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PMMA–cellulose acetate phthalate nanocomposites reinforced with silane-treated nanoclay

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Abstract

A blend of cellulose acetate phthalate with poly (methyl methacrylate) has been developed by reinforcing it with silane-treated nanoclay. In order to enhance interactions between the nanoclay and blend components, maleic anhydride was added as the coupling agent. The mechanical properties were enhanced and were further analyzed by theoretical models. The thermal properties and water absorption characteristics were also assessed.

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References

  • Aoki D, Teramoto Y, Nishio Y (2011) Cellulose acetate/polymethyl methacrylate) interpenetrating networks; synthesis and estimation of thermal and mechanical properties. Cellulose 18:1441–1454

    Article  CAS  Google Scholar 

  • Bhat DK, Selvakumar M (2006) Biodegradability of PMMA blends with some cellulose derivatives. J Polym Environ 14:385–392

    Article  CAS  Google Scholar 

  • Bliznakov ED, White CC, Shaw MT (2000) Mechanical properties of blends of HDPE and recycled urea–formaldehyde resin. J Appl Polym Sci 77:3220–3227

    Article  CAS  Google Scholar 

  • Canche-Escamilla G, Rodriguez-Trijillo G, Herrera-Franco PJ, Mendizabal E, Puig JE (1997) Preparation and characterization of henequen cellulose grafted with methyl methacrylate and its application in composites. J Appl Polym Sci 66:339–346

    Article  CAS  Google Scholar 

  • Dorigato A, Pegoretti A (2012) Fracture behavior of LDPE-fumed silica nanocomposites. Eng Fract Mech 79:213–224

    Article  Google Scholar 

  • Fahma F, Hori N, Iwata T, Takemura A (2013) The morphology and properties of poly (methyl methacrylate)–cellulose nanocomposites prepared by immersion precipitation method. J Appl Polym Sci 128:1563–1568

    CAS  Google Scholar 

  • Fox TG (1956) Influence of diluent of copolymer composition on the glass temperature of a polymer system. Bull Am Phys Soc 1:123–125

    CAS  Google Scholar 

  • Gaurav A, Ashamol A, Deepthi MV, Sailaja RRN (2012) Biodegradable nanocomposites of cellulose acetate phthalate and chitosan reinforced with functionalized nanoclay mechanical, thermal and biodegradability studies. J Appl Polym Sci 125:E16–E26

    Article  CAS  Google Scholar 

  • Gordon M, Taylor JS (1952) Ideal copolymers and the second-order transitions of synthetic rubbers non-crystalline copolymers. J Appl Chem 2:493–500

    Article  CAS  Google Scholar 

  • Guruprasad KH, Shashidhara GM (2004) Grafting, blending and biodegradability of cellulose acetate. J Appl Polym Sci 91:1715–1723

    Article  Google Scholar 

  • Littunen K, HIppi U, Saarinen T, Seppala J (2013) Network formation of nanofibrillated cellulose in solution blended poly (methyl methacrylate) composites. Carbohydr Polym 91:183–190

    Article  CAS  Google Scholar 

  • Liu H, Liu D, Yao F, Wu Q (2010) Fabrication and properties of transparent polymethylmethacrylate/cellulose nanocrystals composites. Bioresour Technol 101:5685–5692

    Article  CAS  Google Scholar 

  • Maiti S, Sain S, Ray D, Mitra D (2013) Biodegradation behavior of PMMA/cellulose nanocomposites prepared by in-situ polymerization and ex-situ dispersion methods. Polym Degrad Stab 98:635–642

    Article  CAS  Google Scholar 

  • Martin L, Kortaberri G, Vazquez A, Fermeglia M, Martinelli L, Sinesi S, Jimeno A, De la Caba K, Mondragon I (2008) A comparative study of nanocomposites based on a recycled poly(methyl methacrylate) matrix containing several nanoclays. Polym Compos 29:782–790

    Article  CAS  Google Scholar 

  • Menjoge AR, Kulkarni MG (2007) Mechanistic investigations of phase behavior in Eudragit E blends. Int J Pharm 343:106–121

    Article  CAS  Google Scholar 

  • Nicolais N, Narkis M (1971) Stress–strain behavior of SAN/glass bead composites above the glass transition temperature. J Appl Polym Sci 15:469–476

    Article  Google Scholar 

  • Nishioka N, Yamaoka M, Handeda H, Kawakami K, Uno M (1993) Thermal decomposition of cellulose/synthetic polymer blends containing grafted products I. Cellulose/poly(methyl methacrylate). Blends Macromol 26:4694–4699

