Abstract
In this work, cotton fabrics grafted with poly (propylene imine) PPI dendrimers (second and fifth generations) were dyed with three different direct dyes (Direct Orange 34, Direct Red 83 and Direct Blue 199) using the salt-free dyeing method. Results showed that the color strength (K/S) of the grafted samples had been markedly enhanced compared with control samples. In addition, the equilibrium and kinetic data of the dye sorption process were evaluated using well-known mathematical models. It was found that the isotherm data of both direct dyes (Direct Orange 34 and Direct Red 83) followed the Langmuir sorption model, while the Freundlich model was able to describe the sorption isotherm of Direct Blue 199 on the grafted cotton fabric. Furthermore, the experimental data of the three direct dyes were fitted by the nonlinear pseudo-second order kinetic model. Wash, light and rubbing fastnesses of the dyed cotton samples were also investigated.
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References
Boas U, Christensen JB, Heegaard PMH (2006) Dendrimers in medicine and biotechnology: new molecular tools. RSC Publishing, Cambridge
Burkinshaw SM, Mignanelli M, Froehling PE, Bide MJ (2000) The use of dendrimers to modify the dyeing behavior of reactive dyes on cotton. Dyes Pigment 47:259–267. doi:10.1016/S0143-7208(00)00053-X
Burkinshaw SM, Froehling PE, Mignanelli M (2002) The effect of hyperbranched polymers on the dyeing of polypropylene fibers. Dyes Pigment 53:229–235. doi:10.1016/S0143-7208(02)00006-2
Dehabadi VA, Buschmann HJ, Gutmann JS (2013) Pretreatment of cotton fabrics with polyamino carboxylic acids for salt-free dyeing of cotton with reactive dyes. Color Technol 129:155–158. doi:10.1111/cot.12010
Diallo MS, Falconer K et al (2007) Dendritic anion hosts: perchlorate uptake by G5-NH2 poly(propyleneimine) dendrimer in water and model electrolyte solutions. Environ Sci Technol 41:6521–6527. doi:10.1021/es0710959
Draper SL, Beck KR, Smith CB, Hauser PJ (2002) Characterization of the dyeing behavior of cationic cotton with direct dyes. AATCC Rev 2:24–27
Draper SL, Beck KR, Smith CB, Hauser PJ (2003) Characterization of the dyeing behavior of cationic cotton with acid dyes. AATCC Rev 3:51–55
El-Shishtawy RM, Youssef YA, Ahmed NSE, Mousa AA (2004) Acid dyeing isotherms of cotton fabrics pretreated with mixtures of reactive cationic agents. Color Technol 120:195–200. doi:10.1111/j.1478-4408.2004.tb00229.x
Freundlich HMF (1906) Über die adsorption in lösungen. Z Phys Chem Frankfurt 57A:385–470
Froehling PE (2001) Dendrimers and dyes-a review. Dyes Pigment 48:187–195. doi:10.1016/S0143-7208(00)00099-1
Garland CE (1993) Textile chemistry. American association of textile chemists and colorists, New York
Goldstein HB, Koeing DV (1959) Effect of crease proofing agents on light fastness of sensitive dyes. Text Res J 29:66–73. doi:10.1177/004051755902900108
Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465. doi:10.1016/S0032-9592(98)00112-5
Ho YS, Porter JF, McKay G (2002) Equilibrium isotherm studies for the sorption of divalent metal Ions onto peat: copper, nickel and lead single component systems. Water Air Soil Pollut 141:1–33. doi:10.1023/A:1021304828010
Jacobasch H, Baubck G, Schurz J (1985) Problems and results of zeta-potential measurements on fibers. Colloid Polym Sci 263:3–24. doi:10.1007/BF01411243
Jacobasch H, Simon F, Werner C, Bellmann C (1996) Bestimmung des zetapotentials aus strömungspotential-und strömungsstrommessungen. Tech Mess 63:447–452. doi:10.1524/teme.1996.63.jg.447
Kabanov VA, Zezin AB et al (1998) Polyelectrolyte behavior of astramol poly (propyleneimine) dendrimers. Macromol 31:5142–5144. doi:10.1021/ma971643a
