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Multifunctional carbon aerogels from typha orientalis for oil/water separation and simultaneous removal of oil-soluble pollutants

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Abstract

Biomass-derived carbon aerogels with 3D network porous structure show excellent physical properties and exhibit superior application potential. Here, we prepare multifunctional carbon aerogels (MCAs) by carbonization of aerogels composed of typha orientalis fibers. The MCAs feature light mass (5.0 mg cm−3), excellent compressibility (80%), good electrical conductivity (0.18 S cm−1), and very high oil absorption capacity (42–160 g g−1). Because of the excellent superhydrophobic/superoleophilic properties, the MCAs can be used as adsorbent materials to remove free oils in water by various methods. The MCAs can also be applied for efficient separation of surfactant-stabilized water-in-oil emulsions and rapid removal of soluble dyes in oils. Furthermore, the mixtures of multi-emulsions and dyes can be purified with MCAs, which makes MCAs alternative materials for oil purification.

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References

  • Barroso-Solares S, Pinto J, Nanni G, Fragouli D, Athanassiou A (2018) Enhanced oil removal from water in oil stable emulsions using electrospun nanocomposite fiber mats. RSC Adv 8:7641–7650

    Article  CAS  Google Scholar 

  • Cai TL, Wang HW, Jin CD, Sun QF, Nie YJ (2018) Fabrication of nitrogen-doped porous electrically conductive carbon aerogel from waste cabbage for supercapacitors and oil/water separation. J Mater Sci Mater Electron 5:4334–4344

    Article  CAS  Google Scholar 

  • Cao EJ, Xiao WL, Duan WZ, Wang NF, Wang AQ, Zheng Y (2018) Metallic nanoparticles roughened Calotropis gigantea fiber enables efficient It absorption of oils and organic solvents. Ind Crop Prod 115:272–279

    Article  CAS  Google Scholar 

  • Chen P, Wang LK, Wang G, Gao MR, Ge J, Yuan WJ, Shen YH, Xie AJ, Yu SH (2014) Nitrogen-doped nanoporous carbon nanosheets derived from plant biomass: an efficient catalyst for oxygen reduction reaction. Energy Environ Sci 7:4095–4103

    Article  CAS  Google Scholar 

  • Deng WS, Long MY, Zhou QN, Wen N, Deng WL (2018) One-step preparation of superhydrophobic acrylonitrile-butadiene-styrene copolymer coating for ultrafast separation of water-in-oil emulsions. J Colloid Interface Sci 511:21–26

    Article  CAS  PubMed  Google Scholar 

  • Du J, Liu L, Hu ZP, Yu YF, Zhang Y, Hou SL, Chen AB (2018) Raw-cotton-derived n-doped carbon fiber aerogel as an efficient electrode for electrochemical capacitors. ACS Sustain Chem Eng 6:4008–4015

    Article  CAS  Google Scholar 

  • Erbil HY, Cansoy CE (2009) Range of Applicability of the Wenzel and Cassie-Baxter equations for superhydrophobic surfaces. Langmuir 25:14135–14145

    Article  CAS  PubMed  Google Scholar 

  • Fang AJ, Long Q, Wu QQ, Li HT, Zhang YY, Yao SZ (2016) Upconversion nanosensor for sensitive fluorescence detection of Sudan I-IV based on inner filter effect. Talanta 148:129–134

    Article  CAS  PubMed  Google Scholar 

  • Feng L, Zhang ZY, Mai ZH, Ma YM, Liu BQ, Jiang L, Zhu DB (2004) A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water. Angew Chem 43:2012–2014

    Article  CAS  Google Scholar 

  • French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896

    Article  CAS  Google Scholar 

  • Guo F, Wen QY, Guo ZG (2017) Low cost and non-fluoride flowerlike superhydrophobic particles fabricated for both emulsions separation and dyes adsorption. J Colloid Interface Sci 507:421–428

    Article  CAS  PubMed  Google Scholar 

  • Hu BB, Wang K, Wu LH, Yu SH, Antonietti M, Titirici MM (2010) Engineering carbon materials from the hydrothermal carbonization process of biomass. Adv Mater 22:813–828

    Article  CAS  Google Scholar 

  • Hu H, Zhao ZB, Gogotsi Y, Qiu JS (2014) Compressible carbon nanotube-graphene hybrid aerogels with superhydrophobicity and superoleophilicity for oil sorption. Environ Sci Technol 1:214–220

    Article  CAS  Google Scholar 

  • Hu JY, Yuan W, Chen WJ, Xu XT, Tang Y (2016) Fabrication and characterization of superhydrophobic copper fiber sintered felt with a 3D space network structure and their oil–water separation. Appl Surf Sci 389:1192–1201

