheric pressure plasma to confer durable water repellent functionality and antimicrobial functionality on cotton/polyester blend. Surf Coat Technol 205:4791–4797. https://doi.org/10.1016/j.surfcoat.2011.04.035
Gao S, Dong X, Huang J, Li S, Li Y, Chen Z, Lai Y (2018) Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil-water separation. Chem Eng J 333:621–629. https://doi.org/10.1016/j.cej.2017.10.006
Gore PM, Kandasubramanian B (2018) Heterogeneous wettable cotton based superhydrophobic Janus biofabric engineered with PLA/functionalized-organoclay microfibers for efficient oil–water separation. J Mater Chem A 6:7457–7479. https://doi.org/10.1039/c7ta11260b
Gupta RK, Dunderdale GJ, England MW, Hozumi A (2017) Oil/water separation techniques: a review of recent progresses and future directions. J Mater Chem A 5:16025–16058. https://doi.org/10.1039/c7ta02070h
Huang JY et al (2015) Robust superhydrophobic TiO2@fabrics for UV shielding, self-cleaning and oil-water separation. J Mater Chem A 3:2825–2832. https://doi.org/10.1039/c4ta05332j
Kale KH, Palaskar S (2010) Atmospheric pressure plasma polymerization of hexamethyldisiloxane for imparting water repellency to cotton fabric. Text Res J 81:608–620. https://doi.org/10.1177/0040517510385176
Lazauskas A, Baltrusaitis J, Grigaliunas V, Jucius D, Guobiene A, Prosycevas I, Narmontas P (2014) Characterization of plasma polymerized hexamethyldisiloxane films prepared by arc discharge. Plasma Chem Plasma Process 34:271–285. https://doi.org/10.1007/s11090-013-9516-y
Li D, Guo Z (2017) Stable and self-healing superhydrophobic MnO2@fabrics: applications in self-cleaning, oil/water separation and wear resistance. J Colloid Interface Sci 503:124–130. https://doi.org/10.1016/j.jcis.2017.05.015
Li J, Yan L, Tang X, Feng H, Hu D, Zha F (2016) Robust superhydrophobic fabric bag filled with polyurethane sponges used for vacuum-assisted continuous and ultrafast absorption and collection of oils from water. Adv Mater Interfaces. https://doi.org/10.1002/admi.201500770
Li J, Yuan Q, Chang X, Wang Y, Yin G, Dong C (2017) Deposition of organosilicone thin film from hexamethyldisiloxane (HMDSO) with 50 kHz/33 MHz dual-frequency atmospheric-pressure plasma jet. Plasma Sci Technol 19:045505. https://doi.org/10.1088/2058-6272/aa57e4
Liu J, Li P, Chen L, Feng Y, He WX, Yan XH, Lu XM (2016) Superhydrophilic and underwater superoleophobic modified chitosan-coated mesh for oil/water separation. Surf Coat Technol 307:171–176. https://doi.org/10.1016/j.surfcoat.2016.08.052
Liu H, Huang J, Chen Z, Chen G, Zhang K-Q, Al-Deyab SS, Lai Y (2017) Robust translucent superhydrophobic PDMS/PMMA film by facile one-step spray for self-cleaning and efficient emulsion separation. Chem Eng J 330:26–35. https://doi.org/10.1016/j.cej.2017.07.114
Marchand DJ, Dilworth ZR, Stauffer RJ, Hsiao E, Kim J-H, Kang J-G, Kim SH (2013) Atmospheric rf plasma deposition of superhydrophobic coatings using tetramethylsilane precursor. Surf Coat Technol 234:14–20. https://doi.org/10.1016/j.surfcoat.2013.03.029
Obaid M, Barakat NAM, Fadali OA, Motlak M, Almajid AA, Khalil KA (2015) Effective and reusable oil/water separation membranes based on modified polysulfone electrospun nanofiber mats. Chem Eng J 259:449–456. https://doi.org/10.1016/j.cej.2014.07.095
Pandiyaraj KN et al (2017) Effect of processing parameters on the deposition of SiOx-like coatings on the surface of polypropylene films using glow discharge plasma assisted polymerization for tissue engineering applications. Vacuum 143:412–422. https://doi.org/10.1016/j.vacuum.2017.06.046
Rau C, Kulisch W (1994) Mechanisms of plasma polymerization of various silico-organic monomers. Thin Solid Films 249:28–37. https://doi.org/10.1016/0040-6090(94)90081-7
Ruan C, Ai K, Li X, Lu L (2014) A superhydrophobic sponge with excellent absorbency and flame retardancy. Angew Chem-Int Ed 53:5556–5560. https://doi.org/10.1002/anie.201400775