    Article  CAS  Google Scholar 

  • Ohno T, Yoshizawa S, Miyashita Y, Nishio Y (2005) Interaction and scale of mixing in cellulose acetate/poly(N-vinyl pyrrolidone—co-vinyl acetate) blends. Cellulose 12:281–291

    Article  CAS  Google Scholar 

  • Pandey P, Anbudayanidhi S, Mohanty S, Nayak SK (2012) Flammability and thermal characterization of PMMA/clay nanocomposites and thermal kinetics analysis. Polym Compos 33:2058–2071

    Article  CAS  Google Scholar 

  • Rao V, Ashokan PV, Shridhar MH (2000a) Studies of dielectric relaxation and ac conductivity in cellulose acetate hydrogen phthalate–poly(methyl methacrylate) blends. Mater Sci Eng A281:213–220

    Article  CAS  Google Scholar 

  • Rao V, Ashokan PV, Shridhar MH (2000b) Miscible blends of cellulose acetate hydrogen phthalate and poly (vinyl pyrollidone) characterization by viscometry, ultrasound and DSC. J Appl Polym Sci 76:859–867

    Article  CAS  Google Scholar 

  • Rao V, Ashokan PV, Amar JV (2002) Studies on dielectric relaxation and ac conductivity of cellulose acetate hydrogen phthalate/poly (vinyl pyrrolidone) blend. J Appl Polym Sci 86:1702–1708

    Article  CAS  Google Scholar 

  • Sagar AD, Merrill EW (1995) Properties of fatty acid esters of starch. J Appl Polym Sci 58:1647–1656

    Article  CAS  Google Scholar 

  • Sailaja RRN (2005) Mechanical properties of esterified topical starch LDPE blends using LDPE-co-glycidyl methacrylate as compatibilizer. Polym Int 54:286–296

    Article  CAS  Google Scholar 

  • Sain S, Ray D, Mukhopadhyay A, Sengupta S, Kar T, Ennis CJ, Rahman PKSM (2012) Synthesis and characterization of PMMA–cellulose nanocomposites by In situ polymerization techniques. J Appl Polym Sci 126:E127–E137

    Article  CAS  Google Scholar 

  • Selvakumar M, Bhat DK (2008) Miscibility of poly (methylmethacrylate) and cellulose acetate/butyrate blends in dimethyl formamide. Indian J Chem Technol 15:547–554

    CAS  Google Scholar 

  • Shanmugharaj AM, Rhee KY, Ryu SH (2006) Influence of dispersing medium on grafting of aminopropyltriethoxysilane in swelling clay materials. J Colloid Interface Sci 298:854–859

    Article  CAS  Google Scholar 

  • Shashidhara GM, Guruprasad KH, Varadarajulu A (2002) Miscibility studies on blends of cellulose acetate and nylon 6. Eur Polym J 38:611–614

    Article  CAS  Google Scholar 

  • Stapountzi OA, Charalamibides MN, Williams JG (2009) Micromechanical models for stiffness prediction of alumina trihydrate (ATH) reinforced poly (methyl methacrylate) (PMMA): effect of filler volume fraction and temperature. Compos Sci Technol 69:2015–2023

    Article  CAS  Google Scholar 

  • Thakore IM, Desai S, Sarawade BD, Devi S (2001) Studies on biodegradability, morphology and thermomechanical properties of LDPE/modified starch blends. Eur Polym J 37:151–160

    Google Scholar 

  • Turcsanyi B, Pukanszky B, Tudos F (1988) Composition dependence of tensile yield stress in filled polymers. J Mater Sci Lett 7:160–163

    Article  CAS  Google Scholar 

  • Wang L, Wang A (2007) Adsorption characteristics of congo red onto the chitosan/montmorillonite nanocomposites. J Hazard Mater 147:979–985

    Article  CAS  Google Scholar 

  • Wang W, Zheng, Y, Wang A (2008) Syntheses and properties of superabsorbent composites based on natural guar gum and attapulgite. Polym Adv Technol 19:1852–1859

    Google Scholar 

  • Zou Y, Wang L, Zhang H, Qian Z, Mou L, Wang J, Liu X (2004) Stabilization and mechanical properties of biodegradable aliphatic polyesteramide and its filled composites. Polym Degrad Stab 83:87–92

    Article  CAS  Google Scholar 

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Correspondence to R. R. N. Sailaja.

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Manjunath, L., Sailaja, R.R.N. PMMA–cellulose acetate phthalate nanocomposites reinforced with silane-treated nanoclay. Cellulose 21, 1793–1802 (2014). https://doi.org/10.1007/s10570-014-0190-x

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  • DOI: https://doi.org/10.1007/s10570-014-0190-x

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