    Article  CAS  Google Scholar 

  • Iglio R, Mariani S, Robbiano V, Strambini L, Barillaro G (2018) Flexible polydimethylsiloxane foams decorated with multiwalled carbon nanotubes enable unprecedented detection of ultralow strain and pressure coupled with a large working range. ACS Appl Mater Interfaces 10:13877–13885

    Article  CAS  PubMed  Google Scholar 

  • Jiao Y, Wan CC, Li J (2016) Synthesis of carbon fiber aerogel from natural bamboo fiber and its application as a green high-efficiency and recyclable adsorbent. Mater Des 107:26–32

    Article  CAS  Google Scholar 

  • Kabiri S, Tran DNH, Altalhi T, Losic D (2014) Outstanding adsorption performance of graphene-carbon nanotube aerogels for continuous oil removal. Carbon 80:523–533

    Article  CAS  Google Scholar 

  • Kılınça E, Çelikb KS, Bilgetekin H (2018) γ-Fe2O3 magnetic nanoparticle functionalized with carboxylated multi walled carbon nanotube for magnetic solid phase extractions and determinations of Sudan dyes and Para Red in food samples. Food Chem 242:533–537

    Article  CAS  Google Scholar 

  • Li LX, Hu T, Sun HX, Zhang JP, Wang AQ (2017) Pressure-sensitive and conductive carbon aerogels from poplars catkins for selective oil absorption and oil/water separation. ACS Appl Mater Interfaces 9:18001–18007

    Article  CAS  PubMed  Google Scholar 

  • Li LX, Li BC, Sun HX, Zhang JP (2013) Compressible and conductive carbon aerogels from waste paper with exceptional performance for oil/water separation. J Mater Chem A 5:14858–14864

    Article  Google Scholar 

  • Liu FT, Lu R, Pan QM (2017) Juncus pith: a versatile material for automatic and continuous separation of various oil–water mixtures. ACS Sustain Chem Eng 5:922–928

    Article  CAS  Google Scholar 

  • Liu RL, Xi X, Xing X, Wu DQ (2016) A facile biomass based approach towards hierarchically porous nitrogen-doped carbon aerogels. RSC Adv 6:83613–83618

    Article  CAS  Google Scholar 

  • Liu Y, Peng YX, Zhang T, Qiu FX, Yuan DS (2018) Superhydrophobic, ultralight and flexible biomass carbon aerogels derived from sisal fibers for highly efficient oil–water separation. Cellulose 25:3067–3078

    Article  CAS  Google Scholar 

  • Miao ZJ, Ding KL, Wu TB, Liu ZM, Han BX, An GM, Miao SD, Yang GY (2008) Fabrication of 3D-networks of native starch and their application to produce porous inorganic oxide networks through a supercritical route. Microporous Mesoporous Mater 111:104–109

    Article  CAS  Google Scholar 

  • Mousavi S, Deuber F, Petrozzi S, Federer L, Aliabadi M, Shahraki F, Adlhart C (2018) Efficient dye adsorption by highly porous nanofiber aerogels. Colloids Surf A 547:117–125

    Article  CAS  Google Scholar 

  • Pan LP, Liu SL, Oderinde O, Li KW, Yao F, Fu GD (2018) Facile fabrication of graphene-based aerogel with rare earth metal oxide for water purification. Appl Surf Sci 427:779–786

    Article  CAS  Google Scholar 

  • Rong J, Qiu FX, Zhang T, Zhang XY, Zhu Y, Xu JC, Yang DY, Dai YT (2017) A facile strategy toward 3D hydrophobic composite resin network decorated with biological ellipsoidal structure rapeseed flower carbon for enhanced oils and organic solvents selective absorption. Chem Eng J 322:397–407

    Article  CAS  Google Scholar 

  • Sidir I, Sidir YG (2015) Estimation of ground and excited state dipole moments of Oil Red O by solvatochromic shift methods. Spectrochim Acta A 135:560–567

    Article  CAS  Google Scholar 

  • Si Y, Yu JY, Tang XM, Ge JL, Ding B (2014) Ultralight nanofibre-assembled cellular aerogels with superelasticity and multifunctionality. Nat Commun 5:5802

    Article  CAS  PubMed  Google Scholar 

  • Stolz A, Floch SL, Reinert L, Ramos SMM, Tuaillon-Combes J, Soneda Y, Chaudet P, Baillis D, Blanchard N, Duclaux L, San-Miguel A (2016) Melamine-derived carbon sponges for oil–water separation. Carbon 107:198–208

    Article  CAS  Google Scholar 

  • Titirici MM, White RJ, Brun N, Budarin VL, Su DS, Monte FD, Clark JH, MacLachlan MJ (2014) Sustainable carbon materials. Chem Soc Rev 44:250–290

    Article  PubMed  Google Scholar 

  • Wang B, Liang WX, Guo ZG, Liu WM (2015) Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: a new strategy beyond nature. Chem Soc Rev 44:336–361