Sasaki K, Tenjimbayashi M, Manabe K, Shiratori S (2016) Asymmetric superhydrophobic/superhydrophilic cotton fabrics designed by spraying polymer and nanoparticles. ACS Appl Mater Interfaces 8:651–659. https://doi.org/10.1021/acsami.5b09782
Song S, Yang H, Zhou C, Cheng J, Jiang Z, Lu Z, Miao J (2017) Underwater superoleophobic mesh based on BiVO 4 nanoparticles with sunlight-driven self-cleaning property for oil/water separation. Chem Eng J 320:342–351. https://doi.org/10.1016/j.cej.2017.03.071
Trinh QH, Lee SB, Mok YS (2014) Hydrophobic coating of silicate phosphor powder using atmospheric pressure dielectric barrier discharge plasma. AlChE J. 60:829–838. https://doi.org/10.1002/aic.14356
Wang B et al (2013) Methodology for robust superhydrophobic fabrics and sponges from in situ growth of transition metal/metal oxide nanocrystals with thiol modification and their applications in oil/water separation. ACS Appl Mater Interfaces 5:1827–1839. https://doi.org/10.1021/am303176a
Wang B, Liang W, Guo Z, Liu W (2015) Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: a new strategy beyond nature. Chem Soc Rev 44:336–361. https://doi.org/10.1039/c4cs00220b
Yalcinkaya F, Siekierka A, Bryjak M (2017) Preparation of fouling-resistant nanofibrous composite membranes for separation of oily wastewater. Polymers. https://doi.org/10.3390/polym9120679
Yan X et al (2016) Colorful hydrophobic poly(vinyl butyral)/cationic dye fibrous membranes via a colored solution electrospinning process. Nanoscale Res Lett 11:1. https://doi.org/10.1186/s11671-016-1763-4
Yang W, Li J, Zhou P, Zhu L, Tang H (2017) Superhydrophobic copper coating: switchable wettability, on-demand oil-water separation, and antifouling. Chem Eng J 327:849–854. https://doi.org/10.1016/j.cej.2017.06.159
Yang J, Pu Y, Miao D, Ning X (2018) Fabrication of durably superhydrophobic cotton fabrics by atmospheric pressure plasma treatment with a siloxane precursor. Polymers 10:460. https://doi.org/10.3390/polym10040460
You YS, Kang S, Mauchauffe R, Moon SY (2017) Rapid and selective surface functionalization of the membrane for high efficiency oil-water separation via an atmospheric pressure plasma process. Sci Rep. https://doi.org/10.1038/s41598-017-15713-x
Zhang L, Li H, Lai X, Su X, Liang T, Zeng X (2017a) Thiolated graphene-based superhydrophobic sponges for oil-water separation. Chem Eng J 316:736–743. https://doi.org/10.1016/j.cej.2017.02.030
Zhang M et al (2017b) Antimicrobial cotton textiles with robust superhydrophobicity via plasma for oily water separation. Appl Surf Sci 419:16–23. https://doi.org/10.1016/j.apsusc.2017.05.008
Zhou H, Wang H, Niu H, Gestos A, Wang X, Lin T (2012) Fluoroalkyl silane modified silicone rubber/nanoparticle composite: a super durable, robust superhydrophobic fabric coating. Adv Mater 24:2409–2412. https://doi.org/10.1002/adma.201200184
Zhou X, Zhang Z, Xu X, Guo F, Zhu X, Men X, Ge B (2013) Robust and durable superhydrophobic cotton fabrics for oil/water separation. ACS Appl Mater Interfaces 5:7208–7214. https://doi.org/10.1021/am4015346
Zhu T, Li S, Huang J, Mihailiasa M, Lai Y (2017) Rational design of multi-layered superhydrophobic coating on cotton fabrics for UV shielding, self-cleaning and oil-water separation. Mater Des 134:342–351. https://doi.org/10.1016/j.matdes.2017.08.071
Acknowledgments
This research was supported by an Institute startup grant from Qingdao University on the establishment of the Industrial Research Institute of Nonwovens &Technical Textiles (IRINTT), and by the General Financial Grant (Grant No.: 2017M612207) from the China Postdoctoral Science Foundation.
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Yang, J., Pu, Y., He, H. et al. Superhydrophobic cotton nonwoven fabrics through atmospheric plasma treatment for applications in self-cleaning and oil–water separation. Cellulose 26, 7507–7522 (2019). https://doi.org/10.1007/s10570-019-02590-y
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DOI: https://doi.org/10.1007/s10570-019-02590-y