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Efficient Room-Temperature Selective Oxidation of Benzyl Alcohol into Benzaldehyde Over Pt/BiOCl Nanocomposite

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Abstract

Stable Pt/BiOCl nanocomposite was successfully fabricated via a facile one-step solution method and applied in room temperature selective oxidation of benzyl alcohol under base-free aqueous conditions. The results demonstrate that Pt/BiOCl exhibits excellent catalytic efficiency with the activity of 99.6% in conversion and nearly 100% selectivity to benzaldehyde in 5 h and it may be ascribed to the coexistence of Pt and BiOCl which facilitate the activation of α-C–H in benzyl alcohol. This study successfully expands the applications of BiOCl-related materials from photocatalysis to selective oxidative reactions in non-photocatalytic reactions.

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Acknowledgements

The authors gratefully acknowledge the financial support of National Natural Science Foundation of China (21703050), China Postdoctoral Science Foundation (512200-X91701) and Special Research Foundation of Young Teachers in Hangzhou Dianzi University (ZX150204307002/032).

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Authors and Affiliations

  1. College of Materials & Environmental Engineering, Hangzhou Dianzi University, Hangzhou, 310036, People’s Republic of China

    Juanjuan Liu, Qihai Yuan & Hongting Zhao

  2. Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou, 310027, People’s Republic of China

    Shihui Zou

Authors
  1. Juanjuan Liu
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  2. Qihai Yuan
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  3. Hongting Zhao
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  4. Shihui Zou
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Correspondence to Juanjuan Liu or Shihui Zou.

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Liu, J., Yuan, Q., Zhao, H. et al. Efficient Room-Temperature Selective Oxidation of Benzyl Alcohol into Benzaldehyde Over Pt/BiOCl Nanocomposite. Catal Lett 148, 1093–1099 (2018). https://doi.org/10.1007/s10562-018-2337-0

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  • DOI: https://doi.org/10.1007/s10562-018-2337-0

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