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Functionalized SBA-15 and its Catalytic Applications in Selective Organic Transformations

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Abstract

Ordered, mesoporous SBA-15 functionalized with organic and inorganic moieties exhibits efficient catalytic activity in a variety of organic transformations. In this account, reviewing our own work, three-sets of surface-modified SBA-15 materials have been investigated. The first-set of materials consists of SBA-15 modified with organo-acidic (propyl thiol and propyl sulfonic acid) and basic (propyl amine and propyl adenine) moieties. The second-set of materials was prepared by grafting Mn complexes to the organo-functionalized SBA-15. The third-set composes of nanocrystalline metal oxides supported on SBA-15. All these catalysts have been characterized by structural and spectroscopic techniques. Catalytic activities of the first-set of solid materials have been investigated in acid/base-catalyzed reactions viz., ring-opening of epoxides with amines (producing β-amino alcohols), esterification, three-component-Mannich reactions and cycloaddition of CO2 to epoxides. The Mn complexes grafted on organofunctionalized SBA-15 are efficient catalysts for the chemo-, regio- and stereoselective aerial oxidation of monoterpenes at ambient conditions. TiOx, VOx, MoOx and WOx supported on SBA-15 catalyzed biomimetic oxyhalogenation of aromatic compounds. In all these reactions, the functionalized SBA-15 showed high selectivity.

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Acknowledgment

Lakshi Saikia acknowledges the Council of Scientific and Industrial Research (CSIR), New Delhi for the award of a senior research fellowship.

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Authors and Affiliations

  1. Catalysis Division, National Chemical Laboratory, Pune, 411 008, India

    Darbha Srinivas & Lakshi Saikia

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  1. Darbha Srinivas
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  2. Lakshi Saikia
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Correspondence to Darbha Srinivas.

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Srinivas, D., Saikia, L. Functionalized SBA-15 and its Catalytic Applications in Selective Organic Transformations. Catal Surv Asia 12, 114–130 (2008). https://doi.org/10.1007/s10563-008-9044-6

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