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Bipyridine-Proline Grafted Silicas with Different Mesopore Structures: Their Catalytic Performance in Asymmetric Aldol Reaction and Structure Effect

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Abstract

A series of immobilized bipyridine-proline based on mesoporous silica with different structures were synthesized via grafting followed by coordination method. All catalysts were used in asymmetric aldol reaction of cyclohexanone with 4-nitrobenzaldehyde, and their catalytic performance including activities and stabilities have been investigated. The results indicated that the pore structure, morphology, and even the particle dispersity all showed the effects on the catalytic performance of immobilized catalysts.

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Acknowledgements

This project was supported by the National Natural Science Foundation of China (21576005, 21403011), and the Beijing Municipal Natural Science Foundation (2152005, 2172004).

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Authors and Affiliations

  1. Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Chemical Engineering, Beijing University of Technology, 100 PingLeYuan, Chaoyang District, Beijing, 100124, People’s Republic of China

    Xu He, Shiyang Bai, Jihong Sun, Yajing Zhang, Hongwu Zhao & Xia Wu

Authors
  1. Xu He
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  2. Shiyang Bai
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  3. Jihong Sun
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  4. Yajing Zhang
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  5. Hongwu Zhao
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  6. Xia Wu
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Corresponding authors

Correspondence to Shiyang Bai or Jihong Sun.

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He, X., Bai, S., Sun, J. et al. Bipyridine-Proline Grafted Silicas with Different Mesopore Structures: Their Catalytic Performance in Asymmetric Aldol Reaction and Structure Effect. Catal Lett 148, 2408–2417 (2018). https://doi.org/10.1007/s10562-018-2421-5

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