Kanik M, Hauser PJ (2003) Printing cationized cotton with acid dyes. AATCC Rev 3:25–28. doi:10.1177/004051750407400108
Kanik M, Hauser PJ (2004) Printing cationized cotton with direct dyes. Text Res J 74:43–50. doi:10.1177/004051750407400108
Lagergren S (1898) Zur theorie der sogenannten adsorption geloster stoffe, Kungliga Svenska Vetenskapsakademiens. Handlingar 24:1–39
Langmuir I (1916) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 38:2221–2295. doi:10.1021/ja02268a002
Lim SH, Hudson SH (2004) Application of a fiber-reactive chitosan derivative to cotton fabric as a zero-salt dyeing auxiliary. Color Technol 120:108–113. doi:10.1111/j.1478-4408.2004.tb00215.x
Lin J, Wang L (2009) Comparison between linear and non-linear forms of pseudo-first-order and pseudo-second-order adsorption kinetic models for the removal of methylene blue by activated carbon. Front Environ Sci Eng China 3:320–324. doi:10.1007/s11783-009-0030-7
Meijer EW, Jansen JFGA, De Brabander-van den Berg EMM (1994) Encapsulation of guest molecules into a dendritic box. Science 266:1226–1229. doi:10.1126/science.266.5188.1226
Montazer M, Malek RMA, Rahimi A (2007) Salt free reactive dyeing of cationized cotton. Fibers Polym 8:608–612. doi:10.1007/BF02875997
Newkome GR, Moorefield CN, Vogtle F (2001) Dendrimers and dendrons. concepts, syntheses, applications. Wiley, Weinheim
Porter JJ (1967) A fundamental study of the acid dyeing equilibria of aminized cotton. Text Res J 37:643–654. doi:10.1177/004051756703700803
Porter JJ (1968) Letters to editor: acid dyeing equilibria on aminized cotton. Text Res J 38:205–207. doi:10.1177/004051756803800212
Porter JJ (2002) Dyeing equilibria: interaction of direct dyes with cellulose substrates. Color Technol 118:238–243. doi:10.1111/j.1478-4408.2002.tb00106.x
Porter JJ (2003) Understanding the sorption of direct dyes on cellulose substrates. AATCC rev 3:20–24
Salimpour Abkenar S, Malek RMA (2012) Preparation, characterization, and antimicrobial property of cotton cellulose fabric grafted with poly (propylene imine) dendrimer. Cellulose 19:1701–1714. doi:10.1007/s10570-012-9744-y
Salimpour Abkenar S, Malek RMA, Mazaheri F (2013) Thermal properties of cotton fabric modified with poly (propylene imine) dendrimers. Cellulose 20:3079–3091. doi:10.1007/s10570-013
Srikulkit K, Santifuengkul P (2000) Salt free dyeing of cotton cellulose with a model cationic reactive dye. JSDC 117:398–402. doi:10.1111/j.1478-4408.2000.tb00017.x
Uma, Banerjee S, Sharma YC (2013) Equilibrium and kinetic studies for removal of malachite green from aqueous solution by a low coast activated carbon. J Ind Eng Chem 19:1099–1105. doi:10.1016/j.jiec.2012.11.030
Vickerstaff T (1954) The physical chemistry of dyeing. Oliver and Boyed, London
Vogtle F (2001) Dendrimers III: Design, dimension and function: topics in current chemistry, 212. Springer, Berlin
Wu TS, Chen KM (1993) New cationic agents for improving the dyeability of cellulose fibers. JSDC 109:153–158. doi:10.1111/j.1478-4408.1992.tb01486.x
Zhang F, Chen Y, Lin H, Lu Y (2007) Synthesis of an amino-terminated hyperbranched polymer and its application in reactive dyeing on cotton as a salt-free dyeing auxiliary. Color Technol 123:351–357. doi:10.1111/j.1478-4408.2007.00108.x
Zhang F, Chen Y, Lin H, Wang H, Zhao B (2008) HBP-NH2 grafted cotton fiber: preparation and salt-free dyeing properties. Carbohydr Polym 74:250–256. doi:10.1016/j.carbpol.2008.02.006
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Salimpour Abkenar, S., Malek, R.M.A. & Mazaheri, F. Salt-free dyeing isotherms of cotton fabric grafted with PPI dendrimers. Cellulose 22, 897–910 (2015). https://doi.org/10.1007/s10570-014-0534-6
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DOI: https://doi.org/10.1007/s10570-014-0534-6