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Palladium Nanoparticles Supported on Ce-MOF-801 as Highly Efficient and Stable Heterogeneous Catalysts for Suzuki-Miyaura Coupling Reactions

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Abstract

Palladium nanoparticles (Pd NPs) supported on a cerium-based metal–organic framework Ce-MOF-801 (Pd/Ce-MOF-801) was prepared using an incipient wetness impregnation strategy. Multiple analytical techniques were used to investigate the physicochemical properties of Pd/Ce-MOF-801. Afterwards, its catalytic efficiency in the Suzuki-Miyaura cross-coupling reaction between different haloarenes and phenylboronic acid was assessed. The developed Pd/Ce-MOF-801 displayed a high catalytic performance at 318 K and in the presence of K2CO3 as well as aqueous ethanol (as a solvent), much superior to Pd/Ce-BTC as well as the analogs reported in the literature by comprehensively comparing the catalytic activity and the relationship between reaction temperature and catalyst dosage. Moreover, the catalyst exhibited negligible Pd species leaching and was capable of being recycled in eight successive runs without any decay in reactivity. Such protocol has the advantages of ambient reaction conditions and tolerance to various substrates with various functional groups.

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Acknowledgements

We thank the financial support from the National Natural Science Foundation of China (Grant No. 21576243), and the Natural Science Foundation of Zhejiang Province (Grant No. LY18B060006).

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Authors and Affiliations

  1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, 321004, People’s Republic of China

    Wenting Lin, Yaping Song, Li Wang, Nan Li, Yanghe Fu, De-Li Chen, Weidong Zhu & Fumin Zhang

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  1. Wenting Lin
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  2. Yaping Song
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  3. Li Wang
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  4. Nan Li
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  5. Yanghe Fu
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  6. De-Li Chen
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  7. Weidong Zhu
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  8. Fumin Zhang
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Contributions

WL: investigation, methodology, writing—original draft. YS: methodology. LW: methodology. NL: methodology. YF: writing—original draft. De-LiC: writing—original draft. WZ: project administration. FZ: conceptualization, project administration, supervision, Writing—review & editing.

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Correspondence to Fumin Zhang.

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Lin, W., Song, Y., Wang, L. et al. Palladium Nanoparticles Supported on Ce-MOF-801 as Highly Efficient and Stable Heterogeneous Catalysts for Suzuki-Miyaura Coupling Reactions. Catal Lett 153, 2368–2377 (2023). https://doi.org/10.1007/s10562-022-04163-4

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