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Phenylene and Isatin Based Bifunctional Mesoporous Organosilica Supported Schiff-Base/Manganese Complex: An Efficient and Recoverable Nanocatalyst

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Abstract

A novel bifunctional periodic mesoporous organosilica supported isatin-Schiff-base/manganese complex [BPMO@ISB/Mn(II)] is prepared, characterized and its catalytic performance is investigated in the synthesis of dihydropyrano[3,2-c]chromene derivatives. The BPMO@ISB was prepared via grafting of 3-aminopropyltrimethoxysilane (APTS) on a phenylene based PMO followed by treatment with isatin. The BPMO@ISB was then reacted with Mn(NO3)2·4H2O to afford the BPMO@ISB/Mn(II) nanocatalyst. This catalyst was characterized using Fourier transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), energy-dispersive X-ray (EDX) spectroscopy, scanning electron microscopy (SEM), low angle powder X-ray diffraction (LAPXRD) analysis and transmission electron microscopy (TEM). The BPMO@ISB/Mn(II) nanocatalyst was successfully used in one-pot synthesis of 3,4-dihydropyrano[c]chromene derivatives at room temperature. In addition, the stability, recyclability and reusability of designed nanocatalyst were studied under applied conditions.

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Acknowledgements

The authors thank the Yasouj University and the Iran National Science Foundation (INSF) for supporting this work.

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  1. Department of Chemistry, Yasouj University, 75918-74831, Yasouj, Iran

    Meysam Norouzi & Dawood Elhamifar

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  1. Meysam Norouzi
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  2. Dawood Elhamifar
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Correspondence to Dawood Elhamifar.

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Norouzi, M., Elhamifar, D. Phenylene and Isatin Based Bifunctional Mesoporous Organosilica Supported Schiff-Base/Manganese Complex: An Efficient and Recoverable Nanocatalyst. Catal Lett 149, 619–628 (2019). https://doi.org/10.1007/s10562-019-02653-6

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