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ZIF-67 Derived Hollow Structured Co3O4 Nanocatalysts: Tunable Synthetic Strategy Induced Enhanced Catalytic Performance

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Abstract

Two different hollow structured Co3O4 micro-polyhedrons, derived from Zeolitic imidazolate frameworks (ZIF)-67 crystals, were fabricated by tuning the synthetic strategy (positive or reverse addition). The results demonstrate that the synthetic strategy significantly affect catalyst structure and properties. Compared with Co3O4-A nanocatalyst, the Co3O4-B nanocatalyst exhibit superior catalytic performance, showing 100% CO conversion at the conditions of T = 110 °C and SV = 30,000 h−1. The higher catalytic performance could be attributed to its higher surface area, lower temperature reducibility, and abundant surface Co3+ and adsorbed oxygen.

Graphic Abstract

Two different hollow structured Co3O4 micro-polyhedrons, derived from Zeolitic imidazolate frameworks (ZIF)-67 crystals, were fabricated by tuning the synthetic strategy (positive or reverse addition). The Co3O4-B nanocatalyst exhibit superior catalytic performance, which should be attributed to its higher surface area, lower temperature reducibility, and abundant surface Co3+ and adsorbed oxygen.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21503184), the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (18KJA610004), and the Natural Science Foundation of Jiangsu Province-General Program (BK20171273).

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Authors and Affiliations

  1. School of Environmental Science and Engineering, Yancheng Institute of Technology, Yancheng, 224051, China

    Changyu Zhang, Ruiyu Jiang, Lei Li, Yan Cao & Jinlong Yan

  2. Department of Chemical Engineering, Sichuan University, Chengdu, 610065, China

    Wei Chu

  3. State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, China

    Qilei Yang

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  1. Changyu Zhang
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  2. Wei Chu
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  3. Ruiyu Jiang
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  4. Lei Li
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  6. Yan Cao
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  7. Jinlong Yan
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Zhang, C., Chu, W., Jiang, R. et al. ZIF-67 Derived Hollow Structured Co3O4 Nanocatalysts: Tunable Synthetic Strategy Induced Enhanced Catalytic Performance. Catal Lett 149, 3058–3065 (2019). https://doi.org/10.1007/s10562-019-02871-y

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  • DOI: https://doi.org/10.1007/s10562-019-02871-y

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