    Article  PubMed  Google Scholar 

  • Wang HY, Gong YT, Wang Y (2014) Cellulose-based hydrophobic carbon aerogels as versatile and superior adsorbents for sewage treatment. RSC Adv 4:45753–45759

    Article  CAS  Google Scholar 

  • Wang J, Hou LA, Yan KK, Zhang L, Yu QJ (2018) Polydopamine nanocluster decorated electrospun nanofibrous membrane for separation of oil/water emulsions. J Membr Sci 547:156–162

    Article  CAS  Google Scholar 

  • Wang JT, Han FN, Liang B, Geng GH (2017a) Hydrothermal fabrication of robustly superhydrophobic cotton fibers for efficient separation of oil/water mixtures and oil-in-water emulsions. J Ind Eng Chem 54:174–183

    Article  CAS  Google Scholar 

  • Wang Y, Zhu L, Zhu FY, You LJ, Shen XQ, Li SJ (2017b) Removal of organic solvents/oils using carbon aerogels derived from waste durian shell. J Taiwan Inst Chem E 78:351–358

    Article  CAS  Google Scholar 

  • Wu XL, Wen T, Guo HL, Yang SB, Wang XK, Xu AW (2013) Biomass-derived sponge-like carbonaceous hydrogels and aerogels for supercapacitors. ACS Nano 7:3589–3597

    Article  CAS  PubMed  Google Scholar 

  • Yang J, Xia YF, Xu P, Chen BB (2018a) Super-elastic and highly hydrophobic/superoleophilic sodium alginate/cellulose aerogel for oil/water separation. Cellulose 25:3533–3544

    Article  CAS  Google Scholar 

  • Yang X, Ma JJ, Ling J, Li N, Wang D, Yue F, Xu SM (2018b) Cellulose acetate-based SiO2/TiO2 hybrid microsphere composite aerogel films for water-in-oil emulsion separation. Appl Surf Sci 435:609–616

    Article  CAS  Google Scholar 

  • Yue XJ, Li JX, Zhang T, Qiu FX, Yang DY, Xue MW (2017a) In situ one-step fabrication of durable superhydrophobic-superoleophilic cellulose/LDH membrane with hierarchical structure for efficiency oil/water separation. Chem Eng J 328:117–123

    Article  CAS  Google Scholar 

  • Yue XJ, Zhang T, Yang DY, Qiu FX, Rong J, Xu JC, Fang JS (2017b) The synthesis of hierarchical porous Al2O3/acrylic resin composites as durable, efficient and recyclable absorbents for oil/water separation. Chem Eng J 309:522–531

    Article  CAS  Google Scholar 

  • Zhang JP, Li BC, Li LX, Wang AQ (2016) Ultralight, compressible and multifunctional carbon aerogels based on natural tubular cellulose. J Mater Chem A 4:2069–2074

    Article  CAS  Google Scholar 

  • Zhang JP, Wu L, Zhang YJ, Wang AQ (2015) Mussel and fish scale-inspired underwater superoleophobic kapok membranes for continuous and simultaneous removal of insoluble oils and soluble dyes in water. J Mater Chem A 3:18475–18482

    Article  CAS  Google Scholar 

  • Zhang T, Kong LY, Dai YT, Yue XJ, Rong J, Qiu FX, Pan JM (2017) Enhanced oils and organic solvents absorption by polyurethane foams composites modified with MnO2 nanowires. Chem Eng J 309:7–14

    Article  CAS  Google Scholar 

  • Zheng Y, Cao EJ, Tu LX, Wang AQ, Hu HM (2017) A comparative study for oil-absorbing performance of octadecyltrichlorosilane treated Calotropis gigantea fiber and kapok fiber. Cellulose 24:989–1000

    Article  CAS  Google Scholar 

  • Zhu DN, Xia YF, Yang J, Chen BB, Guo S, Li CS (2017) One-step removal of insoluble oily compounds and water-miscible contaminants from water by underwater superoleophobic graphene oxide-coated cotton. Cellulose 24:5605–5614

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the National Nature Science Foundation of China (51602132).

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Authors and Affiliations

  1. Institute for Advanced Materials, School of Materials Science and Engineering, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Jin Yang, Peng Xu, Yunfei Xia & Beibei Chen

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  1. Jin Yang
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  2. Peng Xu
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  3. Yunfei Xia
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  4. Beibei Chen
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Correspondence to Jin Yang or Beibei Chen.

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Yang, J., Xu, P., Xia, Y. et al. Multifunctional carbon aerogels from typha orientalis for oil/water separation and simultaneous removal of oil-soluble pollutants. Cellulose 25, 5863–5875 (2018). https://doi.org/10.1007/s10570-018-1994-x

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  • DOI: https://doi.org/10.1007/s10570-018-1994-x

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