Abstract
This work aims to evaluate formed products according to the Anderson-Schulz- Flory (ASF) distribution in Fischer-Tropsch synthesis. The crystalline phases of cerium and cobalt were confirmed in the mesoporous structure of the SBA-15 molecular sieve. The ASF distribution model showed a distribution of products with two chain growth probabilities, α1 and α2 for Co/Ce/SBA-15 catalyst. The maximum production of hydrocarbons was in the range of light olefins, followed by gasoline.
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Bezemer GL, Bitter JH, Kuipers HPCE et al (2006) Cobalt particle size effects in the Fischer–Tropsch reaction studied with carbon nanofiber supported catalysts. Am Chem Soc 128(12):3956–3964
Vo D-VN, Arcotumapathy V, Abdullah B et al (2013) Evaluation of Ba-promoted Mo carbide catalyst for Fischer–Tropsch synthesis. J Chem Technol Biotechnol 88(7):1358–1363
Dry ME (2001) High quality diesel via the Fischer–Tropsch process—a review. J Chem Technol Biotechnol 77(1):43–50
Griboval-Constant A, Butel A, Ordomskya VV et al (2014) Cobalt and iron species in alumina supported bimetallic catalysts for Fischer–Tropsch reaction. Appl Catal A 481:116–126
Dai X, Yu C, Li R (2007) Deactivation of CeO2-promoted Co/SiO2 Fischer–Tropsch catalysts. Chin J Catal 28(12):1047–1052
Bartolini M, Molina J, Alvarez J et al (2015) Effect of the porous structure of the support on hydrocarbon distribution in the Fischer–Tropsch reaction. J Power Sources 285:1–11
Huang J, Qian W, Zhang H et al (2018) Influences of ordered mesoporous silica on product distribution over Nb-promoted cobalt catalyst for Fischer–Tropsch synthesis. Fuel 216:843–851
González GP, Martínez A, Murciano R et al (2009) Cobalt supported on morphologically tailored SBA-15 mesostructures: the impact of pore length on metal dispersion and catalytic activity in the Fischer–Tropsch synthesis. Appl Catal A 367(1–2):146–156
Pardo-Tarifa F, Cabrera S, Sanchez-Dominguez M et al (2017) Ce-promoted Co/Al2O3 catalysts for Fischer–Tropsch synthesis. Int J Hydrogen Energy 42(10):9754–9765
Dai X, Yu C, Li R et al (2006) Role of CeO2 promoter in Co/SiO2 catalyst for Fischer–Tropsch synthesis. Chin J Catal 27(10):904–910
He L, Teng B, Zhang Y et al (2015) Development of composited rare-earth promoted cobalt-based Fischer–Tropsch synthesis catalysts with high activity and selectivity. Appl Catal A 505:276–283
Zhang X, Su H, Zhang Y et al (2016) Effect of CeO2 promotion on the catalytic performance of Co/ZrO2 catalysts for Fischer–Tropsch synthesis. Fuel 184:162–168
Johnson GR, Bell AT (2016) Effects of Lewis acidity of metal oxide promoters on the activity and selectivity of Co-based Fischer–Tropsch synthesis catalysts. J Catal 338:250–264
Yang R, Zhou L, Gao J et al (2017) Effects of experimental operations on the Fischer–Tropsch product distribution. Catal Today 298:77–88
Puskas I, Hurlbut RS (2003) Comments about the causes of deviations from the Anderson–Schulz–Flory distribution of the Fischer–Tropsch reaction products. Catal Today 84(1–2):99–109
Cheng J, Song T, Hu P et al (2008) A density functional theory study of the α-olefin selectivity in Fischer–Tropsch synthesis. J Catal 255(1):20–28
Madon RJ, Iglesia E (1993) The importance of olefin readsorption and H2/CO reactant ratio for hydrocarbon chain growth on ruthenium catalysts. J Catal 139(2):576–590
Zhao D, Feng J, Hou Q et al (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 Angstrom pores. Science 279(5350):548–552
Zhao D, Hou Q, Feng J et al (1998) Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. JACS 120(24):6024–6036
González GP, Concepción P, Murciano R al (2013) The impact of pre-reduction thermal history on the metal surface topology and site-catalytic activity of Co/SiO2 Fischer–Tropsch catalysts. J Catal 302:37–48
Blasco T, Botella P, Concepción P et al (2004) Selective oxidation of propane to acrylic acid on K-doped MoVSbO catalysts: catalyst characterization and catalytic performance. J Catal 228(2):362–373
Martínez A, González GP, Rollán J (2009) Nanofibrous γ-Al2O3 as support for Co-based Fischer–Tropsch catalysts: pondering the relevance of diffusional and dispersion effects on catalytic performance. J Catal 263(2):292–305
González GP (2010) Requerimientos físico-químicos y estructurales en catalizadores avanzados para la conversión de gas de síntesis. Polytechnic University of Valencia, Valencia
Sousa BV (2009) Desenvolvimento de catalisadores (Co/MCM-41) destinados a reação de Fischer–Tropsch. Federal Universitiy of Campina Grande, Campina Grande
Sing KSW (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 57(4):603–619
Borg O, Eri S, Blekkan EA et al (2007) Fischer–Tropsch synthesis over γ-alumina-supported cobalt catalysts: effect of support variables. J Catal 248(1):89–100
Acknowledgements
This research was supported with a partnership between Department of Chemical Engineering - Federal University of Campina Grande and Higher Council for Scientific Research - Polytechnic University of Valencia. The scholarship was awarded by Coordination for the Improvement of Higher Level Education a Personnel (CAPES).
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Albuquerque, J.S., Costa, F.O. & Barbosa, B.V.S. Fischer–Tropsch Synthesis: Analysis of Products by Anderson–Schulz–Flory Distribution Using Promoted Cobalt Catalyst. Catal Lett 149, 831–839 (2019). https://doi.org/10.1007/s10562-019-02655-4
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DOI: https://doi.org/10.1007/s10562-019-02655-4